1-Bromo-3,4-dichlorobenzene

Product Name: 1-Bromo-3,4-dichlorobenzene
CAS No.: 18282-59-2
Chemical Name: 1-Bromo-3,4-dichlorobenzene
Synonyms: 4-BROMO-1,2-DICHLOROBENZENE;4-Bromo-1,2-dichL;1-Bromo-3,4-dichloro;4-DichlorobroMobenzene;3,4-DICHLOROBROMOBENZENE;4-Brom-1,2-dichlorbenzol;3,4-Dichlorophenyl bromide;4-bromo-1,2-dichloro-benzen;1,2-Dichloro-4-bromobenzene;3,4-Dichloro-1-bromobenzene
CBNumber: CB7162237
Molecular Formula: C6H3BrCl2
Formula Weight: 225.9
MOL File: 18282-59-2.mol

More

Less

1-Bromo-3,4-dichlorobenzene Property

Melting point:: 24-25 °C(lit.)
Boiling point:: 124 °C33 mm Hg(lit.)
Density: 1.761 g/mL at 25 °C(lit.)
vapor pressure: 0.6-25Pa at 20-50℃
refractive index: n20/D 1.599(lit.)
Flash point:: 189 °F
storage temp.: Sealed in dry,Room Temperature
form: Liquid After Melting
color: Clear slightly yellow
Water Solubility: insoluble
BRN: 1635735
LogP: 4.3 at 25℃ and pH7
CAS DataBase Reference: 18282-59-2(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 4-bromo-1,2-dichloro-(18282-59-2)
EPA Substance Registry System: Benzene, 4-bromo-1,2-dichloro- (18282-59-2)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39-28A
WGK Germany: 3
TSCA: T
HazardClass: IRRITANT
HS Code: 29039990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 412023
Product name: 4-Bromo-1,2-dichlorobenzene
Purity: 99%
Packaging: 25ml
Price: $205
Updated: 2023/06/20

TCI Chemical

Product number: B0983
Product name: 1-Bromo-3,4-dichlorobenzene
Packaging: 25G
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: B0983
Product name: 1-Bromo-3,4-dichlorobenzene
Packaging: 500G
Price: $401
Updated: 2025/07/31

TCI Chemical

Product number: B0983
Product name: 1-Bromo-3,4-dichlorobenzene
Packaging: 100G
Price: $119
Updated: 2025/07/31

TRC

Product number: B691013
Product name: 1-Bromo-3,4-dichlorobenzene
Packaging: 1g
Price: $55
Updated: 2021/12/16

More

Less

1-Bromo-3,4-dichlorobenzene Chemical Properties,Usage,Production

Chemical Properties

colorless to light yellow liqui

General Description

4-Bromo-1,2-dichlorobenzene participates in the synthesis of N-arylated sultams.

Synthesis

95-50-1

18282-59-2

General procedure for the synthesis of 4-bromo-1,2-dichlorobenzene from o-dichlorobenzene: 26.2 g of 1,2-dichlorobenzene was mixed with 2.75 g of iron powder, heated to 45 °C and 26 g of bromine was added slowly and dropwise at a rate of 0.2 mL/min. The reaction was completed after the dropwise addition process lasted for 2 hours. At the end of the reaction, the reaction was quenched by the addition of sodium sulfite solution and the reaction mixture was extracted with dichloromethane and the solvent was subsequently removed to give 41.6 g of crude product. Compositional analysis of the crude product showed the presence of 5.5% of 1,2-dichlorobenzene, 2.1% of 2,3-dichlorobromobenzene isomers and 0.6% of high-boiling substances (mainly dibrominated or polybrominated products). The unreacted 1,2-dichlorobenzene was recovered by distillation purification by first collecting the 100-110 °C fraction at pressures of -0.09 to -0.1 MPa, followed by collecting the 160-165 °C fraction at the same pressures to give 33.2 g of 4-bromo-1,2-dichlorobenzene with a purity of 98.5% and a molar yield of 90.3%.

References

[1] Patent: CN107915659, 2018, A. Location in patent: Paragraph 0032-0034; 0037-0039; 0042-0044; 0047-0054
[2] Organic and Biomolecular Chemistry, 2003, vol. 1, # 14, p. 2506 - 2511

1-Bromo-3,4-dichlorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

1-Bromo-3,4-dichlorobenzene Suppliers

Americas 1 Belgium 1 Canada 1 China 287 Europe 2 France 2 Germany 7 India 16 Israel 2 Japan 3 Jordan 1 Switzerland 2 Ukraine 1 United Kingdom 16 United States 41 Global 383

Zhejiang Xieshi New Materials Co., Ltd.,

Tel: 15715833231
Email: sales09@xieshichem.com
Country: China
ProdList: 183
Advantage: 58

Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.

Tel: 13396369453 QQ3007939906 18678026865
Fax: 0536-2101172
Email: sdfantai@163.com
Country: China
ProdList: 906
Advantage: 58

Shandong Xibang Biological Technology Development Co. LTD

Tel: 0536-3611186 15063661551
Fax: 0536-3611186
Email: 196056703@qq.com
Country: China
ProdList: 54
Advantage: 58

Weifang Weimeng Chemical Co., Ltd.

Tel: QQ 1340191485 15105445095
Email: weimengchem@163.com
Country: China
ProdList: 482
Advantage: 58

Shanghai Taijilin Industrial Co., Ltd.

Tel: 021-50630626 18964684208
Fax: 021-50563898
Email: kate@tajilin.com
Country: China
ProdList: 1291
Advantage: 58

Yancheng Creator Chemical Co., Ltd.

Tel: 0515-83072966 13016507129
Email: yc@jssdchem.com
Country: China
ProdList: 20
Advantage: 58

Shanghai Boyle Chemical Co., Ltd.

Tel: 021-50182298 021-50180596
Fax: +86-21-57758967
Email: sales@boylechem.com
Country: China
ProdList: 2208
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

future industrial shanghai co., ltd

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: sales@jonln.com
Country: China
ProdList: 1995
Advantage: 65

More

Less

View Lastest Price from 1-Bromo-3,4-dichlorobenzene manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1-Bromo-3,4-dichlorobenzene 18282-59-2
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-Bromo-3,4-dichlorobenzene 18282-59-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-Bromo-3,4-dichlorobenzene 18282-59-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

18282-59-2, 1-Bromo-3,4-dichlorobenzeneRelated Search:

2-Bromofluorobenzene Bromoxynil octanoate 2-Bromobenzonitrile 1,2-Dibromobenzene 3-Bromoanisole 1,2-Dichlorobenzene 1,4-Dichlorobenzene Brompheniramine hydrogen maleate 4-Bromoanisole Brompheniramine BROMO(2-)-4-DICHLOROBENZENE,1-Bromo-2,4-dichlorobenzene, 98+%,1-BROMO-2,4-DICHLOROBENZENE / 2,4-DICHLOROBROMOBENZENE,1-BROMO-2,4-DICHLOROBENZENE 1-BROMO-3,5-DICHLOROBENZENE p-Dichlorobenzene 1-Bromo-4,5-dichloro-2-nitrobenzene 4,6-DIBROMO-2,3-DICHLOROANILINE 1-BROMO-2,4,5-TRICHLOROBENZENE Pigment Green 36 Bromine

4-bromo-1,2-dichloro-benzen

Benzene, 1-bromo-3,4-dichloro-

Benzene,4-bromo-1,2-dichloro-

3,4-DICHLOROBROMOBENZENE

4-BROMO-1,2-DICHLOROBENZENE

1-BROMO-3,4-DICHLOROBENZENE

3,4-Dichloro-1-bromobenzene

4-Bromo-1,2-dichlorobenzene, 98+%

3,4-Dichlorophenyl bromide

1,2-Dichloro-4-bromobenzene

1-Bromo-3,4-dichloro

3,4-Dichlorobromobenzene 98+%

4-DichlorobroMobenzene

1-BroMo-3,4-dichlorobenzene, 98+% 100GR

4-BroMo-1,2-dichlorobenzene, 97+%

1-Bromo-3,4-dichlorobenzene, 98+%

4-Bromo-1,2-dichL

1-Bromo-3,4-dichlorobenzene &gt

1-Bromo-3,4-dichlorobenzene ISO 9001：2015 REACH

4-Brom-1,2-dichlorbenzol

18282-59-2

HALOGEN

Halogenated Hydrocarbons

Organic Building Blocks

Building Blocks

Aryl

C6

Aryl

Halogenated Hydrocarbons

Aromatic Halides (substituted)

Benzene derivates

API intermediates

Bromine Compounds

Chlorine Compounds

bc0001

C6