ChemicalBook > CAS DataBase List > (R)-(S)-BPPFA

(R)-(S)-BPPFA

Product Name
(R)-(S)-BPPFA
CAS No.
74311-56-1
Chemical Name
(R)-(S)-BPPFA
Synonyms
(R)-(S)-BPPFA;(-)-(R)-(S)-BPPFA;)-(R)-N,N-Dimethyl-1-[(S)-1;(-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho;(R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino;(-)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino;N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl;(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferroceny...;[r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene;(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
CBNumber
CB8760209
Molecular Formula
C38H37FeNP210*
Formula Weight
625.5
MOL File
74311-56-1.mol
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(R)-(S)-BPPFA Property

Melting point:
143-144 °C(lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
solid
color 
Light yellow to Brown
optical activity
[α]20/D 350°, c = 0.5 in chloroform
InChIKey
VUJPTJYMSBMZOZ-ZEECNFPPSA-N
SMILES
[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.C[C@H]([C]4[CH][CH][CH][C]4P(c5ccccc5)c6ccccc6)N(C)C
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2931.90.6000
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D2537
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Purity
>98.0%(GC)
Packaging
100mg
Price
$77
Updated
2025/07/31
TRC
Product number
B676690
Product name
(-)-(R)-(S)-BPPFA
Packaging
1g
Price
$685
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD59974
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Packaging
1g
Price
$840
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD59974
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Packaging
500mg
Price
$520
Updated
2021/12/16
AK Scientific
Product number
4147AL
Product name
(R)-(S)-BPPFA
Packaging
100mg
Price
$190
Updated
2021/12/16
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(R)-(S)-BPPFA Chemical Properties,Usage,Production

Uses

Ligand used in the enantioselective silylation of allylic chlorides.

Uses

(-)-(R)-(S)-BPPFA is an electron-rich bulky ligand used in amination reactions of aryl halides and tosylates. Homogeneous catalyst.

(R)-(S)-BPPFA Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(S)-BPPFA Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
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Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
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Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
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Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
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China
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Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
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9718
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Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
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Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
150-2103-5486 18017383231
Fax
qq:2817624287
Email
983544897@qq.com
Country
China
ProdList
9341
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View Lastest Price from (R)-(S)-BPPFA manufacturers

Career Henan Chemical Co
Product
(R)-(S)-BPPFA 74311-56-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

74311-56-1, (R)-(S)-BPPFARelated Search:


  • (R)-(S)-BPPFA
  • (-)-(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
  • (-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho
  • (-)-(R)-N,N-DIMETHYL-1-((S)-1',2-BIS(DI- PHENYLPHOSPHINO)FERROCENYL)ET-AMIN,95%
  • (R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino
  • [r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene
  • N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl
  • (2S)-1-[(1R)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene
  • Ferrocene,1-[(1R)-1-(dimethylamino)ethyl]-1',2-bis(diphenylphosphino)-, (2S)-
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,98%
  • )-(R)-N,N-Dimethyl-1-[(S)-1
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine&gt
  • (-)-(R)-(S)-BPPFA
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferroceny...
  • (-)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino
  • (-)-(|R|)-|N|,|N|-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (R)-N,N-Dimethyl-1-[(Rp)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (?)-(<i>R</i>)-<i>N,N</i>-Dimethyl-1-[(<i>S</i>)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • [R,R]-1-[1-Dimethylaminoethyl]-1′,2-bis[diphenylphosphino]ferrocene, CAS 74311-56-1
  • 74311-56-1
  • C38H37FeNP2
  • Chiral Catalysts, Ligands, and Reagents
  • Phosphine Ligands
  • Fe (Iron) Compounds
  • Ferrocenes
  • Transition Metal Compounds
  • Classes of Metal Compounds
  • Asymmetric Synthesis
  • Metallocenes
  • Other Chiral Ligands
  • Chiral Phosphine
  • Asymmetric Synthesis
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds