ChemicalBook > CAS DataBase List > 4,4'-DI-TERT-BUTYLBIPHENYL

4,4'-DI-TERT-BUTYLBIPHENYL

Product Name
4,4'-DI-TERT-BUTYLBIPHENYL
CAS No.
1625-91-8
Chemical Name
4,4'-DI-TERT-BUTYLBIPHENYL
Synonyms
4,4'-Di-tert-butyL;TIMTEC-BB SBB007812;4,4'-DI-T-BUTYLBIPHENYL;4,4'-DI-TERT-BUTYLBIPHENYL;4,4'-DI-TERT-BUTYLBIPHENYL;4,4'-Di-t-butylbiphenyl, 99+%;4,4'-Di-tert-butylbiphenyl>4,4'-Di-tert-butylbiphenyl 99%;4,4'-Ditert-butyl-1,1'-biphenyl;4,4'-Di-tert-butylbiphenyl, 99+%
CBNumber
CB8316992
Molecular Formula
C20H26
Formula Weight
266.42
MOL File
1625-91-8.mol
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4,4'-DI-TERT-BUTYLBIPHENYL Property

Melting point:
126-130 °C(lit.)
Boiling point:
190-192 °C13 mm Hg(lit.)
Density 
0.9463 (estimate)
refractive index 
1.5928 (estimate)
Flash point:
190-192°C/13mm
storage temp. 
Sealed in dry,Room Temperature
solubility 
dioxane: 0.1 g/mL, clear
form 
Crystalline Powder
color 
Light yellow to yellow-orange
BRN 
2095855
CAS DataBase Reference
1625-91-8(CAS DataBase Reference)
NIST Chemistry Reference
4,4'-Di-tert-butylbiphenyl(1625-91-8)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29029090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
193801
Product name
4,4′-Di-tert-butylbiphenyl
Purity
99%
Packaging
5g
Price
$62
Updated
2024/03/01
Sigma-Aldrich
Product number
193801
Product name
4,4′-Di-tert-butylbiphenyl
Purity
99%
Packaging
25g
Price
$225
Updated
2024/03/01
TCI Chemical
Product number
D2450
Product name
4,4'-Di-tert-butylbiphenyl
Purity
>98.0%(GC)
Packaging
5g
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
D2450
Product name
4,4'-Di-tert-butylbiphenyl
Purity
>98.0%(GC)
Packaging
25g
Price
$88
Updated
2024/03/01
Alfa Aesar
Product number
B21470
Product name
4,4'-Di-tert-butylbiphenyl, 99%
Packaging
5g
Price
$49.65
Updated
2024/03/01
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4,4'-DI-TERT-BUTYLBIPHENYL Chemical Properties,Usage,Production

Chemical Properties

Powder

Uses

It is used in the generation of 1,2-di(lithiomethyl)benzene. It is found to accept electrons from Li metal to give a radical anion which is highly effective in the conversion of alkyl halides to alkyllithiums. 4,4?-Di-tert-butylbiphenyl is used in production of homoallylic amine derivatives. It is also used in the preparation of lithium di-tert-butylbiphenylide, a radical anion, superior to sodium or lithium naphthalenides for metalation reactions. Along with lithium, 4,4?-Di-tert-butylbiphenyl catalyzes; reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers and reductive opening of N-phenylazetidine.

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 1655, 1985 DOI: 10.1016/S0040-4039(00)98576-9

General Description

4,4′-Di-tert-butylbiphenyl along with lithium catalyzes:

  • reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers
  • reductive opening of N-phenylazetidine

4,4'-DI-TERT-BUTYLBIPHENYL Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-DI-TERT-BUTYLBIPHENYL Suppliers

Americas 1 Belgium 4 China 110 Europe 1 France 1 Germany 4 India 10 Japan 6 Lithuania 2 Poland 1 Russia 1 South Korea 1 Switzerland 3 United Kingdom 11 United States 27 Global 183
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from 4,4'-DI-TERT-BUTYLBIPHENYL manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
4,4'-Di-tert-butylbiphenyl 1625-91-8
Price
US $0.00/KG
Min. Order
10g
Purity
99.90%
Supply Ability
5TONS
Release date
2020-11-20
Henan Fengda Chemical Co., Ltd
Product
4,4'-Di-tert-butylbiphenyl 1625-91-8
Price
US $200.00-1.00/KG
Min. Order
1KG
Purity
99%, 99.5% Sublimated
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-30
Career Henan Chemical Co
Product
4,4'-DI-TERT-BUTYLBIPHENYL 1625-91-8
Price
US $0.01/KG
Min. Order
1KG
Purity
98%; 99%
Supply Ability
1kg；10kg; 25kg
Release date
2020-01-07

1625-91-8, 4,4'-DI-TERT-BUTYLBIPHENYLRelated Search:

3,5-Bis(tert-butyl)benzaldehyde 1,3-DI-TERT-BUTYLBENZENE 3,5-Di-tert-butyl-4-hydroxybenzyl alcohol Bis(4-tert-butylphenyl)iodonium hexafluorophosphate Ultranox 626 4,4'-[[2,5-Bis(tert-butyl)-1,4-phenylene]bis(oxy)]bis[3-(trifluoromethyl)benzenamine 2,7-Di-tert-butylfluorene 4,4'-DI-TERT-BUTYLBIPHENYL 1,4-Di-tert-butylbenzene 2,6-Di-tert-butyl-p-benzoquinone 4-Bromo-2,6-di-tert-butylanisole Antioxidant 168 2,4-Di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate 4,4'-Methylenebis(2,6-di-tert-butylphenol) 3,5-Di-tert-butylcatechol 2 7-DI-TERT-BUTYL-9-FLUORENYLMETHANOL Pseudomorphine (Morphine Impurity) CODEINE IMP C

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