ChemicalBook > CAS DataBase List > Chromocene

Chromocene

Product Name
Chromocene
CAS No.
1271-24-5
Chemical Name
Chromocene
Synonyms
CHROMOCENE;Chromocene,95%;Bis(cyclopentadienyl)chrom;dicyclopentadienyl-chromiu;dicyclopentadienylchromium;bis(cyclopentadiene)chromium;Bis(cyclopentadienyl)cadmium;BIS(CYCLOPENTADIENYL)CHROMIUM;di-pi-cyclopentadienyl-chromiu;Chromocene ISO 9001:2015 REACH
CBNumber
CB8708085
Molecular Formula
C10H10Cr10*
Formula Weight
182.18
MOL File
1271-24-5.mol
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Chromocene Property

Melting point:
168-170 °C(lit.)
storage temp. 
Store below +30°C.
form 
crystal
color 
scarlet
Water Solubility 
Insoluble in water.
Sensitive 
Air & Moisture Sensitive
NIST Chemistry Reference
Bis(«eta»5-cyclopentadienyl) chromium(1271-24-5)
EPA Substance Registry System
Chromocene (1271-24-5)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
RIDADR 
1325
WGK Germany 
3
RTECS 
GB7600000
TSCA 
Yes
HazardClass 
4.2
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
381004
Product name
Bis(cyclopentadienyl)chromium(II)
Purity
95%
Packaging
1g
Price
$134
Updated
2024/03/01
Alfa Aesar
Product number
043177
Product name
Bis(cyclopentadienyl)chromium, sublimed, 97+%
Packaging
1g
Price
$125.65
Updated
2024/03/01
Alfa Aesar
Product number
043177
Product name
Bis(cyclopentadienyl)chromium, sublimed, 97+%
Packaging
5g
Price
$461.65
Updated
2024/03/01
Strem Chemicals
Product number
24-0135
Product name
Bis(cyclopentadienyl)chromium, min. 95%, sublimed (Chromocene)
Packaging
1g
Price
$115
Updated
2024/03/01
Strem Chemicals
Product number
24-0135
Product name
Bis(cyclopentadienyl)chromium, min. 95%, sublimed (Chromocene)
Packaging
5g
Price
$457
Updated
2024/03/01
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Chromocene Chemical Properties,Usage,Production

Chemical Properties

bordeaux crystalline powder

Uses

Provides catalyst for ethylene polymerization. A precursor to other chromium(II) compounds.

General Description

Red needles or reddish-purple solid.

Air & Water Reactions

Chromocene is very sensitive to exposure to air and moisture (decomposition is not vigorous). Decomposes in water .

Reactivity Profile

Chromocene reacts with water and alcohols. . It's reaction with alcohols produces pyrophoric metal alkoxides (dialkoxychromium and cyclopentadiene).

Fire Hazard

Literature sources indicate that Chromocene is flammable.

Purification Methods

Chromocene forms pyrophoric red crystals on sublimation at 50o/0.1mm followed by resublimation at 75-90o/0.1mm. Although it is stable at least to 300o, it is readily oxidised in air, and effervesces slowly in H2O to give cyclopentadiene. All operations should be carried out in a dry box. It decomposes in CCl4 or CS2, and for IR even grinding with nujol, KBr or KI causes some decomposition. [Wilkinson et al. J Inorg Nucl Chem 95 109 1956, Wilkinson J Am Chem Soc 76 209 1954, Beilstein 16 IV 1774.]

Chromocene Preparation Products And Raw materials

Raw materials

Preparation Products

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Chromocene Suppliers

DALCHEM
Tel
--
Fax
--
Email
info@dalchem.nnov.ru
Country
Russia
ProdList
705
Advantage
64
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View Lastest Price from Chromocene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Chromocene 1271-24-5
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10000KG
Release date
2024-08-09
Career Henan Chemical Co
Product
Chromocene 1271-24-5
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg , 5kg, 50kg
Release date
2020-01-17

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