3-BROMOCHLOROBENZENE
- Product Name
- 3-BROMOCHLOROBENZENE
- CAS No.
- 108-37-2
- Chemical Name
- 3-BROMOCHLOROBENZENE
- Synonyms
- 3-BromochL;3-BroMochlorob;M-chlorbromobenzene;M-BROMOCHLOROBENZENE;M-CHLOROBROMOBENZENE;3-BROMOCHLOROBENZENE;3-Chlorobromobenzene;3-BroMochluorobenzene;m-bromophenylchloride;m-chlorophenylbromide
- CBNumber
- CB8720272
- Molecular Formula
- C6H4BrCl
- Formula Weight
- 191.45
- MOL File
- 108-37-2.mol
3-BROMOCHLOROBENZENE Property
- Melting point:
- -21.5 °C
- Boiling point:
- 196 °C(lit.)
- Density
- 1.63 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.576(lit.)
- Flash point:
- 177 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- Liquid
- Specific Gravity
- 1.630
- color
- Clear colorless to light yellow
- Water Solubility
- Insoluble
- BRN
- 1446353
- Dielectric constant
- 4.5
- InChI
- 1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H
- InChIKey
- JRGGUPZKKTVKOV-UHFFFAOYSA-N
- SMILES
- Clc1cccc(Br)c1
- CAS DataBase Reference
- 108-37-2(CAS DataBase Reference)
- NIST Chemistry Reference
- 3-Chlorobromobenzene(108-37-2)
- EPA Substance Registry System
- Benzene, 1-bromo-3-chloro- (108-37-2)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-20/22
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- RTECS
- CY9005000
- Hazard Note
- Irritant
- TSCA
- TSCA listed
- HS Code
- 29039990
- Storage Class
- 10 - Combustible liquids
- Hazard Classifications
- Eye Irrit. 2
Skin Irrit. 2
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 124036
- Product name
- 1-Bromo-3-chlorobenzene
- Purity
- 99%
- Packaging
- 100g
- Price
- $199
- Updated
- 2025/07/31
- Product number
- 124036
- Product name
- 1-Bromo-3-chlorobenzene
- Purity
- 99%
- Packaging
- 25g
- Price
- $59.2
- Updated
- 2023/06/20
- Product number
- B0570
- Product name
- 1-Bromo-3-chlorobenzene
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $30
- Updated
- 2025/07/31
- Product number
- B0570
- Product name
- 1-Bromo-3-chlorobenzene
- Purity
- >99.0%(GC)
- Packaging
- 100g
- Price
- $68
- Updated
- 2025/07/31
- Product number
- B682215
- Product name
- 1-Bromo-3-chlorobenzene
- Packaging
- 100g
- Price
- $250
- Updated
- 2021/12/16
3-BROMOCHLOROBENZENE Chemical Properties,Usage,Production
Chemical Properties
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
Uses
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031
General Description
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Synthesis
Taking m-chloroaniline as raw material, mixed with concentrated hydrobromic acid, make the temperature drop to 0 ??, under stirring, quickly add sodium nitrite aqueous solution, make o-chloroaniline nitrogenation, to produce diazonium salts, in the process of the reaction should be controlled the temperature does not exceed 10 ??. Then use Sandmeyer reaction, add catalyst copper bromide and hydrobromic acid in the reaction system to decompose the diazonium salt, the decomposition reaction is carried out at the boiling temperature, after the reaction is completed, let it stand, take out the organic layer underneath, wash it with water, remove the water by drying and distill it under reduced pressure, m-bromochlorobenzene can be produced.
3-BROMOCHLOROBENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-BROMOCHLOROBENZENE manufacturers
- Product
- 3-BROMOCHLOROBENZENE 108-37-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-07
- Product
- 3-BROMOCHLOROBENZENE 108-37-2
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20tons
- Release date
- 2023-10-13
- Product
- 3-BROMOCHLOROBENZENE 108-37-2
- Price
- US $9.00/KG
- Min. Order
- 1KG
- Purity
- 99.8%
- Supply Ability
- 100tons
- Release date
- 2024-08-22