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Antimony trifluoride

Product Name
Antimony trifluoride
CAS No.
7783-56-4
Chemical Name
Antimony trifluoride
Synonyms
SbF3;ANTIMONY(III) FLUORIDE;trifluorostibine;ANTIMONY FLUORIDE;NA 1549;trifluoro-stibin;trifluorostibane;trifluoro-Stibine;Antimonyfluoride1;antimoinefluorure
CBNumber
CB8304955
Molecular Formula
F3Sb
Formula Weight
178.76
MOL File
7783-56-4.mol
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Antimony trifluoride Property

Melting point:
292 °C
Boiling point:
376 °C
Density 
4.38 g/mL at 25 °C(lit.)
vapor pressure 
26.34kPa at 292℃
Flash point:
376°C
storage temp. 
Store below +30°C.
solubility 
4430g/l Hydrolysis
form 
powder
color 
White to gray
Specific Gravity
4.379
Water Solubility 
385 g/100 mL (20 ºC)
Sensitive 
Moisture Sensitive
Merck 
14,709
Sublimation 
376 ºC
Exposure limits
ACGIH: TWA 0.5 mg/m3; TWA 2.5 mg/m3
NIOSH: IDLH 50 mg/m3; IDLH 250 mg/m3; TWA 0.5 mg/m3
LogP
0.72 at 25℃
CAS DataBase Reference
7783-56-4(CAS DataBase Reference)
NIST Chemistry Reference
Antimony trifluoride(7783-56-4)
EPA Substance Registry System
Antimony trifluoride (7783-56-4)
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Safety

Hazard Codes 
T,N,C
Risk Statements 
23/24/25-51/53
Safety Statements 
7-26-45-61
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
CC5150000
10
Hazard Note 
Corrosive/Highly Toxic
TSCA 
Yes
HS Code 
2826 19 90
HazardClass 
8
PackingGroup 
III
Hazardous Substances Data
7783-56-4(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.07839
Product name
Antimony(III) fluoride
Purity
for synthesis
Packaging
5G
Price
$31.4
Updated
2024/03/01
Sigma-Aldrich
Product number
8.07839
Product name
Antimony(III) fluoride
Purity
for synthesis
Packaging
250g
Price
$135
Updated
2024/03/01
Sigma-Aldrich
Product number
381292
Product name
Antimony(III) fluoride
Purity
powder, 99.8% trace metals basis
Packaging
100G
Price
$143
Updated
2024/03/01
Sigma-Aldrich
Product number
381292
Product name
Antimony(III) fluoride
Purity
powder, 99.8% trace metals basis
Packaging
500G
Price
$502.4
Updated
2024/03/01
Alfa Aesar
Product number
011492
Product name
Antimony(III) fluoride, 99+%
Packaging
100g
Price
$65.4
Updated
2024/03/01
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Antimony trifluoride Chemical Properties,Usage,Production

Description

Antimony trifluoride is a noncombustible,odorless, white to gray crystalline solid. Molecularweight= 178.75; Specific gravity= 4.38 at 21℃ (solid);Boiling point= 376℃; Freezing/Melting point= 292℃;Vapor pressure= 3 mmHg at 17℃. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 0, Reactivity 0. Soluble in water.

Chemical Properties

white to grey crystalline powder

Chemical Properties

Antimony trifluoride is a noncombustible, odorless, white to gray crystalline solid.

Uses

To catalyze fluorinations by HF, manufacture of chlorofluorides, in dyeing, usually in form of double salts, e.g., antimony sodium fluoride or antimony fluoride and ammonium sulfate double salt, manufacture of pottery and porcelains.

Uses

Antimony(III) fluoride is used as a reagent in inorganic and organofluorine chemistry. It acts as a fluorination reagent and electroplating agent. Further, it is used in the preparation of dye, pottery, porcelains, ceramic enamels and glazes. It is utilized in the preparation of Freon.

General Description

Antimony trifluoride solution is the white to gray crystalline solid dissolved in water. Antimony trifluoride is corrosive to metals and tissue. Antimony trifluoride is used in ceramics and to make other chemicals.

Air & Water Reactions

Water slowly hydrolyzes antimony fluoride to form antimony (III) oxide. The dry powdered oxide ignites on heating in air [Mellor Vol. 9 425.1939].

Reactivity Profile

ANTIMONY TRIFLUORIDE is a colorless, solid compound, toxic and corrosive. When heated to decomposition, Antimony trifluoride emits very toxic fumes of fluoride and metallic antimony [Lewis, 3rd ed., 1993, p. 83].

Hazard

Strong irritant to eyes and skin.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

Poison by subcutaneous route. Corrosive to skin and eyes. See also FLUORIDES and ANTIMONY COMPOUNDS. When heated to decomposition it emits very toxic fumes of Fand Sb

Potential Exposure

It is used in dyeing; to make porcelain and pottery; and as a fluorinating agent.

First aid

his chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immedi ately with soap and water. Seek medical attention immedi ately. If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precau tions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. If victim is con scious, administer water or milk. Do not induce vomiting.Medical observation is recommended for 24°48 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor or254 Antimony trifluorideauthorized paramedic may consider administering a corticosteroid spray.

storage

Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with this chemicalyou should be trained on its proper handling and storage.Store in tightly closed containers in a cool, well-ventilatedarea away from heat.

Shipping

UN1549 Antimony compounds, inorganic, solid, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Purification Methods

It crystallises from MeOH to remove oxide and oxyfluoride, then it is sublimed under vacuum in an aluminium cup on to a water-cooled copper condenser. Its solubility is 443g/100g in H2O at 20o and 562g/100g in H2O at 30o with partial hydrolysis. [Woolf J Chem Soc 279 1955, Kwasnik in Handbook of Preparative Inorganic Chem (Ed. Brauer) Academic Press Vol I p 199 1963].

Incompatibilities

Hot perchloric acid.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

Antimony trifluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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Antimony trifluoride Suppliers

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View Lastest Price from Antimony trifluoride manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Antimony trifluoride 7783-56-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
Antimony trifluoride 7783-56-4
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-20

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