ChemicalBook > CAS DataBase List > 2-PHENYL-PYRIDIN-4-YLAMINE

2-PHENYL-PYRIDIN-4-YLAMINE

Product Name
2-PHENYL-PYRIDIN-4-YLAMINE
CAS No.
21203-86-1
Chemical Name
2-PHENYL-PYRIDIN-4-YLAMINE
Synonyms
2-PPA;2-Phenylpyridin-4-aMine;4-AMINO-2-PHENYLPYRIDINE;4-Pyridinamine, 2-phenyl-;2-PHENYL-PYRIDIN-4-YLAMINE;Pyridine, 4-amino-2-phenyl-
CBNumber
CB8370897
Molecular Formula
C11H10N2
Formula Weight
170.21
MOL File
21203-86-1.mol
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2-PHENYL-PYRIDIN-4-YLAMINE Property

Boiling point:
384.2±30.0 °C(Predicted)
Density 
1.133±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
8.22±0.10(Predicted)
form 
solid
color 
Pale yellow
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Safety

Risk Statements 
41
Safety Statements 
26-39
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A615980
Product name
4-Amino-2-phenylpyridine
Packaging
50mg
Price
$55
Updated
2021/12/16
ChemScene
Product number
CS-D1566
Product name
2-Phenylpyridin-4-amine
Purity
>98.0%
Packaging
250mg
Price
$51
Updated
2021/12/16
ChemScene
Product number
CS-D1566
Product name
2-Phenylpyridin-4-amine
Purity
>98.0%
Packaging
1g
Price
$66
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-1-KX
Product name
4-Amino-2-phenylpyridine
Purity
97%
Packaging
1g
Price
$228
Updated
2021/12/16
Matrix Scientific
Product number
076480
Product name
4-Amino-2-phenylpyridine
Purity
95+%
Packaging
250mg
Price
$231
Updated
2021/12/16
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2-PHENYL-PYRIDIN-4-YLAMINE Chemical Properties,Usage,Production

Uses

2-PPA is a selective inhibitor of TMEM175 (IC50=32 μM) with activity in modulating lysosomal function. Acute inhibition of TMEM175 by 2-PPA increases lysosomal macromolecular catabolism, thereby accelerating macrophage and other digestive processes. 2-PPA can be used in the study of Parkinson's disease[1].

Synthesis

14432-12-3

98-80-6

21203-86-1

a) Synthesis of 2-phenyl-pyridin-4-ylamine: To a stirred solution of 16.0 g (124 mmol) of 2-chloro-4-aminopyridine dissolved in 200 ml of toluene, 18.2 g (149 mmol) of phenylboronic acid, 7.19 g (6.22 mmol) of tetrakis(triphenylphosphine)palladium(0), and 130 ml (260 mmol) of 2M sodium carbonate were added in turn. aqueous solution. The reaction mixture was heated to reflux at 100 °C for 16 h and subsequently cooled to room temperature. The reaction solution was extracted three times with ethyl acetate and the organic phases were combined. The organic phase was washed three times with 200 ml of 1 M hydrochloric acid aqueous solution. The acidic and aqueous phases were combined, adjusted to alkaline with 5 M aqueous sodium hydroxide and extracted three times with dichloromethane. The organic extracts were combined, dried with anhydrous sodium sulfate and concentrated under reduced pressure. The crude product was purified by fast column chromatography (eluent: acetone) and subsequently ground in hexane containing a small amount of ether to give 18.5 g (87% yield) of 2-phenyl-pyridin-4-ylamine as a white solid.ES-MS m/e (relative abundance): 171 ([M+H]+, 100).

References

[1] SeCheol, et al. "Discovery of Selective Inhibitors for the Lysosomal Parkinson’s Disease Channel TMEM175." Journal of the American Chemical Society (2024). DOI:10.1021/jacs.4c05623

2-PHENYL-PYRIDIN-4-YLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-PHENYL-PYRIDIN-4-YLAMINE Suppliers

Tetranov Biopharm
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China
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Shanghai Topbiochem Technology Co., Ltd
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China
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SynAsst Chemical.
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Bide Pharmatech Ltd.
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Synchem OHG
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+49 5662 408730
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NovoChemy Ltd.
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86-(0)21-31261262 373522135
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China
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View Lastest Price from 2-PHENYL-PYRIDIN-4-YLAMINE manufacturers

Career Henan Chemical Co
Product
2-PHENYL-PYRIDIN-4-YLAMINE 21203-86-1
Price
US $1.00/KG
Min. Order
1KG
Purity
95%
Supply Ability
500KG
Release date
2018-08-19