ChemicalBook > CAS DataBase List > Dicarbonylacetylacetonato rhodium(I)
Dicarbonylacetylacetonato rhodium(I)
Reaction- Product Name
- Dicarbonylacetylacetonato rhodium(I)
- CAS No.
- 14874-82-9
- Chemical Name
- Dicarbonylacetylacetonato rhodium(I)
- Synonyms
- Dicarbonylacetylacet;acetonato)dicarbonyL;Rhodium (Acac)Carbonyl - CARAC;Dicarbonylacetylacetonatorhodium;Acetylacetonatodicarbonylrhodium;Rhodium dicarbonylacetylacetonate;Dicarbonylrhodium acetylacetonate;Acetylacetonatorhodium dicarbonyl;Rhodium bis(carbonyl)acetyl acetone;Dicarbonyl-(2,4-pentandione)-rhodium
- CBNumber
- CB8698018
- Molecular Formula
- C7H7O4Rh
- Formula Weight
- 258.03
- MOL File
- 14874-82-9.mol
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Dicarbonylacetylacetonato rhodium(I) Property
- Melting point:
- 154-156 °C (lit.)
- Density
- 1.96[at 20℃]
- vapor pressure
- 0.13Pa at 25℃
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in acetone
- form
- Needles or Flakes
- color
- Greenish-red
- Water Solubility
- insoluble
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 - LogP
- 0.4 at 20℃
- NIST Chemistry Reference
- Rhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9)
- EPA Substance Registry System
- Rhodium, dicarbonyl(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (SP-4-2)- (14874-82-9)
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Safety
- Hazard Codes
- Xi,F,T
- Risk Statements
- 36/37/38-44-43-25
- Safety Statements
- 26-37/39-45-36/37/39-24/25
- RIDADR
- 3282
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 28439000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H228Flammable solid
H317May cause an allergic skin reaction
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 683183
- Product name
- (Acetylacetonato)dicarbonylrhodium(I)
- Purity
- 98%
- Packaging
- 2g
- Price
- $1180
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 288101
- Product name
- (Acetylacetonato)dicarbonylrhodium(I)
- Purity
- 98%
- Packaging
- 1g
- Price
- $597
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 039295
- Product name
- Dicarbonyl(2,4-pentanedionato)rhodium(I), 99%
- Packaging
- 250mg
- Price
- $234
- Updated
- 2023/06/20
Alfa Aesar
- Product number
- 039295
- Product name
- Dicarbonyl(2,4-pentanedionato)rhodium(I), 99%
- Packaging
- 1g
- Price
- $919
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 45-0700
- Product name
- Dicarbonylacetylacetonato rhodium(I), 99%
- Packaging
- 250mg
- Price
- $215
- Updated
- 2024/03/01
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Dicarbonylacetylacetonato rhodium(I) Chemical Properties,Usage,Production
Reaction
- Precatalyst for hydroformylation of olefins.
- Precatalyst for silylformylation of olefins.
- Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids.
- Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones.
Chemical Properties
Red/Green Crystalline Powder
Uses
(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.
Uses
Employed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering.
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds
Flammability and Explosibility
Flammable
Dicarbonylacetylacetonato rhodium(I) Preparation Products And Raw materials
Raw materials
Preparation Products
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Dicarbonylacetylacetonato rhodium(I) Suppliers
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View Lastest Price from Dicarbonylacetylacetonato rhodium(I) manufacturers
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- Dicarbonylacetylacetonato rhodium(I) 14874-82-9
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
Career Henan Chemical Co
- Product
- Dicarbonylacetylacetonato rhodium(I) 14874-82-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-07-03
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