METHYLTRIPHENOXYPHOSPHONIUM IODIDE

Product Name: METHYLTRIPHENOXYPHOSPHONIUM IODIDE
CAS No.: 17579-99-6
Chemical Name: METHYLTRIPHENOXYPHOSPHONIUM IODIDE
Synonyms: methyl(triphenoxy)phosphanium;Triphenylphosphine Methiodide;Methyltriphenoxyphosphorus(1+);TRIPHENYL PHOSPHITE METHIODIDE;TRIPHENYL PHOSPHITE METHOIODIDE;METHYLTRIPHENOXYPHOSPHONIUM IODIDE;Methyltriphenoxyphosphorus(1+) Iodide;Methyltriphenoxyphosphonium iodide,95%;Methyltriphenoxyphosphonium iodide 96%;Phosphorus(1+), methyltriphenoxy-, iodide (1:1), (T-4)-
CBNumber: CB8686334
Molecular Formula: C19H18IO3P
Formula Weight: 452.22
MOL File: 17579-99-6.mol

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METHYLTRIPHENOXYPHOSPHONIUM IODIDE Property

Melting point:: 142-146 °C(lit.)
storage temp.: 0-6°C
solubility: Chloroform (Slightly), DMSO (Slightly, Sonicated), Methanol (Sparingly)
form: solid
color: Dark Orange to Very Dark Brown
BRN: 3580189
Stability:: Hygroscopic, Moisture Sensitive

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 22-24/25
WGK Germany: 3
F: 3-8-10
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 226432
Product name: Methyltriphenoxyphosphonium iodide
Purity: 96%
Packaging: 10g
Price: $54
Updated: 2024/03/01

Sigma-Aldrich

Product number: 226432
Product name: Methyltriphenoxyphosphonium iodide
Purity: 96%
Packaging: 50g
Price: $257
Updated: 2024/03/01

Usbiological

Product number: 282861
Product name: Methyltriphenoxyphosphonium iodide
Packaging: 2g
Price: $396
Updated: 2021/12/16

TRC

Product number: M330990
Product name: Methyltriphenoxyphosphonium iodide
Packaging: 100g
Price: $970
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0004505
Product name: METHYLTRIPHENOXYPHOSPHONIUM IODIDE
Purity: 95.00%
Packaging: 10G
Price: $1187.53
Updated: 2021/12/16

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METHYLTRIPHENOXYPHOSPHONIUM IODIDE Chemical Properties,Usage,Production

Chemical Properties

Yellow-Brownish Solid

Uses

Methyltriphenoxyphosphonium Iodide is used in the transformation of the 5’-hydroxyl group in nucleosides to the 5’-deoxy-5’-iodo group.

Uses

Used in the transformation of the 5′-hydroxyl group in nucleosides to the 5′-deoxy-5′-iodo group.

Uses

Methyltriphenoxyphosphonium Iodide is used in the transformation of the 5?hydroxyl group in nucleosides to the 5?deoxy-5?iodo group

Purification Methods

Gently heat the impure iodide with good grade Me2CO. The saturated solution obtained is decanted rapidly from undissolved salt and treated with an equal volume of dry Et2O. The iodide separates as flat needles which are collected by centrifugation, washed several times with dry Et2O, and dried in a vacuum over P2O5. For this recrystallisation it is essential to minimise the time of contact with Me2CO and to work rapidly and with rigorous exclusion of moisture. If the crude material is to be used, it should be stored under dry Et2O, and dried and weighed in vacuo immediately before use. [Landauer & Rydon J Chem Soc 224 1953, Hudson et al. J Chem Soc Perkin Trans 1 982 1974, Beilstein 6 IV 704.]

METHYLTRIPHENOXYPHOSPHONIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYLTRIPHENOXYPHOSPHONIUM IODIDE Suppliers

Belgium 1 Canada 2 China 16 Germany 1 India 2 Japan 1 Switzerland 2 United Kingdom 1 United States 7 Global 33

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17579-99-6, METHYLTRIPHENOXYPHOSPHONIUM IODIDERelated Search:

PHOSPHONIUM IODIDE Triphenyl phosphite METHYL DIPHENYLPHOSPHITE METHYLTRIPHENOXYPHOSPHONIUM IODIDE

Methyltriphenoxyphosphonium iodide 96%

TRIPHENYL PHOSPHITE METHIODIDE

TRIPHENYL PHOSPHITE METHOIODIDE

METHYLTRIPHENOXYPHOSPHONIUM IODIDE

Methyltriphenoxyphosphorus(1+) Iodide

Triphenylphosphine Methiodide

Methyltriphenoxyphosphonium iodide,95%

Methyltriphenoxyphosphorus(1+)

Phosphorus(1+), methyltriphenoxy-, iodide (1:1), (T-4)-

methyl(triphenoxy)phosphanium

17579-99-6

C19H18IO3P

C19H18O3PI

CH3PIOC6H53

Synthetic Reagents

C-X Bond Formation (Halogen)

Iodination

Phosphorylating and Phosphitylating Agents