ChemicalBook > CAS DataBase List > Tetramethylammonium bromide

Tetramethylammonium bromide

Product Name
Tetramethylammonium bromide
CAS No.
64-20-0
Chemical Name
Tetramethylammonium bromide
Synonyms
TMAB;[M4N]Br;Tetramethylammoniumbromid;tetramethyl-ammoniubromide;Ammonium, tetramethyl-, bromide;(dimethylamino)-methymethobromide;n,n,n-trimethyl-methanaminiubromide;Tetramethylammonium Bromide, Reagent;TETRAMETHYLAMMONIUM BROMIDE, FOR IPC;Methyl, (dimethylamino)-, methobromide
CBNumber
CB8256627
Molecular Formula
C4H12BrN
Formula Weight
154.05
MOL File
64-20-0.mol
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Tetramethylammonium bromide Property

Melting point:
>300 °C (lit.)
Boiling point:
>360°C
Density 
1,56 g/cm3
refractive index 
1.4379 (estimate)
storage temp. 
Store below +30°C.
solubility 
H2O: 0.1 g/mL, clear, colorless
form 
Crystalline Powder
color 
Slightly gray
Odor
Odorless
PH
5.5-6.5 (100g/l, H2O)
Water Solubility 
soluble
Sensitive 
Hygroscopic
λmax
λ: 240 nm Amax: 0.06
λ: 250 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02
BRN 
3620955
CAS DataBase Reference
64-20-0(CAS DataBase Reference)
NIST Chemistry Reference
Tetramethylammonium bromide(64-20-0)
EPA Substance Registry System
Methanaminium, N,N,N-trimethyl-, bromide (64-20-0)
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Safety

Hazard Codes 
T
Risk Statements 
25-36/37/38
Safety Statements 
26-28-36-45-37/39-28A
RIDADR 
UN 2811 6.1/PG 2
WGK Germany 
3
RTECS 
BS7600000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29239000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H300Fatal if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
195758
Product name
Tetramethylammonium bromide
Purity
98%
Packaging
100g
Price
$36.2
Updated
2024/03/01
Sigma-Aldrich
Product number
195758
Product name
Tetramethylammonium bromide
Purity
98%
Packaging
500g
Price
$130
Updated
2024/03/01
TCI Chemical
Product number
T0135
Product name
Tetramethylammonium Bromide
Purity
>97.0%(T)
Packaging
25g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
T0135
Product name
Tetramethylammonium Bromide
Purity
>97.0%(T)
Packaging
500g
Price
$77
Updated
2024/03/01
Alfa Aesar
Product number
A13368
Product name
Tetramethylammonium bromide
Purity
98%
Packaging
100g
Price
$38.8
Updated
2024/03/01
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Tetramethylammonium bromide Chemical Properties,Usage,Production

Chemical Properties

SLIGHTLY GREY CRYSTALLINE POWDER

Uses

Tetramethylammonium bromide acts as an ion pair reagent. It is used as a surface-active agent and an active ingredient for conditioners. Further, it is used as a softner for textiles and paper products. It is also employed as a disinfection agent, sanitizer, antimicrobial and antistatic agent. In addition to this, it plays in important role as a phase transfer catalyst in synthetic chemistry.

Uses

Tetrabutylammonium bromide (TBAB) may be used in the molten state in the following processes:

  • Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.
  • Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.
  • Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.
  • Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.
  • Catalyze the addition of thiols to conjugated alkenes.
  • Dehydrochlorination of poly(vinyl chloride).

Definition

ChEBI: The bromide salt of tetramethylammonium.

General Description

Tetrabutylammonium bromide is a quaternary ammonium compound that is widely used as a phase transfer catalyst. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.

Purification Methods

Crystallise the bromide from EtOH, EtOH/diethyl ether, MeOH/acetone, water or from acetone/MeOH (4:1) by adding an equal volume of acetone. It is dried at 110o under reduced pressure or at 140o for 24hours. [Beilstein 4 IV 145.]

Tetramethylammonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tetramethylammonium bromide manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetramethylammonium bromide 64-20-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Yanxi Chemical Co., Ltd.
Product
Tetramethylammonium bromide 64-20-0
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
5 tons
Release date
2023-10-23
Hebei Weibang Biotechnology Co., Ltd
Product
Tetramethylammonium bromide 64-20-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24

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