Dicarbonylacetylacetonato rhodium(I)

Reaction

Product Name: Dicarbonylacetylacetonato rhodium(I)
CAS No.: 14874-82-9
Chemical Name: Dicarbonylacetylacetonato rhodium(I)
Synonyms: Dicarbonylacetylacet;acetonato)dicarbonyL;Rhodium (Acac)Carbonyl - CARAC;Dicarbonylacetylacetonatorhodium;Acetylacetonatodicarbonylrhodium;Rhodium dicarbonylacetylacetonate;Dicarbonylrhodium acetylacetonate;Acetylacetonatorhodium dicarbonyl;Rhodium bis(carbonyl)acetyl acetone;Dicarbonyl-(2,4-pentandione)-rhodium
CBNumber: CB8698018
Molecular Formula: C7H7O4Rh
Formula Weight: 258.03
MOL File: 14874-82-9.mol

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Dicarbonylacetylacetonato rhodium(I) Property

Melting point:: 154-156 °C (lit.)
Density: 1.96[at 20℃]
vapor pressure: 0.13Pa at 25℃
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in acetone
form: Needles or Flakes
color: Greenish-red
Water Solubility: insoluble
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
LogP: 0.4 at 20℃
NIST Chemistry Reference: Rhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9)
EPA Substance Registry System: Rhodium, dicarbonyl(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (SP-4-2)- (14874-82-9)

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Safety

Hazard Codes: Xi,F,T
Risk Statements: 36/37/38-44-43-25
Safety Statements: 26-37/39-45-36/37/39-24/25
RIDADR: 3282
WGK Germany: 3
TSCA: No
HazardClass: 6.1
PackingGroup: III
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H228Flammable solid

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 683183
Product name: (Acetylacetonato)dicarbonylrhodium(I)
Purity: 98%
Packaging: 2g
Price: $1180
Updated: 2024/03/01

Sigma-Aldrich

Product number: 288101
Product name: (Acetylacetonato)dicarbonylrhodium(I)
Purity: 98%
Packaging: 1g
Price: $597
Updated: 2024/03/01

Alfa Aesar

Product number: 039295
Product name: Dicarbonyl(2,4-pentanedionato)rhodium(I), 99%
Packaging: 250mg
Price: $234
Updated: 2023/06/20

Alfa Aesar

Product number: 039295
Product name: Dicarbonyl(2,4-pentanedionato)rhodium(I), 99%
Packaging: 1g
Price: $919
Updated: 2023/06/20

Strem Chemicals

Product number: 45-0700
Product name: Dicarbonylacetylacetonato rhodium(I), 99%
Packaging: 250mg
Price: $215
Updated: 2024/03/01

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Dicarbonylacetylacetonato rhodium(I) Chemical Properties,Usage,Production

Reaction

Precatalyst for hydroformylation of olefins.
Precatalyst for silylformylation of olefins.
Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids.
Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones.

Chemical Properties

Red/Green Crystalline Powder

Uses

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.

Uses

Employed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering.

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds

Flammability and Explosibility

Flammable

Dicarbonylacetylacetonato rhodium(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dicarbonylacetylacetonato rhodium(I) Suppliers

Belgium 2 China 162 Germany 6 India 6 Japan 1 Singapore 1 Switzerland 1 United Kingdom 3 United States 15 Global 197

Shandong Carbene New Material Technology Co., Ltd

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Fax: 86-21-61259102
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Alfa Aesar

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Beijing HwrkChemical Technology Co., Ltd

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Chemsky（shanghai）International Co.,Ltd.

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Sinopharm Chemical Reagent Co,Ltd.

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View Lastest Price from Dicarbonylacetylacetonato rhodium(I) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: Dicarbonylacetylacetonato rhodium(I) 14874-82-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: Dicarbonylacetylacetonato rhodium(I) 14874-82-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-07-03

14874-82-9, Dicarbonylacetylacetonato rhodium(I)Related Search:

Chloroplantinic acid Tris(triphenylphosphine)rhodiu Platinum dioxide Palladium (II) Acetate Rhodium (triphenylphosphine)carbonylacetylacetonate Rhodium(III) 2,4-pentanedionate VANADIUM(III) ACETYLACETONATE Ferric acetylacetonate Bis(acetylacetonato)cobalt Zinc(II) acetylacetonate Acetylacetone ZIRCONIUM(IV) ACETYLACETONATE Rhodium Aluminum acetylacetonate titanium (Ⅳ) acetylacetonate CARBON MONOXIDE Dicarbonylacetylacetonato rhodium(I) copper (Ⅱ) acetylacetonate

DICARBONYLACETYLACETONATO RHODIUM(I)

DICARBONYLRHODIUM(I) 2,4-PENTANEDIONATE

Acetylacetonatorhodium(I) dicarbonyl~Dicarbonyl(2,4-pentanedionato)rhodium(I)

Dicarbonyl-(2,4-pentandione)-rhodium

Dicarbonyl(2,4-pentanedionato)rhodium

Dicarbonylacetylacetonatorhodium

Dicarbonylrhodium acetylacetonate

Rhodium dicarbonylacetylacetonate

Rhodium, dicarbonyl(2,4-pentanedionato)-

Rhodium, dicarbonyl(2,4-pentanedionato-O,O')-

RHODIUM I DICARBONYL 2,4-PENTANEDIONATE

RHODIUM(I) DICARBONYL ACETYLACETONATE

RHODIUM DICARBONYL-2,4-PENTANEDIONATE

(ACETYLACETONATO)DICARBONYLRHODIUM(I)

dicarbonyl(pentane-2,4-dionato-O,O')rhodium

Dicarbonylacetylacet

Acetylacetonatodicarbonylrhodium

Acetylacetonatorhodium dicarbonyl

Dicarbonylacetylacetonato rhodiuM(I),98%

(Acetylacetonato)dicarbonylrhodium(Ⅰ)

(Acetylacetonato)dicarbonylrhodiuM(Ⅰ), 40% Rh, Product of UMicore

(Acetylacetonate group) two carbon-based iridiuM (I)

Dicarbonylacetylacetonatorhodium(I),99%

dicarbonyl-2,4-pentanedionatorhodium(i)

(ACETYLACETONATO)DICARBONYLRHODIUM(I), 9 8%

2,4-Pentanedionatodicarbonyl rhodium

(Actylacetatonato) dicarbonylrhodium (I)

(Acetylacetonato)dicarbonylrhodium (I), min. 99% (Rh-50, #209050)

Dicarbonyl-acetylacetonato-rhodium(I), Dicarbonylrhodium(I) 2,4-pentanedionate, Rhodium(I) dicarbonyl acetylacetonate

Dicarbonylrhodium(I) 2,4-pentanedionate, Rhodium(I) dicarbonyl acetylacetonate

Acetylacetonatodicarbonylrhodium(I) Dichroic green-red crystals sublm. 144-147

(Acetylacetonato)dicarbonylrhodium(I), 40% Rh, Product of Umicore

acetonato)dicarbonyL

(Acetylacetonato)dicarbonylrhodium(I) “CARAC”

Dicarbonylacetylacetonato rhodium(I) ISO 9001：2015 REACH

Rhodium (Acac)Carbonyl - CARAC

Rhodium bis(carbonyl)acetyl acetone

14874-82-9

C7H7RhO4

C7H7O4Rh

RhC5H7O2CO2

RhCO2C5H7O2

RhCO2acac

C7H11O4Rh

Catalysis and Inorganic Chemistry

Rh

metal carbonyl complexes

chemical reaction,pharm,electronic,materials