ChemicalBook > CAS DataBase List > (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

Product Name: (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
CAS No.: 55700-44-2
Chemical Name: (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
Synonyms: Josiphos;(R)-(S)-PPFA;Josiphos SL-0000-2;)-N,N-DiMethyl-1-[(S)-2-(diphenylphosphino)ferro;(-)-(R)-N,N-dimethyl-1-((S)-2-(diphenyl-phosphino;(R)-N,N-Dimethyl-1-((S)-2-(diphenylphosphino)ferro;(R)-N,N-Dimethyl-1-((S)-2-diphenylphosphino)ferrocene)amine;(1R)-1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethylethanamine;(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethy...;)-N,N-DiMethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylaMine
CBNumber: CB8478872
Molecular Formula: C26H28FeNP10*
Formula Weight: 441.33
MOL File: 55700-44-2.mol

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(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Property

Melting point:: 141-143 °C(lit.)
alpha: -355 º (C=0.6 IN ETOH)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: solid
color: Light yellow to Yellow to Orange
optical activity: [α]20/D 355°, c = 0.6 in ethanol
Water Solubility: Insoluble in water.
Sensitive: Air Sensitive

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36-36/37/38
RIDADR: 3288
WGK Germany: 3
HazardClass: 6.1
PackingGroup: III
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D2535
Product name: (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine
Purity: >96.0%(HPLC)
Packaging: 100mg
Price: $114
Updated: 2025/07/31

TRC

Product number: D474193
Product name: (R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine
Packaging: 5mg
Price: $55
Updated: 2021/12/16

Chem-Impex

Product number: 40742
Product name: (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine,96%(HPLC)
Purity: 96%(HPLC)
Packaging: 100MG
Price: $84
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0001318
Product name: (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
Purity: 95.00%
Packaging: 100MG
Price: $192.15
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD59972
Product name: (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine
Packaging: 250mg
Price: $240
Updated: 2021/12/16

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(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Chemical Properties,Usage,Production

Chemical Properties

Yellow solid

Uses

Ligand used in the enantioselective vinylation of aldehydes.

Application

(R)-N,N-dimethyl-1-[(s)-2-(diphenylphosphino)ferrocenyl]ethylamine is an effective chiral phosphine ligand for nickel- or palladium-catalyzed asymmetric cross-couplings of organomagnesium or zinc reagents with alkenyl bromides and for palladium-catalyzed asymmetric hydrosilylations of 1,3-dienes.

reaction suitability

reaction type: Asymmetric synthesis
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

storage

stable in air for years, but best kept sealed in a refrigerator.

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Suppliers

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View Lastest Price from (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: (|R|)-()-|N|,|N|-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine 55700-44-2
Price: US $2.00-5.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons
Release date: 2025-07-10

Career Henan Chemical Co

Product: (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE 55700-44-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

55700-44-2, (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINERelated Search:

(-)-(R)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (+)-(S)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE,(S)-N,N-DIMETHYL-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Dichloro[(S)-N,N-dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine]palladium(II) (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (R)-(S)-BPPFA (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(2-METHYLPHENYL)PHOSPHINO]FERROCENE (R,R)-1-[ALPHA-(DIMETHYLAMINO)-2-(DIPHENYLPHOSPHINO)BENZYL]-2-(DIPHENYLPHOSPHINO)FERROCENE

(-)-(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

(R) -NN-dimethyl-1-((S) -2-diphenylphosphorus) ferrocene) ethylamine

(R)-(-)-N,N-DIMETHYL-1-(2-DIPHENYLPHOSPHINO)FERROCENYLETHYLAMINE

(R)-(S)-PPFA

(-)-(R)-N,N-dimethyl-1-((S)-2-(diphenyl-phosphino

(R)-N,N-Dimethyl-1-((S)-2-(diphenylphosphino)ferro

Josiphos SL-0000-2

)-N,N-DiMethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylaMine

)-N,N-DiMethyl-1-[(S)-2-(diphenylphosphino)ferro

(R) - (-) - N, N- diMethyl-1- (2-biphenyl-phosphino) ferrocene ethylaMine

(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine,96%

Josiphos

(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine&gt

(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 96%, for synthesis

(S)-1-[(R)-1-(Dimethylamino)ethyl]-2-(diphenylphosphino) ferrocene

(1R)-1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethylethanamine

(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethy...

(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine, 97%,

(R)-N,N-Dimethyl-1-[(Sp)-2-(diphenylphosphino)ferrocenyl]ethylamine

(2R)-1-[(1R)-1-(Dimethylamino)ethyl]-2-(diphenylphosphino)ferrocene

(Sp)-1-[(1R)-1-(Dimethylamino)ethyl]-2-(diphenylphosphino)ferrocene

(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine,98%

(R)-(?)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine

(R)-N,N-Dimethyl-1-((S)-2-diphenylphosphino)ferrocene)amine

55700-44-2

Chiral Catalysts, Ligands, and Reagents

Other Chiral Ligands

Asymmetric Synthesis

Ferrocenes

Transition Metal Compounds

Classes of Metal Compounds

Phosphine Ligands

Metallocenes

Fe (Iron) Compounds

Chiral Phosphine

Asymmetric Synthesis

Classes of Metal Compounds

Fe (Iron) Compounds

Ferrocenes

Metallocenes

Phosphine Ligands

Synthetic Organic Chemistry

Transition Metal Compounds

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Other Chiral Ligands