ChemicalBook > CAS DataBase List > (R)-(S)-BPPFA

(R)-(S)-BPPFA

Product Name
(R)-(S)-BPPFA
CAS No.
74311-56-1
Chemical Name
(R)-(S)-BPPFA
Synonyms
(R)-(S)-BPPFA;(-)-(R)-(S)-BPPFA;)-(R)-N,N-Dimethyl-1-[(S)-1;(-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho;(R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino;(-)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino;N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl;(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferroceny...;[r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene;(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
CBNumber
CB8760209
Molecular Formula
C38H37FeNP210*
Formula Weight
625.5
MOL File
74311-56-1.mol
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(R)-(S)-BPPFA Property

Melting point:
143-144 °C(lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
solid
color 
Light yellow to Brown
optical activity
[α]20/D 350°, c = 0.5 in chloroform
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D2537
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Purity
>98.0%(GC)
Packaging
100mg
Price
$85
Updated
2024/03/01
TRC
Product number
B676690
Product name
(-)-(R)-(S)-BPPFA
Packaging
1g
Price
$685
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD59974
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Packaging
1g
Price
$840
Updated
2021/12/16
Chem-Impex
Product number
41167
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,≥98%(Chiralpurity)
Purity
≥98%(Chiralpurity)
Packaging
100MG
Price
$118.81
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD59974
Product name
(R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
Packaging
100mg
Price
$125
Updated
2021/12/16
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(R)-(S)-BPPFA Chemical Properties,Usage,Production

Uses

Ligand used in the enantioselective silylation of allylic chlorides.

Uses

(-)-(R)-(S)-BPPFA is an electron-rich bulky ligand used in amination reactions of aryl halides and tosylates. Homogeneous catalyst.

(R)-(S)-BPPFA Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(S)-BPPFA Suppliers

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View Lastest Price from (R)-(S)-BPPFA manufacturers

Career Henan Chemical Co
Product
(R)-(S)-BPPFA 74311-56-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

74311-56-1, (R)-(S)-BPPFARelated Search:

Cinchonidine (S)-(R)-BPPFA (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE (R)-(S)-BPPFA (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(2-METHYLPHENYL)PHOSPHINO]FERROCENE

  • (R)-(S)-BPPFA
  • (-)-(R)-N,N-DIMETHYL-1-[(S)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
  • (-)-(R)-N,N-dimethyl-1-((S)-1',2-bis(di-phenylpho
  • (-)-(R)-N,N-DIMETHYL-1-((S)-1',2-BIS(DI- PHENYLPHOSPHINO)FERROCENYL)ET-AMIN,95%
  • (R)-N,N-Dimethyl-1-((S)-1',2-bis(diphenylphosphino
  • [r,r]-1-[1-dimethylaminoethyl]-1',2-bis[diphenylphosphino]ferrocene
  • N,N-dimethyl-1-[1,2-bis(diphenylphosphino)ferrocenyl]ethyl
  • (2S)-1-[(1R)-1-(Dimethylamino)ethyl]-1',2-bis(diphenylphosphino)ferrocene
  • Ferrocene,1-[(1R)-1-(dimethylamino)ethyl]-1',2-bis(diphenylphosphino)-, (2S)-
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine,98%
  • )-(R)-N,N-Dimethyl-1-[(S)-1
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine&gt
  • (-)-(R)-(S)-BPPFA
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferroceny...
  • (-)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino
  • (-)-(|R|)-|N|，|N|-Dimethyl-1-[(S)-1'，2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (R)-N,N-Dimethyl-1-[(Rp)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • (R)-N,N-Dimethyl-1-[(S)-1',2-bis(diphenylphosphino)ferrocenyl]ethylamine
  • 74311-56-1
  • C38H37FeNP2
  • Chiral Catalysts, Ligands, and Reagents
  • Phosphine Ligands
  • Fe (Iron) Compounds
  • Ferrocenes
  • Transition Metal Compounds
  • Classes of Metal Compounds
  • Asymmetric Synthesis
  • Metallocenes
  • Other Chiral Ligands
  • Chiral Phosphine
  • Asymmetric Synthesis
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds