ChemicalBook > CAS DataBase List > 1,3-BENZOXAZOL-6-AMINE

1,3-BENZOXAZOL-6-AMINE

Product Name
1,3-BENZOXAZOL-6-AMINE
CAS No.
177492-52-3
Chemical Name
1,3-BENZOXAZOL-6-AMINE
Synonyms
benzo[d]oxazol-6-amine;6-BenzoxazolaMine;6-AMINO-BENZOXAZOLE;Benzooxazol-6-ylamine;6-Aminobenzoxazole,95%;1,3-BENZOXAZOL-6-AMINE;6-Amino-1,3-benzoxazole
CBNumber
CB8280376
Molecular Formula
C7H6N2O
Formula Weight
134.14
MOL File
177492-52-3.mol
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1,3-BENZOXAZOL-6-AMINE Property

Melting point:
88 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
Solid
color 
Orange to brown
Water Solubility 
Slightly soluble in water.
Sensitive 
Air Sensitive
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-36-22
Safety Statements 
22-26-36/37/39
RIDADR 
2811
HazardClass 
IRRITANT
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
CDS013806
Product name
1,3-benzoxazol-6-amine
Purity
Aldrich<SUP>CPR</SUP>
Packaging
250 mg
Price
$107
Updated
2025/07/31
TRC
Product number
B130008
Product name
6-​Benzoxazolamine
Packaging
500mg
Price
$110
Updated
2021/12/16
Matrix Scientific
Product number
043883
Product name
1,3-Benzoxazol-6-amine
Purity
97%
Packaging
5g
Price
$119
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB139721
Product name
Benzo[d]oxazol-6-amine
Packaging
500mg
Price
$130
Updated
2021/12/16
SynQuest Laboratories
Product number
4H30-1-5N
Product name
6-Amino-1,3-benzoxazole
Packaging
1g
Price
$168
Updated
2021/12/16
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1,3-BENZOXAZOL-6-AMINE Chemical Properties,Usage,Production

Uses

6-Aminobenzoxazole is used as pharmaceutical intermediate.

Definition

ChEBI: 6-Amino-benzoxazole is a benzoxazole.

Synthesis

17200-30-5

177492-52-3

GENERAL METHOD: 6-nitro-1,3-benzoxazole (6.13 mmol) was dissolved in ethanol (30 mL) and 10% Pd/C catalyst was added (the amount of catalyst was 20% of the mass of 6-nitro-1,3-benzoxazole). The mixture was placed in a Parr hydrogenation unit and the hydrogenation reaction was carried out at 50 psi H?(g) pressure overnight. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under vacuum to remove the solvent. The crude product was purified by fast column chromatography using a 30%-40% ethyl acetate/hexane gradient elution to give pure 6-aminobenzoxazole.

References

[1] ACS Catalysis, 2015, vol. 5, # 3, p. 1526 - 1529
[2] Molecules, 2014, vol. 19, # 1, p. 925 - 939
[3] Collection of Czechoslovak Chemical Communications, 1996, vol. 61, # 2, p. 268 - 275
[4] Collection of Czechoslovak Chemical Communications, 1996, vol. 61, # 3, p. 371 - 380
[5] Chemical Communications, 2011, vol. 47, # 39, p. 10972 - 10974

1,3-BENZOXAZOL-6-AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-BENZOXAZOL-6-AMINE Suppliers

Belgium 1 China 84 Germany 2 India 3 United Kingdom 3 United States 13 Global 106
Accela ChemBio Inc.
Tel
+1-858-6993322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
ProdList
21193
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58
Alchem Pharmtech,Inc.
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8485655694
Email
sales@alchempharmtech.com
Country
United States
ProdList
63687
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58
Aladdin Scientific
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Email
tp@aladdinsci.com
Country
United States
ProdList
52923
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58
Aceschem Inc.
Tel
+1-817863-6948 +1-（817）863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19632
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58
Synthonix Inc
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--
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Email
info@synthonix.com
Country
United States
ProdList
6872
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Abblis Chemicals LLC
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info@abblis.com
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United States
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1272
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Combi-Blocks Inc.
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SynQuest Laboratories, Inc.
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Country
United States
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Matrix Scientific
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sales@matrixscientific.com
Country
United States
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6632
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Riedel-de Haen AG
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Ryan Scientific, Inc.
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Email
ryan.reichlyn@ryansci.com
Country
United States
ProdList
6439
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60
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
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47
HONEST JOY HOLDINGS LIMITED
Tel
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Fax
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Email
sales@honestjoy.cn
Country
United States
ProdList
6675
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View Lastest Price from 1,3-BENZOXAZOL-6-AMINE manufacturers

Career Henan Chemical Co
Product
1,3-BENZOXAZOL-6-AMINE 177492-52-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-30

177492-52-3, 1,3-BENZOXAZOL-6-AMINERelated Search:

2-(4-AMINOPHENYL)-6-AMINOBENZOXAZOLE 2-Methyl-6-nitrobenzoxazole 6-NITRO BENZOXAZOLINONE 5-CHLORO-6-BENZOXAZOLAMINE 2-(2-NAPHTHYL)-1,3-BENZOXAZOL-5-AMINE 2-Methyl-5-chloro-6-benzoxazolamine 1,3-BENZOXAZOL-2-AMINE 6-Amino-2-methylbenzoxazole Benzoxazole Oxazole N-METHYL-N'-(2-METHYL-1,3-BENZOXAZOL-6-YL)THIOUREA 6-Amino-2-(3-aminophenyl)benzoxazole OTAVA-BB 1315014 2-(4-METHOXY-PHENYL)-BENZOOXAZOLE-6-YLAMINE OTAVA-BB 1315037 6-NITRO-1,3-BENZOXAZOLE 2-Phenyl-benzooxazol-6-ylamine 5-CHLORO-2-METHYL-6-NITRO-1,3-BENZOXAZOLE

  • 6-AMINO-BENZOXAZOLE
  • Benzooxazol-6-ylamine
  • benzo[d]oxazol-6-amine
  • 6-Amino-1,3-benzoxazole
  • 6-BenzoxazolaMine
  • 1,3-BENZOXAZOL-6-AMINE
  • 6-Aminobenzoxazole,95%
  • 177492-52-3