ChemicalBook > CAS DataBase List > 5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE

5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE

Product Name
5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE
CAS No.
53051-97-1
Chemical Name
5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE
Synonyms
AKOS BB-9240;AKOS BBS-00002729;TIMTEC-BB SBB005653;2-AMINO-5,6-DIHYDRO-4H-CYCLOPENTATHIAZOLE;4H-Cyclopentathiazol-2-amine, 5,6-dihydro-;4H,5H,6H-cyclopenta[d][1,3]thiazol-2-amine;5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE;5,6-DIHYDRO-4H-CYCLOPENTA[D]THIAZOL-2-AMINE;2-Amino-5,6-dihydro-4H-cyclopenta[d]thiazole;5,6-Dihydro-4H-cyclopentathiazol-2-ylaMinehydrobroMide
CBNumber
CB8269924
Molecular Formula
C6H8N2S
Formula Weight
140.21
MOL File
53051-97-1.mol
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5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE Property

Melting point:
96-99°C
Boiling point:
295.5±9.0 °C(Predicted)
Density 
1.354±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
6.02±0.20(Predicted)
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
H326313
Product name
4H,5H,6H-Cyclopenta[d][1,3]thiazol-2-amineHydrobromide
Packaging
100mg
Price
$65
Updated
2021/12/16
SynQuest Laboratories
Product number
7H70-1-3G
Product name
5,6-Dihydro-4H-cyclopenta[d]thiazol-2-amine
Packaging
5G
Price
$695
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0012508
Product name
5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE
Purity
95.00%
Packaging
1G
Price
$812.54
Updated
2021/12/16
SynQuest Laboratories
Product number
7H70-1-3G
Product name
5,6-Dihydro-4H-cyclopenta[d]thiazol-2-amine
Packaging
1g
Price
$175
Updated
2021/12/16
AK Scientific
Product number
7512AB
Product name
5,6-Dihydro-4H-cyclopenta[d]thiazol-2-amine
Packaging
1g
Price
$201
Updated
2021/12/16
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5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE Chemical Properties,Usage,Production

Synthesis

82514-58-7

53051-97-1

General procedure for the synthesis of 5,6-dihydro-4H-cyclopentathiazol-2-amines from 2-amino-5,6-dihydro-4H-cyclopentathiazole hydrochloride: 1. 2-Amino-5,6-dihydro-4H-cyclopentathiazole hydrochloride (16.5 g, 93 mmol) was added to a mixture of aqueous sodium bicarbonate (16.5 g dissolved in 250 mL of water) and 25% THF/EtOAc (160 mL, v/v). 2. The reaction mixture was stirred at room temperature for 15 minutes. 3. The mixture was filtered through a diatomaceous earth pad to clarify the mixture. 4. The organic layer was separated and dried over anhydrous magnesium sulfate and subsequently concentrated under vacuum to 47 g. The mixture was purified by adding toluene (100 mL). 5. Toluene (100 mL) was added and the mixture was again concentrated to 45 g under vacuum. 6. the mixture was diluted with heptane (40 mL), cooled and the product was collected by filtration and dried to afford 5,6-dihydro-4H-cyclopentathiazol-2-amine as the free base (10.75 g, 85% yield). Product characterization data: 1H NMR (CD3OD) δ 4.88 (2H, s), 2.75-2.70 (2H, m), 2.60-2.55 (2H, m), 2.39-2.33 (2H, m).

References

[1] Patent: US2007/149499, 2007, A1. Location in patent: Page/Page column 19

5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE Suppliers

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View Lastest Price from 5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE manufacturers

Career Henan Chemical Co
Product
5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE 53051-97-1
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-14

53051-97-1, 5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINERelated Search:


  • 5,6-DIHYDRO-4H-CYCLOPENTATHIAZOL-2-YLAMINE
  • AKOS BB-9240
  • AKOS BBS-00002729
  • TIMTEC-BB SBB005653
  • 5,6-Dihydro-4H-cyclopentathiazol-2-ylaMinehydrobroMide
  • 5,6-dihydro-4H-cyclopenta[d]thiazol-2-aMine hydrobroMide
  • 5,6-DIHYDRO-4H-CYCLOPENTA[D]THIAZOL-2-AMINE
  • 2-Amino-5,6-dihydro-4H-cyclopenta[d]thiazole
  • 2-AMINO-5,6-DIHYDRO-4H-CYCLOPENTATHIAZOLE
  • 4H,5H,6H-cyclopenta[d][1,3]thiazol-2-amine
  • 4H-Cyclopentathiazol-2-amine, 5,6-dihydro-
  • 53051-97-1