ChemicalBook > CAS DataBase List > 4-METHANESULFONYL-BENZOIC ACID METHYL ESTER
4-METHANESULFONYL-BENZOIC ACID METHYL ESTER
Application- Product Name
- 4-METHANESULFONYL-BENZOIC ACID METHYL ESTER
- CAS No.
- 22821-70-1
- Chemical Name
- 4-METHANESULFONYL-BENZOIC ACID METHYL ESTER
- Synonyms
- RARECHEM AL BF 0606;Methyl 4-Methanesulfonylbenzoate;Methyl4-(methylsulfonyl)benzoate;4-METHANESULFONYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 4-(methylsulfonyl)-, methyl ester
- CBNumber
- CB8283463
- Molecular Formula
- C9H10O4S
- Formula Weight
- 214.24
- MOL File
- 22821-70-1.mol
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4-METHANESULFONYL-BENZOIC ACID METHYL ESTER Property
- Melting point:
- 118-120 °C
- Boiling point:
- 377.8±34.0 °C(Predicted)
- Density
- 1.266±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- solid
- Appearance
- White to off-white Solid
- InChI
- 1S/C9H10O4S/c1-13-9(10)7-3-5-8(6-4-7)14(2,11)12/h3-6H,1-2H3
- InChIKey
- GUGXKWUWYBKREL-UHFFFAOYSA-N
- SMILES
- O=S(C(C=C1)=CC=C1C(OC)=O)(C)=O
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Safety
- WGK Germany
- WGK 3
- HS Code
- 2916310090
- Storage Class
- 11 - Combustible Solids
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N-Bromosuccinimide Price
Activate Scientific
- Product number
- AS16297
- Product name
- 4-Methanesulfonyl-benzoicacidmethylester
- Purity
- 97+%
- Packaging
- 1g
- Price
- $185
- Updated
- 2021/12/16
AK Scientific
- Product number
- W4651
- Product name
- Methyl4-methanesulfonylbenzoate
- Packaging
- 10g
- Price
- $424
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0150665
- Product name
- 4-METHANESULFONYL-BENZOIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $716.1
- Updated
- 2021/12/16
Alichem
- Product number
- 22821701
- Product name
- Methyl4-methanesulfonylbenzoate
- Packaging
- 25g
- Price
- $721.71
- Updated
- 2021/12/16
Chemenu
- Product number
- CM157043
- Product name
- Methyl4-methanesulfonylbenzoate
- Purity
- 95+%
- Packaging
- 25g
- Price
- $427
- Updated
- 2021/12/16
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4-METHANESULFONYL-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production
Application
Methyl 4-methanesulfonylbenzoate is an aryl sulfone compound that can be used as a pharmaceutical synthesis intermediate and an organic synthesis intermediate. It is mainly used in laboratory research and development processes and chemical and pharmaceutical synthesis processes.
Synthesis
In a reaction tube, 262 mg of ethyl p-iodobenzoate (MW = 262.04, 1.0 mmol) was added, followed by 153 mg of sodium salt of methyl ketene sulfonate (MW = 102.09, 1.2 mmol, 80%), 28 mg of sodium salt of L-proline (MW = 137.05, 0.2 mmol), 19 mg of CuI (MW = 190.45, 0.1 mmol), 2 ml of DMSO as a solvent, under the protection of nitrogen, the reaction was carried out in an oil bath at 80 ?? for 36 h. Cooling, 4 ml of water was added, and each time it was extracted with 10 ml of ethyl acetate, and repeated three times, and the extract was washed with saturated saline water, dried with anhydrous sodium sulfate, and then filtered, and the filtrate was distilled under reduced pressure, and separated over silica gel columns (the eluent petroleum ether: ethyl acetate = 3: 1 ), obtained 158 mg product 4-methylsulfonylbenzoic acid methyl ester, yield 77%.
4-METHANESULFONYL-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-METHANESULFONYL-BENZOIC ACID METHYL ESTER manufacturers
Career Henan Chemical Co
- Product
- 4-METHANESULFONYL-BENZOIC ACID METHYL ESTER 22821-70-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-08
22821-70-1, 4-METHANESULFONYL-BENZOIC ACID METHYL ESTERRelated Search:
Benzoic acid, 4-(2-aminoethoxy)-, methyl ester, hydrochloride (1:1)
methyl 4-(difluoromethyl)benzoate
4-(4-IODO-PHENOXY)-BENZOIC ACID METHYL ESTER
METHYL 4-(PIPERAZIN-1-YL)BENZOATE
Methyl 4-(2-hydroxyphenyl)butanoate
Benzoic acid, 4-?(1-?azetidinylmethyl)?-?, methyl ester
Methyl 4-(4-cyanophenoxy)benzoate
3,3,4,4-diphenylsulfonetetracarboxylicdianhydride
METHYL 3-AMINO-4-(PHENYLSULFONYL)BENZENECARBOXYLATE
RARECHEM AL BF 1445
METHYL 3-NITRO-4-(PHENYLSULFONYL)BENZENECARBOXYLATE
4-METHANESULFONYL-BENZOIC ACID METHYL ESTER
4-METHANESULFONYL-BENZOIC ACID ETHYL ESTER
DIMETHYL DIPHENYL SULFONE 4,4'-DICARBOXYLATE
DI-N-BUTYL-4,4'-SULFONYLDIBENZOATE
METHYL 3-AMINO-4-[(4-METHYLPHENYL)SULFONYL]BENZENECARBOXYLATE
METHYL 4-[(4-METHYLPHENYL)SULFONYL]-3-[(2-THIENYLCARBONYL)AMINO]BENZENECARBOXYLATE
METHYL 4-[(4-METHYLPHENYL)SULFONYL]-3-NITROBENZENECARBOXYLATE