ChemicalBook > CAS DataBase List > 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)

Product Name
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
CAS No.
14172-92-0
Chemical Name
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
Synonyms
STK567921;NICKEL TPP;RARECHEM AS SA 0006;PROTOPORPHYRIN IX NI(II);Nickel tetraphenylporphine;Nickel tetraphenylporphyrin;NI(II) MESO-TETRAPHENYLPORPHINE;NICKEL MESO-TETRAPHENYLPORPHINE;meso-Tetraphenylporphine-Ni(II);(Tetraphenylporphyrinato)nickel
CBNumber
CB8405249
Molecular Formula
C44H28N4Ni
Formula Weight
671.41
MOL File
14172-92-0.mol
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Property

Melting point:
>300 °C
form 
crystal
color 
purple
Water Solubility 
Insoluble in H2O; soluble in CHCl3; slightly soluble in ether, benzene, hexane, and methanol.
λmax
525 nm (2nd)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
37/39-26-36
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
252204
Product name
5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II)
Purity
dye content ≥95 %
Packaging
500mg
Price
$93
Updated
2024/03/01
Strem Chemicals
Product number
28-1690
Product name
Nickel(II) meso-tetraphenylporphine
Packaging
1g
Price
$214
Updated
2024/03/01
Strem Chemicals
Product number
28-1690
Product name
Nickel(II) meso-tetraphenylporphine
Packaging
5g
Price
$853
Updated
2024/03/01
TRC
Product number
N598540
Product name
Ni(II)meso-Tetraphenylporphine(1-3%chlorin)
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
N598540
Product name
Ni(II)meso-Tetraphenylporphine(1-3%chlorin)
Packaging
50mg
Price
$60
Updated
2021/12/16
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Chemical Properties,Usage,Production

Chemical Properties

dark purple crystalline powder or crystals

Uses

Nickel(II) Tetraphenylporphyrinate is an electron transfer agent and catalyst for aryl halogen exchange reactions. It could be used in cyclizations of saturated ο-iodo ketones and hydrogenation of alkenes.

reaction suitability

reagent type: catalyst
core: nickel

Purification Methods

Purify it by chromatography on neutral (Grade I) alumina, followed by recrystallisation from CH2Cl2/MeOH [Yamashita J Phys Chem 91 3055 1987]. [Beilstein 26 III/IV 1960.]

Precautions

Stable in air and water. Some nickel compounds are known carcinogens, so standard safety precautions apply.

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) Suppliers

CHEMICAL LAND21
Tel
--
Fax
--
Email
sales21@chemicalland21.com
Country
South Korea
ProdList
6303
Advantage
74
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View Lastest Price from 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) manufacturers

Career Henan Chemical Co
Product
5,10,15,20-tetraphenyl-21h,23h-porphine nickel(ii) 14172-92-0
Price
US $2.00/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
20tons
Release date
2019-12-30

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