ChemicalBook > CAS DataBase List > S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM

S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM

Product Name
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
CAS No.
133545-17-2
Chemical Name
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
Synonyms
SL-A101-2;)-(6,6′(S)-(-)-MeO-BIPHEP;97% (S)-MeO-BIPHEP;-diyl)bis(diphenylphosphine);-diyl)bis(diphenylphosphine);S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM;(S)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(S)-(-)-2,3'-Bis(diphenylphosphino)-6-6'-dimethoxy-1,1'-biphenyl;(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
CBNumber
CB8502823
Molecular Formula
C38H32O2P2
Formula Weight
582.61
MOL File
133545-17-2.mol
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S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Property

Melting point:
213-216 °C
alpha 
-101 º (C=0.3 IN TOLUENE)
Boiling point:
651.1±55.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
white
BRN 
4790083
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Safety

WGK Germany 
3
8-10-23
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
29511
Product name
(S)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
Purity
≥97%, optical purity ee: ≥99%
Packaging
1g
Price
$700
Updated
2023/06/20
Sigma-Aldrich
Product number
29511
Product name
(S)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
Purity
≥97%, optical purity ee: ≥99%
Packaging
5g
Price
$3350
Updated
2023/06/20
Strem Chemicals
Product number
15-0179
Product name
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (S)-MeO-BIPHEP
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
15-0179
Product name
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (S)-MeO-BIPHEP
Packaging
500mg
Price
$355
Updated
2024/03/01
Sigma-Aldrich
Product number
29511
Product name
(S)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
Purity
≥97%, optical purity ee: ≥99%
Packaging
100g
Price
$19570
Updated
2024/03/01
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S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Preparation Products And Raw materials

Raw materials

Preparation Products

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S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Suppliers

Henan Runfeng Catalyst Co. LTD
Tel
15560227177
Fax
0373-7759608
Email
sales@runcatalysts.cn
Country
China
ProdList
111
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58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
950
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12458
Advantage
60
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
17987
Advantage
64
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
6854
Advantage
65
Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
18521735133 18521732826;
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25015
Advantage
65
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10658
Advantage
60
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View Lastest Price from S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM manufacturers

Career Henan Chemical Co
Product
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM 133545-17-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

133545-17-2, S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIMRelated Search:


  • S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
  • (S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(S)-MeO-BIPHEP
  • (S)-(-)-MeO-BIPHEP, SL-A101-2, (S)-(-)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(S)-MeO-BIPHEP
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (S)-MeO-BIPHEP
  • (S)-(-)-2,3'-Bis(diphenylphosphino)-6-6'-dimethoxy-1,1'-biphenyl
  • (S)-(-)-MeO-BIPHEP
  • SL-A101-2
  • (S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99%
  • (R)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine)
  • -diyl)bis(diphenylphosphine)
  • 97% (S)-MeO-BIPHEP
  • 1,1'-[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine
  • Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl-
  • (S)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny
  • )-(6,6&#8242
  • -diyl)bis(diphenylphosphine)
  • (S)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
  • 133545-17-2
  • Chiral Phosphine
  • MeOBIPHEP Series