2-Acetonaphthone

Product Name: 2-Acetonaphthone
CAS No.: 93-08-3
Chemical Name: 2-Acetonaphthone
Synonyms: ORANGE II;2-ACETYLNAPHTHALENE;Acetonaphthone;METHYL NAPHTHYL KETONE;ORANGE 2;ACID ORANGE II;ORANGER CRYSTALS;Methyl β-naphthyl ketone;FEMA 2723;2-ACETYLNAPHTHONE
CBNumber: CB8272988
Molecular Formula: C12H10O
Formula Weight: 170.21
MOL File: 93-08-3.mol

More

Less

2-Acetonaphthone Property

Melting point:: 52-56 °C (lit.)
Boiling point:: 300-301 °C (lit.)
Density: 1.12 g/mL at 25 °C(lit.)
vapor pressure: 0.12Pa at 25℃
refractive index: n20/D 1.628(lit.)
FEMA: 2723 | METHYL BETA-NAPHTHYL KETONE
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
solubility: 0.272g/l
form: Fine Crystalline Powder and Chunks
pka: 0[at 20 ℃]
color: White
Odor: orange-blossom odor
Odor Type: floral
Water Solubility: insoluble
JECFA Number: 811
BRN: 774965
LogP: 2.678 at 25℃
CAS DataBase Reference: 93-08-3(CAS DataBase Reference)
NIST Chemistry Reference: 2-Naphthyl methyl ketone(93-08-3)
EPA Substance Registry System: 2'-Acetonaphthone (93-08-3)

More

Less

Safety

Hazard Codes: Xn,Xi,N
Risk Statements: 36/37/38-51/53-22-20/21/22
Safety Statements: 26-36-61-24/25-22-36/37
RIDADR: UN3077
WGK Germany: 3
RTECS: DB7084000
Hazard Note: Irritant
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 29143900
Toxicity: skn-hmn 100% FCTXAV 13,867,75

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W272302
Product name: Methyl β-naphthyl ketone
Purity: ≥99%,FCC,FG
Packaging: 1kg
Price: $160
Updated: 2024/03/01

Sigma-Aldrich

Product number: 134775
Product name: 2-Acetonaphthone
Purity: 99%
Packaging: 5g
Price: $137
Updated: 2024/03/01

Sigma-Aldrich

Product number: 134775
Product name: 2-Acetonaphthone
Purity: 99%
Packaging: 100g
Price: $260
Updated: 2024/03/01

Sigma-Aldrich

Product number: W272302
Product name: Methyl β-naphthyl ketone
Purity: ≥99%,FCC,FG
Packaging: 100g
Price: $76.5
Updated: 2023/06/20

TCI Chemical

Product number: A0053
Product name: 2'-Acetonaphthone
Purity: >98.0%(GC)
Packaging: 25g
Price: $23
Updated: 2024/03/01

More

Less

2-Acetonaphthone Chemical Properties,Usage,Production

Chemical Properties

2-Acetonaphthone smells similar to orange blossomand is a colorless crystalline solid (mp 56 °C). It is usually prepared by Friedel–Crafts acetylation of naphthalene (with acetyl chloride, acetic anhydride, etc.) in the presence of aluminumchloride. In polar solvents (e.g., nitrobenzene), the percentage of the simultaneously formed ??-isomer is lower. Methyl 2-naphthyl ketone is used in eau de cologne, soap perfumes, and detergents. It is a good fixative.

Physical properties

Methyl β-napthyl ketone has a floral, neroli odor suggestive of orange blossom and a strawberry-like flavor.

Uses

2-Acetonaphthone was used in direct time-resolved studies on singlet molecular oxygen phosphorescence in heterogeneous silica gel/cyclohexane systems.

Uses

2-Acetonaphthone is a flavoring agent that is a crystalline solid (white or nearly white) with orange blossom-like odor. It is soluble in most fixed oils, slightly soluble in mineral oil and propylene glycol, and insoluble in glycerin. It is obtained by chemical synthesis.

Preparation

2-Acetonaphthone may be prepared by Friedel-Crafts reaction of naphthalene, acetyl chloride and AlCl3.

Definition

ChEBI: 2-acetylnaphthalene is a naphthyl ketone that is naphthalene substituted at position 2 by an acetyl group.

Synthesis Reference(s)

Journal of the American Chemical Society, 99, p. 3101, 1977 DOI: 10.1021/ja00451a041
The Journal of Organic Chemistry, 55, p. 319, 1990 DOI: 10.1021/jo00288a054
Tetrahedron Letters, 19, p. 147, 1978 DOI: 10.1016/S0040-4039(01)85068-1

General Description

2-Acetonaphthone undergoes efficient photoreduction in the presence of tri-n-butylstannane as hydrogen donor. It is solubilized in air-saturated sodium dodecyl sulphate micelles in D₂O or H₂O by pulsed nitrogen laser photolysis for triplet sensitized production of singlet oxygen.

Flammability and Explosibility

Not classified

Biochem/physiol Actions

Odor at 1.0%

Safety Profile

Moderately toxic by ingestion. A human skin irritant. Flammable liquid. When heated to decomposition it emits acrid smoke and fumes

Purification Methods

Separate it from the 1-isomer by fractional crystallisation of the picrate in EtOH (see entry for the 1-isomer above) to m 82o. Decomposition of the picrate with dilute NaOH and extraction with Et2O, then evaporation, give purer 2-acetylnaphthalene. If this residue solidifies, it can be recrystallised from pet ether, EtOH or acetic acid; otherwise it should be distilled in a vacuum and the solid distillate is recrystallised [Gorman & Rodgers J Am Chem Soc 108 5074 1986, Levanon et al. J Phys Chem 91 14 1987]. Purity should be checked by high field NMR spectroscopy. Its oxime has m 145o(dec), and the semicarbazone has m 235o. [Stobbe & Lenzer Justus Liebigs Ann Chem 380 95 1911, Raffauf J Am Chem Soc 72 753 1950, Hunsberger J Am Chem Soc 72 5626 1950, Immediata & Day J Org Chem 5 512 1940, Beilstein 7 IV 1294.]

2-Acetonaphthone Preparation Products And Raw materials

Raw materials

Aluminum chloride

Preparation Products

2-(2-NAPHTHYL)-1H-INDOLE-3-CARBALDEHYDE

More

Less

2-Acetonaphthone Suppliers

Americas 1 Australia 1 Belgium 4 Canada 1 China 255 Czech Republic 1 Europe 3 France 2 Germany 18 India 44 Italy 2 Japan 8 Singapore 2 Slovakia 1 South Korea 1 Spain 2 Switzerland 3 The Netherlands 2 Ukraine 2 United Kingdom 16 United States 86 Global 455

Suzhou Laing Biological Technology Co., LTD

Tel: 0512-62968256 18550502935
Fax: 0512-62968256
Email: export@laingbiotec.com
Country: China
ProdList: 1037
Advantage: 58

Lu'an Jianuo Biochemical Technology Co., Ltd.

Tel: 0564-3619988 18056418988
Fax: 0564-3619988
Email: 549945567@qq.com
Country: China
ProdList: 89
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3576
Advantage: 66

Shandong Xingshun New Material Co., Ltd.

Tel: 0519-86464994 13382824994;
Fax: 86-519-86463703
Email: gxy@xingshengtech.com
Country: China
ProdList: 100
Advantage: 65

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18217
Advantage: 66

More

Less

View Lastest Price from 2-Acetonaphthone manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 2-Acetonaphthone 93-08-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-25

Hebei Mojin Biotechnology Co., Ltd

Product: 2-Acetonaphthone 93-08-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-28

Hebei Guanlang Biotechnology Co,.LTD

Product: 2-Acetonaphthone 93-08-3
Price: US $19.00/KG
Min. Order: 1KG
Purity: 99.%
Supply Ability: 50 ton
Release date: 2022-01-11

93-08-3, 2-AcetonaphthoneRelated Search:

1-Tetralone Methyl acrylate Basic Violet 1 Acetonitrile Methylparaben 1-(1-NAPHTHYL)-2-THIOUREA PIPERACETAZINE (250 MG) beta-Tetralone Methanol Kresoxim-methyl Nabumetone 1'-Acetonaphthone Methyl 2-Acetyl-6-methoxynaphthalene 1,2,3,4-Tetrahydro-1,1,3,4,4,6-hexamethyl-7-acetylnaphthalene 2'-HYDROXY-1'-ACETONAPHTHONE,2-HYDROXY-1-ACETONAPHTHONE,1'-Acetonaphthone, 2'-hydroxy- 2-Imidazolyl-2'-acetonaphthone 6'-METHYL-2'-ACETONAPHTHONE

METHYL NAPHTHYL KETONE

B-NAPHTHYL METHYL KETONE

BETA'-ACETONAPHTHONE

BETA-ACETYLNAPHTHALENE

METHYL 2-NAPHTHYL KETONE

METHYL-A-NAPHTHYL KETONE

METHYL-ALPHA-NAPHTHYL KETONE

METHYL-B-NAPHTHYL KETONE

METHYL BETA-NAPHTHYL KETONE

MANDARIN G

LABOTEST-BB LT00847536

LABOTEST-BB LT02085122

BETA-NAPHTHYLMETHYLKETONE

FEMA 2723

ERIO ORANGE II

CI NO 5510

CI NO 15510

D AND C ORANGE NO 4

1-(2-naphthalenyl)-Ethanone

1-naphthalen-2-yl-ethanone

2-Acetylnaphtyalene

Acetonaphthone

beta-Acetonaphthalene

beta-Methyl naphthyl ketone

beta-methylnaphthylketone

Ethanone, 1-(2-naphthalenyl)-

2-Acetonaphthone99%

2-Acetylnaphtalene, 99%

2-Acetonaphthone=2-Acetylnaphthalene

2-Acetylnaphthalene,99%

β-Acetonaphthylene

2-Acetyl Naphthalene(2-Acetonaphthone, Methyl 2-Naphthyl Ketone)

2-ACETYLNAPHTHALIN

SS''-ACETONAPHTTHONE

METHYL NAPHTHYL KETONE, CRYSTALS

METHYL-B-NAPTHYL KETONE

Acid Orange 2

2μ-Acetonaphthone, 2-Acetonaphthone, 2-Acetylnaphthalene, Methyl 2-naphthyl ketone

1-(2-Naphtyl)ethanone

Methyl(2-naphtyl) ketone

Methyl β-naphthyl ketone,2′-Acetonaphthone, 2-Acetonaphthone, 2-Acetylnaphthalene, Methyl 2-naphthyl ketone

α-naphthyl ketone

2-Acetylnaphthalene, (Naphth-2-yl)ethan-1-one

Methyl 2-naphth ketone

2-Acetylnaphthalene for synthesis

1-(2-NAPHTHYL)ETHAN-1-ONE

1-(2-NAPHTHYL)ETHANONE

2-ACETONAPHTHANONE

2'-ACETONAPHTHONE

2-ACETONAPHTHONE

2-ACETYLNAPHTHALENE

2-ACETYLNAPHTHONE

2-NAPHTHYL METHYL KETONE

1-NAPHTHYL METHYL KETONE

RALU(R)PLATE MNK

ORANGE 2

ORANGE A

ORANGE EXTRA