4-Bromophenetole

Product Name: 4-Bromophenetole
CAS No.: 588-96-5
Chemical Name: 4-Bromophenetole
Synonyms: P-BROMOPHENETOLE;4-BROMOPHENETOLE;4-BROMO PHENETOL;For broMophenetole;Phenetole, p-bromo-;4-Bromophenetole>4-ETHOXYBROMOBENZENE;p-Bromoethoxybenzene;p-Ethoxybromobenzene;4-Bromoethoxybenzene
CBNumber: CB0337898
Molecular Formula: C8H9BrO
Formula Weight: 201.06
MOL File: 588-96-5.mol

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4-Bromophenetole Property

Melting point:: 4 °C (lit.)
Boiling point:: 233 °C (lit.)
Density: 1.407 g/mL at 25 °C (lit.)
refractive index: n20/D 1.551(lit.)
Flash point:: 218 °F
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform, Methanol
form: Liquid
Specific Gravity: 1.436
color: Clear colorless to yellow
Merck: 14,1428
BRN: 2042066
InChIKey: WVUYYXUATWMVIT-UHFFFAOYSA-N
CAS DataBase Reference: 588-96-5(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-bromo-4-ethoxy-(588-96-5)
EPA Substance Registry System: Benzene, 1-bromo-4-ethoxy- (588-96-5)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 24/25
WGK Germany: 3
Hazard Note: Irritant
TSCA: Yes
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 211443
Product name: 4-Bromophenetole
Purity: 98%
Packaging: 100g
Price: $65
Updated: 2025/07/31

TCI Chemical

Product number: B1434
Product name: 4-Bromophenetole
Purity: >98.0%(GC)
Packaging: 25g
Price: $38
Updated: 2025/07/31

TRC

Product number: B686150
Product name: 4-Bromophenetole
Packaging: 500g
Price: $300
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK409462
Product name: 4-Bromophenetole
Purity: 97%
Packaging: 5g
Price: $15
Updated: 2021/12/16

AK Scientific

Product number: L667
Product name: 4-Bromophenylethylether
Packaging: 25g
Price: $15
Updated: 2021/12/16

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4-Bromophenetole Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO YELLOWISH LIQUID

Uses

4-Bromophenetole is a non-irritant used to verify ocular irritability tests.

Synthesis

106-41-2

75-03-6

588-96-5

Step 1: Synthesis of 1-bromo-4-ethoxybenzene: Potassium carbonate (118 g) was added to a solution of 4-bromophenol (50 g) in acetone (250 mL) at room temperature and stirred for 30 min. Subsequently, iodoethane (67.6 g) was added slowly and dropwise. The reaction mixture was heated to reflux for 10 hours and the progress of the reaction was monitored by thin layer chromatography (TLC). After completion of the reaction, the mixture was filtered and acetone was removed using a rotary evaporator. The residue was dissolved in ethyl acetate, washed sequentially with water and saturated brine, dried over anhydrous sodium sulfate and concentrated. Purification by silica gel column chromatography with ethyl acetate and hexane (1:7) as eluents afforded 4-bromophenetole as a colorless liquid (57 g, 98.27% yield).1H NMR (CDCl3, 300 MHz): δ 7.35 (d, J = 8.7 Hz, 2H), 6.76 (d, J = 8.7 Hz, 2H), 3.99 (q, J = 6.9 Hz, 2H), 1.40 (t, J = 6.9 Hz, 3H).

References

[1] Patent: WO2012/25857, 2012, A1. Location in patent: Page/Page column 57-58
[2] Patent: US2010/331307, 2010, A1. Location in patent: Page/Page column 18
[3] Journal of the Korean Chemical Society, 2012, vol. 56, # 6, p. 706 - 711
[4] Journal of the American Chemical Society, 1931, vol. 53, p. 1408,1409
[5] Molecular Crystals and Liquid Crystals, 2004, vol. 411, p. 93/[1135]-102/[1144]

4-Bromophenetole Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromophenetole Suppliers

Americas 1 Belgium 3 Canada 1 China 257 Europe 1 France 1 Germany 5 India 28 Japan 5 Slovakia 1 Switzerland 2 The Netherlands 1 Ukraine 2 United Arab Emirates 1 United Kingdom 12 United States 37 Global 358

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TCI (Shanghai) Development Co., Ltd.

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Beijing HwrkChemical Technology Co., Ltd

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Energy Chemical

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View Lastest Price from 4-Bromophenetole manufacturers

Hebei Fengjia New Material Co., Ltd

Product: 4-Bromophenetole 588-96-5
Price: US $7.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10000
Release date: 2024-09-11

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4-Bromophenetole 588-96-5
Price: US $9.90/KG
Min. Order: 100KG
Purity: 99%
Supply Ability: 10 tons
Release date: 2025-03-14

Hebei Zhanyao Biotechnology Co. Ltd

Product: 4-Bromophenetole 588-96-5
Price: US $10.00/Kg/Bag
Min. Order: 1Kg/Bag
Purity: 99%
Supply Ability: 20 Tons
Release date: 2021-10-29

588-96-5, 4-BromophenetoleRelated Search:

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P-BROMOPHENETOLE

Benzene,1-bromo-4-ethoxy-

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p-Bromophenol ethyl ether

p-Ethoxybromobenzene

p-Ethoxyphenyl bromide

Phenetole, p-bromo-

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1-bromo-4-ethoxy-benzen

4-Bromophenetole,98%

4-Bromophenol, ethyl ether

1-Ethoxy-4-bromobenzene

Ethyl(4-bromophenyl) ether

4-Bromophenetole,97%

4-BroMophenetole, 97% 100GR

4-BroMophenetole, 97% 5GR

For broMophenetole

4-Bromophenetole≥ 99% (GC)

4-Bromophenetole&gt

4-Bromophenetole 588-96-5

4-Bromophenethyl Ether

P-bromophenethyl ether

588-96-5

588-69-5

BrC6H4OC2H5

ARYL HALIDE

Oxygen Compounds

Organic Building Blocks

Ethers

Building Blocks

alkyl bromide

Phenetole

Anisoles, Alkyloxy Compounds & Phenylacetates

Bromine Compounds