ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE

Product Name: ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE
CAS No.: 138907-68-3
Chemical Name: ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE
Synonyms: AKOS BBS-00007066;BUTTPARK 23\09-43;TIMTEC-BB SBB000884;SALOR-INT L251488-1EA;ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE;ETHYL 5-AMINO-1-(4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLATE;5-AMINO-1-(4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER;1H-Pyrazole-4-carboxylic acid, 5-amino-1-(4-fluorophenyl)-, ethyl ester;5-Amino-4-(ethoxycarbonyl)-1-(4-fluorophenyl)-1H-pyrazole, 1-[5-Amino-4-(ethoxycarbonyl)-1H-pyrazol-1-yl]-4-fluorobenzene
CBNumber: CB8273208
Molecular Formula: C12H12FN3O2
Formula Weight: 249.24
MOL File: 138907-68-3.mol

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ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE Property

Melting point:: 153 °C
Boiling point:: 380.0±32.0 °C(Predicted)
Density: 1.33±0.1 g/cm3(Predicted)
storage temp.: 2-8°C, protect from light
pka: 0.99±0.14(Predicted)
Appearance: Off-white to light yellow Solid
CAS DataBase Reference: 138907-68-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
Hazard Note: Irritant
HS Code: 2933199090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B433775
Product name: Ethyl5-Amino-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 004512
Product name: Ethyl 5-amino-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate
Packaging: 1g
Price: $12
Updated: 2021/12/16

Apolloscientific

Product number: PC0837
Product name: Ethyl5-amino-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate
Packaging: 1g
Price: $53
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H58-3-X0
Product name: Ethyl 5-amino-1-(4-fluorophenyl)pyrazole-4-carboxylate
Packaging: 1g
Price: $58
Updated: 2021/12/16

AK Scientific

Product number: Y1233
Product name: Ethyl5-amino-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate
Packaging: 1g
Price: $85
Updated: 2021/12/16

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ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

94-05-3

138907-68-3

The general procedure for the synthesis of ethyl 5-amino-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate from ethyl ethoxymethylcyanoacetate was as follows: 11.38 g (70.0 mmol) of 4-fluorophenylhydrazine hydrochloride, 11.84 g (70.0 mmol) of ethyl ethoxymethylcyanoacetate and 9.67 g (70.0 mmol) of potassium carbonate were dissolved in 100 mL of ethanol The reaction was heated to reflux overnight. After the reaction was completed, 300 mL of water was added to the reaction mixture and a precipitate was precipitated. The precipitate was collected by filtration and dried under vacuum to give 12.87 g of light yellow crystalline solid in 74% yield. The product was recrystallized from ethanol and the melting point was 151-152 °C. Elemental analysis results (C12H12FN3O2): calculated value C 57.82%, H 4.85%, N 16.86%; measured value C 57.82%, H 4.78%, N 16.79%.

References

[1] Patent: US5064851, 1991, A

ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE Suppliers

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Clearsynth Labs Limited

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A.J Chemicals

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Dr. Jagath Reddy's Heterocyclics

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View Lastest Price from ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE manufacturers

Career Henan Chemical Co

Product: ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE 138907-68-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-24

138907-68-3, ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATERelated Search:

6-aminopyridine-2-carboxylic acid 5-AMINO-1-(4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL 5-AMINO-1-(3-CHLORO-4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLATE 5-AMINO-1-(2,4-DIFLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER ethyl 5-amino-1-(3-chloro-4-fluorophenyl)-3-cyclobutyl-1H-pyrazole-4-carboxylate ethyl 5-amino-3-cyclopentyl-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate ethyl 5-amino-3-cyclobutyl-1-(4-fluorophenyl)-1H-pyrazole-4-carboxylate ethyl 5-amino-1-(3-chloro-4-fluorophenyl)-3-cyclopentyl-1H-pyrazole-4-carboxylate ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE

ETHYL 5-AMINO-1-(4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLATE

ETHYL 5-AMINO-1-(4-FLUOROPHENYL)PYRAZOLE-4-CARBOXYLATE

BUTTPARK 23\09-43

5-AMINO-1-(4-FLUOROPHENYL)-1H-PYRAZOLE-4-CARBOXYLIC ACID ETHYL ESTER

AKOS BBS-00007066

SALOR-INT L251488-1EA

TIMTEC-BB SBB000884

5-Amino-4-(ethoxycarbonyl)-1-(4-fluorophenyl)-1H-pyrazole, 1-[5-Amino-4-(ethoxycarbonyl)-1H-pyrazol-1-yl]-4-fluorobenzene

1H-Pyrazole-4-carboxylic acid, 5-amino-1-(4-fluorophenyl)-, ethyl ester

138907-68-3

C12H12FN3O2

ARYL AMINE