3-BENZYLOXYBENZYL BROMIDE
- Product Name
- 3-BENZYLOXYBENZYL BROMIDE
- CAS No.
- 1700-31-8
- Chemical Name
- 3-BENZYLOXYBENZYL BROMIDE
- Synonyms
- 1-(Benzyloxy)-3-(bromomethyl)benzene;3-BENZYLOXYBENZYL BR;-Benzyloxybenzyl bromide;3-BENZYLOXYBENZYL BROMIDE;1700-31-8---3-BENZYLOXYBENZYL BROMIDE;Benzene, 1-(bromomethyl)-3-(phenylmethoxy)-
- CBNumber
- CB8262334
- Molecular Formula
- C14H13BrO
- Formula Weight
- 277.16
- MOL File
- 1700-31-8.mol
3-BENZYLOXYBENZYL BROMIDE Property
- Melting point:
- 54-55 °C
- Boiling point:
- 365.6±22.0 °C(Predicted)
- Density
- 1.361±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder to crystal
- color
- White to Orange to Green
- InChI
- InChI=1S/C14H13BrO/c15-10-13-7-4-8-14(9-13)16-11-12-5-2-1-3-6-12/h1-9H,10-11H2
- InChIKey
- ITJWNXBZSFIJTP-UHFFFAOYSA-N
- SMILES
- C1(CBr)=CC=CC(OCC2=CC=CC=C2)=C1
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B5708
- Product name
- 3-(Benzyloxy)benzyl Bromide
- Packaging
- 1G
- Price
- $146
- Updated
- 2024/03/01
- Product number
- B5708
- Product name
- 3-(Benzyloxy)benzyl Bromide
- Packaging
- 5G
- Price
- $497
- Updated
- 2024/03/01
- Product number
- B291395
- Product name
- 3-(Benzyloxy)benzyl Bromide
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB150775
- Product name
- 3-(Benzyloxy)benzyl Bromide
- Packaging
- 100mg
- Price
- $79
- Updated
- 2021/12/16
- Product number
- OR400465
- Product name
- 3-(Benzyloxy)benzyl Bromide
- Packaging
- 1g
- Price
- $24
- Updated
- 2021/12/16
3-BENZYLOXYBENZYL BROMIDE Chemical Properties,Usage,Production
Synthesis
1700-30-7
1700-31-8
Synthesis of compound 172 (3-benzyloxybenzyl bromide): 3-benzyloxybenzyl alcohol (3.0 g, 14.0 mmol) was dissolved in anhydrous ethyl ether (50 mL) under nitrogen protection and cooled in an ice bath to 0°C. Subsequently, phosphorus tribromide (0.66 mL, 7.0 mmol) was added dropwise (0.66 mL, 7.0 mmol), and after completion of the dropwise addition the ice bath was removed, and the mixture was gradually allowed to come to room temperature and stirred for 3 hours. The reaction mixture was gradually warmed to room temperature and stirred for 3 hours. After the reaction was completed, the mixture was diluted with ether (60 mL) and washed with deionized water (2 × 40 mL), saturated sodium bicarbonate solution (2 × 40 mL) and saturated saline (2 × 40 mL). The organic layer was dried over anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent to give 3-benzyloxybenzyl bromide (3.76 g, 97% yield) as a light yellow solid.
References
[1] Patent: US2003/186943, 2003, A1
[2] Patent: US6458829, 2002, B1
[3] Patent: US6770658, 2004, B2
[4] Journal of Organic Chemistry, 2011, vol. 76, # 16, p. 6703 - 6714
[5] Journal of Organic Chemistry, 1997, vol. 62, # 19, p. 6690 - 6691
3-BENZYLOXYBENZYL BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-BENZYLOXYBENZYL BROMIDE manufacturers
- Product
- 3-BENZYLOXYBENZYL BROMIDE 1700-31-8
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-07-19
- Product
- 3-BENZYLOXYBENZYL BROMIDE 1700-31-8
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2025-03-07
- Product
- 3-Benzyloxybenzyl bromide 1700-31-8
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-06-04