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Bis-(triphenylphosphino)-cuprous borohydride

Product Name
Bis-(triphenylphosphino)-cuprous borohydride
CAS No.
16903-61-0
Chemical Name
Bis-(triphenylphosphino)-cuprous borohydride
Synonyms
BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYD;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYDRIDE;bis-(triphenylphosphino)-cuprous borohydride;BIS(TRIPHENYLPHOSPHINE)COPPER TETRAHYDROBORATE;Copper bis(trimethylphosphine)(tetrahydroborate);Bis(triphenylphosphine)copper Tetrahydroborate >BIS(TRIPHENYLPHOSPHINE)COPPER(I) TETRAHYDRIDOBORATE;16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride;Bis(triphenylphosphine)copper Tetrahydroborate, (PPh3)2CuBH4;Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-
CBNumber
CB8408215
Molecular Formula
2C18H15P.Cu.BH4
Formula Weight
602.97
MOL File
16903-61-0.mol
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Bis-(triphenylphosphino)-cuprous borohydride Property

Melting point:
164 °C (dec.)(lit.)
storage temp. 
Store below +30°C.
form 
powder to crystal
color 
White to Almost white
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
CAS DataBase Reference
16903-61-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-15
Safety Statements 
26-60-43-37-7/8
RIDADR 
2813
WGK Germany 
3
F 
9-21
HazardClass 
4.3
PackingGroup 
III
HS Code 
29319019
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H261In contact with water releases flammable gas

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P231+P232Handle under inert gas. Protect from moisture.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.18504
Product name
Bis(triphenylphosphine)copper(I) borohydride
Purity
for synthesis
Packaging
5G
Price
$64.7
Updated
2024/03/01
TCI Chemical
Product number
B1139
Product name
Bis(triphenylphosphine)copper Tetrahydroborate
Purity
>90.0%(T)
Packaging
5g
Price
$49
Updated
2024/03/01
Alfa Aesar
Product number
A13730
Product name
Bis(triphenylphosphine)copper(I) borohydride
Packaging
5g
Price
$25.4
Updated
2021/12/16
Alfa Aesar
Product number
A13730
Product name
Bis(triphenylphosphine)copper(I) borohydride
Packaging
25g
Price
$84.7
Updated
2021/12/16
Alfa Aesar
Product number
A13730
Product name
Bis(triphenylphosphine)copper(I) borohydride
Packaging
100g
Price
$228
Updated
2021/12/16
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Bis-(triphenylphosphino)-cuprous borohydride Chemical Properties,Usage,Production

Uses

Bis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0) is an organometallic catalyst used in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. Bis(triphenylphosphine)copper tetrahydroborate is also used in the preparation of tungsten, ruthenium and copper cluster complexes.

Bis-(triphenylphosphino)-cuprous borohydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis-(triphenylphosphino)-cuprous borohydride Suppliers

Americas 1 China 85 Europe 1 Germany 3 India 2 Japan 1 Switzerland 1 United Kingdom 4 United States 8 Global 106
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Merck Schuchardt OHG
Tel
--
Fax
--
Email
schuchardt-vertrieb@merck.de
Country
Germany
ProdList
5827
Advantage
74
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View Lastest Price from Bis-(triphenylphosphino)-cuprous borohydride manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Bis(triphenylphosphine)copper Tetrahydroborate 16903-61-0
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16
Career Henan Chemical Co
Product
Bis-(triphenylphosphino)-cuprous borohydride 16903-61-0
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-10

16903-61-0, Bis-(triphenylphosphino)-cuprous borohydrideRelated Search:

Sodium cyanoborohydride Copper oxychloride Copper Copper(I) Cyanide Sodium triacetoxyborohydride BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE Bis(triphenylphosphine)nickel(II)chloride BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Potassium borohydride Trimethylphosphine Triphenylphosphine Lithium borohydride Sodium borohydride BORANE-TRIPHENYLPHOSPHINE COMPLEX COPPER PHOSPHORUS BORANE-DIPHENYLPHOSPHINE COMPLEX Bis-(triphenylphosphino)-cuprous borohydride GOLD COAST SOLUTION NO 1

  • Bis(triphenylphosphine)copper Tetrahydroborate, (PPh3)2CuBH4
  • BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYD
  • Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-
  • BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYDRIDE
  • BIS(TRIPHENYLPHOSPHINE)COPPER(I) TETRAHYDRIDOBORATE
  • BIS(TRIPHENYLPHOSPHINE)COPPER TETRAHYDROBORATE
  • bis-(triphenylphosphino)-cuprous borohydride
  • Copper bis(trimethylphosphine)(tetrahydroborate)
  • Copper, tetrahydroborato(1-)-.kappa.H,.kappa.Hbis(triphenylphosphine)-, (T-4)-
  • Bis(triphenylphosphine)copper Tetrahydroborate &gt
  • 16903-61-0 Bis-(triphenylphosphino)-cuprous borohydride
  • 16903-61-0
  • 2C18H15PCuBH4
  • C36H34BCuP2
  • Synthetic Reagents
  • Borohydrides
  • Tetrahydroborates
  • Classes of Metal Compounds
  • Reduction
  • Transition Metal Compounds
  • Cu (Copper) Compounds
  • B (Classes of Boron Compounds)
  • Cu
  • B (Classes of Boron Compounds)
  • Classes of Metal Compounds
  • Cu (Copper) Compounds
  • Reduction
  • Synthetic Organic Chemistry
  • Tetrahydroborates
  • Transition Metal Compounds