ChemicalBook > CAS DataBase List > 2-BROMOBENZOPHENONE

2-BROMOBENZOPHENONE

Application

Product Name: 2-BROMOBENZOPHENONE
CAS No.: 13047-06-8
Chemical Name: 2-BROMOBENZOPHENONE
Synonyms: o-Bromobenzophenone;2-BROMOBENZOPHENONE;2-BroMobenzophenone 95%;2-Bromobenzophenone >2-Bromophenyl phenyl ketone;Methanone, (2-bromophenyl)phenyl-;(2-Bromo-phenyl)-phenyl-methanone
CBNumber: CB8488653
Molecular Formula: C13H9BrO
Formula Weight: 261.11
MOL File: 13047-06-8.mol

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2-BROMOBENZOPHENONE Property

Melting point:: 42
Boiling point:: 345
Density: 1.4309 g/mL at 25 °C
refractive index: n20/D 1.6254
Flash point:: 110 °C
storage temp.: Sealed in dry,Room Temperature
solubility: soluble in Toluene
form: powder to lump
color: White to Yellow to Orange
InChI: InChI=1S/C13H9BrO/c14-12-9-5-4-8-11(12)13(15)10-6-2-1-3-7-10/h1-9H
InChIKey: ABEVIHIQUUXDMS-UHFFFAOYSA-N
SMILES: C(C1=CC=CC=C1Br)(C1=CC=CC=C1)=O
CAS DataBase Reference: 13047-06-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,N
Risk Statements: 51/53
Safety Statements: 61
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29143990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H411Toxic to aquatic life with long lasting effects
Precautionary statements: P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 682926
Product name: 2-Bromobenzophenone
Purity: 95%
Packaging: 5g
Price: $131
Updated: 2025/07/31

Sigma-Aldrich

Product number: 682926
Product name: 2-Bromobenzophenone
Purity: 95%
Packaging: 1g
Price: $33
Updated: 2023/06/20

TCI Chemical

Product number: B3937
Product name: 2-Bromobenzophenone
Purity: >97.0%(GC)
Packaging: 1g
Price: $21
Updated: 2025/07/31

TCI Chemical

Product number: B3937
Product name: 2-Bromobenzophenone
Purity: >97.0%(GC)
Packaging: 5g
Price: $82
Updated: 2025/07/31

TRC

Product number: B680603
Product name: 2-Bromobenzophenone
Packaging: 250mg
Price: $55
Updated: 2021/12/16

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2-BROMOBENZOPHENONE Chemical Properties,Usage,Production

Application

2-Bromobenzophenone can be used as an intermediate in organic synthesis and pharmaceutical research and development, and is suitable for laboratory organic synthesis and chemical and pharmaceutical synthesis processes. In organic synthesis, it can be used to prepare compounds such as N-benzoylmethylbromopyridine and unsubstituted ketone methylthiourea thiazole.

Chemical Properties

White solid

Synthesis

59142-47-1

13047-06-8

General procedure for the synthesis of 2-bromobenzyl ketone from 2-bromo-diphenylmethanol: In a pre-dried oven-dried Schlenk tube, 2-bromo-diphenylmethanol (69.0-199.5 mg, 0.5 mmol), CuI (10 mol%), 1,10-phenanthroline (20 mol%), and K3PO4 (2 mmol) were sequentially added, followed by injection of dioxane ( 2 mL). The reaction system was stirred at room temperature and under air atmosphere, and subsequently transferred to an oil bath at 80 °C to heat the reaction for 7-48 h. The reaction was carried out by thin layer chromatography (TLC). The reaction process was monitored by thin layer chromatography (TLC) until the reaction was complete. Upon completion of the reaction, the mixture was cooled to room temperature and quenched with aqueous NH4Cl, followed by extraction with CH2Cl2 (3 × 10 mL). The organic phases were combined, washed with saturated NaCl solution, dried over anhydrous Na2SO4 and filtered. The filtrate was concentrated under reduced pressure, and the resulting crude product was further purified by silica gel column chromatography (eluent: mixed system of petroleum ether/ethyl acetate) to finally obtain the target product 2-bromobenzophenone in 61-97% yields.

References

[1] Synthetic Communications, 2014, vol. 44, # 14, p. 2076 - 2087
[2] Journal of Organic Chemistry, 2014, vol. 79, # 5, p. 2059 - 2074
[3] Tetrahedron Asymmetry, 1992, vol. 3, # 7, p. 841 - 844
[4] Organic and Biomolecular Chemistry, 2018, vol. 16, # 2, p. 208 - 212
[5] Organic Letters, 2006, vol. 8, # 15, p. 3379 - 3381

2-BROMOBENZOPHENONE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-BROMOBENZOPHENONE manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: 2-BROMOBENZOPHENONE 13047-06-8
Price: US $9.00/KG
Min. Order: 1KG
Purity: 99.8%
Supply Ability: 100tons
Release date: 2024-08-20

Shaanxi Dideu Medichem Co. Ltd

Product: 2-BROMOBENZOPHENONE 13047-06-8
Price: US $4480.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 1T
Release date: 2020-06-29

Shaanxi Dideu Medichem Co. Ltd

Product: 2-BROMOBENZOPHENONE 13047-06-8
Price: US $4480.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 1T
Release date: 2020-06-29

13047-06-8, 2-BROMOBENZOPHENONERelated Search:

1-Amino-4-bromo anthraquinone 1-Methylamino-4-bromo anthraquinone 1-Amino-2,4-dibromoanthraquinone 6-bromo-3-methyl-3H-dibenz[f,ij]isoquinoline-2,7-dione 1-AMINO-4-BROMOANTHRAQUINONE-2-SULFONIC ACID SODIUM SALT Bromaminic acid 2-BROMOBENZOPHENONE 1-AMINO-4-BROMO-2-METHYLANTHRAQUINONE 4-Bromophenetole 2-AMINO-5-BROMOBENZOPHENONE 4-BROMOBENZOPHENONE,P-BROMOBENZOPHENONE,p-BROMOBENZOPHENONE pure,4-Bromobenzophenone,98% 2-AMINO-3-BROMOBENZOPHENONE 4,4'-Dibromobenzophenone 2-AMINO-2'-FLUORO-5-BROMOBENZOPHENONE 3,4-DIMETHOXY-4'-BROMOBENZOPHENONE,3,4-DIMETHOXY-4''-BROMOBENZOPHENONE 99.0% 2-AMINO-4-BROMOBENZOPHENONE,2-Amino-4&#39-bromobenzophenone,2-AMINO-4-BROMOBENZOPHENONE 95% 3-BROMOBENZOPHENONE,BromoBenzophenone,m-,m-Bromobenzophenone METHOXYPHENONE

2-BROMOBENZOPHENONE

(2-Bromo-phenyl)-phenyl-methanone

o-Bromobenzophenone

2-BroMobenzophenone 95%

2-Bromophenyl phenyl ketone

2-Bromobenzophenone &gt

Methanone, (2-bromophenyl)phenyl-

13047-06-8

13847-86-8

ARYL HALIDE

Building Blocks

Carbonyl Compounds

C13 to C14

Organic Building Blocks

Ketones

Organic Building Blocks

Building Blocks

C13 to C14

Carbonyl Compounds

Chemical Synthesis