FMoc-α-Me-Lys(Boc)-OH

Product Name: FMoc-α-Me-Lys(Boc)-OH
CAS No.: 1202003-49-3
Chemical Name: FMoc-α-Me-Lys(Boc)-OH
Synonyms: (S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-6-((tert-butoxycarbonyl)amino)-2-methylhexanoic acid;Fmoc-a-Me-Lys(Boc)-OH;Fmoc-α-Me-Lys(Boc)-OH;Fmoc-alpha-Me-Lys(Boc)-OH;Fmoc-alpha-Me-L-Lys(Boc)-OH;Fmoc-α-methyl-L-Lysine(Boc);FMoc-α-Me-Lys(Boc)-OH USP/EP/BP;N6-Boc-N2-Fmoc-alfa-Me--L-Lys-OH;N6-Boc-N2-Fmoc-2-methyl-L-Lysine;(S)-Na-Fmoc-NW-Boc-α-Methyllysine
CBNumber: CB82729321
Molecular Formula: C27H34N2O6
Formula Weight: 482.57
MOL File: 1202003-49-3.mol

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FMoc-α-Me-Lys(Boc)-OH Property

Boiling point:: 687.9±55.0 °C(Predicted)
Density: 1.196±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 3.92±0.41(Predicted)
form: powder
color: white
InChI: InChI=1S/C27H34N2O6/c1-26(2,3)35-24(32)28-16-10-9-15-27(4,23(30)31)29-25(33)34-17-22-20-13-7-5-11-18(20)19-12-6-8-14-21(19)22/h5-8,11-14,22H,9-10,15-17H2,1-4H3,(H,28,32)(H,29,33)(H,30,31)/t27-/m0/s1
InChIKey: MYQXEVZHWDILHG-MHZLTWQESA-N
SMILES: C(O)(=O)[C@](C)(CCCCNC(OC(C)(C)C)=O)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-40-67
Safety Statements: 23-24/25-36/37
TSCA: No

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P281Use personal protective equipment as required.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: F647540
Product name: (S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-6-((tert-butoxycarbonyl)amino)-2-methylhexanoicAcid
Packaging: 10mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: 0415AP
Product name: Fmoc-alpha-Me-Lys(Boc)-OH
Packaging: 25mg
Price: $95
Updated: 2021/12/16

ChemSupplyAustralia

Product number: 300598
Product name: (S)-Nα-Fmoc-Nω-Boc-α-Methyllysine, 98%
Packaging: 100mg
Price: $121
Updated: 2021/12/16

Activate Scientific

Product number: AS115441
Product name: (S)-Na-Fmoc-Nw-Boc-alpha-methyllysine
Purity: 97+% ee
Packaging: 100mg
Price: $194
Updated: 2021/12/16

AK Scientific

Product number: 0415AP
Product name: Fmoc-alpha-Me-Lys(Boc)-OH
Packaging: 100mg
Price: $217
Updated: 2021/12/16

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FMoc-α-Me-Lys(Boc)-OH Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder.

Uses

(S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-6-((tert-butoxycarbonyl)amino)-2-methylhexanoic acid is a reagent in the preparation/biological evaluation of a vapreotide analogs containing (S)?-?α-?methyl-?lysine.

Synthesis

Benzyl (2R,3S)-(?)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate (4) was successively alkylated with methyl iodide and 1,4-diiodobutane using a base. In each alkylation step anti-alkylated product formed exclusively. The iodo group was displaced with azide, which served as a precursor for the side-chain amino function. Catalytic hydrogenation with concomitant cleavage of the chiral auxiliary afforded (L)-α-Me-Lys-OH (9) in a total of four steps in good yield. (L)-Fmoc-α-Me-Lys(Boc)-OH (16) was obtained from 9 via regioselective benzyloxycarbonylation. Alternately, (L)-Fmoc-α-Me-Lys(Boc)-OH (16) was obtained via Staudinger reduction of azide (8) in a total of six steps in good yield.

FMoc-α-Me-Lys(Boc)-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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FMoc-α-Me-Lys(Boc)-OH Suppliers

China 90 Germany 1 India 1 Japan 1 United States 3 Global 96

Shanghai GL Peptide Ltd.

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ChemPep, Inc.

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Hunan Hui Bai Shi Biotechnology Co., Ltd.

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View Lastest Price from FMoc-α-Me-Lys(Boc)-OH manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: FMoc-α-Me-Lys(Boc)-OH 1202003-49-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-10-08

1202003-49-3, FMoc-α-Me-Lys(Boc)-OHRelated Search:

Fmoc-α-Me-L-Dab(Boc)-OH Fmoc-α-Me-homoPhe-OH FMoc-α-Me-Trp(Boc)-OH (R)-N-FMoc-2-(6'-heptenyl)alanine (S)-N-FMoc-2-(2'--propynyl)alanine (S)-N-Fmoc-2-(3'-butenyl)alanine FMoc-α-Me-D-Pro-OH FMoc-α-Me-Asp(OtBu)-OH (S)-N-FMoc-2-(5'-pentenyl)alanine (S)-N-FMoc-2-(6'-heptenyl)alanine (S)-N-Fmoc-2-(2'-propylenyl)alanine FMoc-α-Me-D-Phe(2-F)-OH FMoc-α-Me-D-Orn(Boc)-OH Fmoc-α-methyl-L-Leucine FMOC-ALPHA-METHYL-L-PHE FMoc-α-Me-D-Lys(Boc)-OH FMoc-α-Me-Orn(Boc)-OH Fmoc-alpha-methyl-D-leucine

(S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-6-((tert-butoxycarbonyl)amino)-2-methylhexanoic acid

N6-[(1,1-Dimethylethoxy)carbonyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-2-methyl-L-lysine

(S)-N-ALPHA-FMOC-N-EPSILON-BOC-ALPHA-METHYLLYSINE

(S)-NΑ-FMOC-NΩ-BOC-Α-METHYLLYSINE

(S)-Na-Fmoc-NW-Boc-α-Methyllysine

Fmoc-alpha-Me-L-Lys(Boc)-OH

(2S)-6-{[(tert-butoxy)carbonyl]amino}-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylhexanoic acid

(9H-Fluoren-9-yl)MethOxy]Carbonyl Alpha-Methyl-Lys(Boc)-OH

N6-Boc-N2-Fmoc-alfa-Me--L-Lys-OH

(S)-N-ALPHA-FMOC-N-EPSILON-BOC-ALPHA-METHYLLYSINE, >97%

Fmoc-a-Me-Lys(Boc)-OH

Fmoc-α-methyl-L-Lysine(Boc)

(S)-Na-Fmoc-Nw-Boc-A-Methyllysine

Fmoc-alpha-Me-Lys(Boc)-OH

L-Lysine, N6-[(1,1-dimethylethoxy)carbonyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-2-methyl-

N6-Boc-N2-Fmoc-2-methyl-L-Lysine

Fmoc-α-Me-Lys(Boc)-OH

FMoc-α-Me-Lys(Boc)-OH USP/EP/BP

N-α-(9-Fluorenylmethoxycarbonyl)-N-ε-(t-butoxycarbonyl)-α-methyl-L-lysine

(S)-Na-Fmoc-NW-Boc-α-Methyllysine

1202003-49-3

1202003-41-3

α-Methyl Amino Acids