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3-BENZYLOXYBENZYL BROMIDE

Product Name
3-BENZYLOXYBENZYL BROMIDE
CAS No.
1700-31-8
Chemical Name
3-BENZYLOXYBENZYL BROMIDE
Synonyms
1-(Benzyloxy)-3-(bromomethyl)benzene;3-BENZYLOXYBENZYL BR;-Benzyloxybenzyl bromide;3-BENZYLOXYBENZYL BROMIDE;1700-31-8---3-BENZYLOXYBENZYL BROMIDE;Benzene, 1-(bromomethyl)-3-(phenylmethoxy)-
CBNumber
CB8262334
Molecular Formula
C14H13BrO
Formula Weight
277.16
MOL File
1700-31-8.mol
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3-BENZYLOXYBENZYL BROMIDE Property

Melting point:
54-55 °C
Boiling point:
365.6±22.0 °C(Predicted)
Density 
1.361±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
powder to crystal
color 
White to Orange to Green
InChI
InChI=1S/C14H13BrO/c15-10-13-7-4-8-14(9-13)16-11-12-5-2-1-3-6-12/h1-9H,10-11H2
InChIKey
ITJWNXBZSFIJTP-UHFFFAOYSA-N
SMILES
C1(CBr)=CC=CC(OCC2=CC=CC=C2)=C1
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5708
Product name
3-(Benzyloxy)benzyl Bromide
Packaging
1G
Price
$146
Updated
2024/03/01
TCI Chemical
Product number
B5708
Product name
3-(Benzyloxy)benzyl Bromide
Packaging
5G
Price
$497
Updated
2024/03/01
TRC
Product number
B291395
Product name
3-(Benzyloxy)benzyl Bromide
Packaging
1g
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB150775
Product name
3-(Benzyloxy)benzyl Bromide
Packaging
100mg
Price
$79
Updated
2021/12/16
Apolloscientific
Product number
OR400465
Product name
3-(Benzyloxy)benzyl Bromide
Packaging
1g
Price
$24
Updated
2021/12/16
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3-BENZYLOXYBENZYL BROMIDE Chemical Properties,Usage,Production

Synthesis

1700-30-7

1700-31-8

Synthesis of compound 172 (3-benzyloxybenzyl bromide): 3-benzyloxybenzyl alcohol (3.0 g, 14.0 mmol) was dissolved in anhydrous ethyl ether (50 mL) under nitrogen protection and cooled in an ice bath to 0°C. Subsequently, phosphorus tribromide (0.66 mL, 7.0 mmol) was added dropwise (0.66 mL, 7.0 mmol), and after completion of the dropwise addition the ice bath was removed, and the mixture was gradually allowed to come to room temperature and stirred for 3 hours. The reaction mixture was gradually warmed to room temperature and stirred for 3 hours. After the reaction was completed, the mixture was diluted with ether (60 mL) and washed with deionized water (2 × 40 mL), saturated sodium bicarbonate solution (2 × 40 mL) and saturated saline (2 × 40 mL). The organic layer was dried over anhydrous magnesium sulfate and concentrated under reduced pressure to remove the solvent to give 3-benzyloxybenzyl bromide (3.76 g, 97% yield) as a light yellow solid.

References

[1] Patent: US2003/186943, 2003, A1
[2] Patent: US6458829, 2002, B1
[3] Patent: US6770658, 2004, B2
[4] Journal of Organic Chemistry, 2011, vol. 76, # 16, p. 6703 - 6714
[5] Journal of Organic Chemistry, 1997, vol. 62, # 19, p. 6690 - 6691

3-BENZYLOXYBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BENZYLOXYBENZYL BROMIDE Suppliers

Americas 1 China 107 Europe 1 Germany 2 India 5 Japan 1 United Kingdom 3 United States 12 Global 132
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from 3-BENZYLOXYBENZYL BROMIDE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
3-BENZYLOXYBENZYL BROMIDE 1700-31-8
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-07-19
Hebei Chuanghai Biotechnology Co., Ltd
Product
3-BENZYLOXYBENZYL BROMIDE 1700-31-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2025-03-07
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
3-Benzyloxybenzyl bromide 1700-31-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-06-04

1700-31-8, 3-BENZYLOXYBENZYL BROMIDERelated Search:

BENZYLOXYACETALDEHYDE BENZOYL BROMIDE 4-BENZYLOXYBENZYL BROMIDE POLYSTYRENE (100-200 MESH, 0.5-1.3 MMOL/G) 2-BENZYLOXYBENZYLBROMIDE 4-Benzyloxybenzyl bromide polystyrene (100-200 mesh, 0.5-1.3 mmol JANDAJEL(TM)-4-BENZYLOXYBENZYL BROMIDE 4-BENZYLOXYBENZYL BROMIDE 3,5-BIS[3,5-BIS(BENZYLOXY)BENZYLOXY]BENZYL BROMIDE 2-(BENZYLOXY)-4-(BROMOMETHYL)-1-METHOXYBENZENE 3,5-BIS(BENZYLOXY)BENZYL BROMIDE 3-(BROMOMETHYL)PHENYL BENZOATE 3,5-BIS(3,5-DIMETHOXYBENZYLOXY)BENZYL BROMIDE 3-BENZYLOXYBENZYL BROMIDE

  • 3-BENZYLOXYBENZYL BROMIDE
  • 1-(Benzyloxy)-3-(bromomethyl)benzene
  • 3-BENZYLOXYBENZYL BR
  • Benzene, 1-(bromomethyl)-3-(phenylmethoxy)-
  • 1700-31-8---3-BENZYLOXYBENZYL BROMIDE
  • -Benzyloxybenzyl bromide
  • 1700-31-8
  • ALKYL HALIDE
  • pharmacetical