ChemicalBook > CAS DataBase List > (1-PHENYL-1-TOSYL)METHYL ISOCYANIDE

(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE

Product Name
(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE
CAS No.
36635-66-2
Chemical Name
(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE
Synonyms
SKL019;A-TOSYLBENZYL ISOCYANIDE;alfa-Tosylbenzylisocyanide;ALPHA-TOSYLBENZYL ISOCYANIDE;a-(4-Tolylsulfonyl)benzylisocyanide;(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE;α-(p-Toluenesulfonyl)benzyl Isocyanide;α-(p-Toluenesulfonyl)benzyl Isocyanide;alpha-(p-Toluenesulfonyl)benzyl Isocyanide;alpha-(Toluene-4-sulphonyl)benzyl isocyanide
CBNumber
CB8709143
Molecular Formula
C15H13NO2S
Formula Weight
271.33
MOL File
36635-66-2.mol
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(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE Property

Melting point:
106 °C(dec.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
powder to crystal
color 
White to Light yellow to Light orange
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Safety

Hazard Codes 
Xi
Hazard Note 
Irritant
HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T3157
Product name
α-(p-Toluenesulfonyl)benzyl Isocyanide
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$554
Updated
2024/03/01
TCI Chemical
Product number
T3157
Product name
α-(p-Toluenesulfonyl)benzyl Isocyanide
Purity
>98.0%(HPLC)(N)
Packaging
5g
Price
$1686
Updated
2024/03/01
TRC
Product number
P399218
Product name
(1-Phenyl-1-tosyl)methylIsocyanide
Packaging
100mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
8663-1-Y4
Product name
Isocyano(phenyl)methyl 4-methylphenyl sulfone
Packaging
1g
Price
$60
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
COR0003729
Product name
(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE
Purity
95.00%
Packaging
1G
Price
$177.45
Updated
2021/12/16
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(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE Chemical Properties,Usage,Production

Preparation

A 1-L, three-necked, roundbottomed flask fitted with an overhead stirrer, a 100 mL addition funnel, and a temperature probe was charged with THF (200 mL) and 1615 (27.6 g, 94.8 mmol). Phosphoryl chloride (17.7 mL, 190 mmol) was added and the resulting solution was stirred for 5 min at 25 C??. After cooling the solution to 0 C??, triethylamine (79.3 mL, 569 mmol) was added slowly over 30¨C45 min while keeping the internal reaction temperature below 10 C??. After the addition of triethylamine was complete, the reaction mixture was warmed to 5¨C10 C?? and maintained at this temperature for 30¨C45 min. Ethyl acetate (140 mL) and water (140 mL) were added sequentially to the reaction mixture, stirring was continued for 5 min, and then the mixture was transferred to a separatory funnel and the aqueous layer was removed. The organic layer was washed with water (2?á140 mL), saturated sodium hydrogen carbonate solution (140 mL), and brine (70 mL). The organic layer was transferred to a 500-mL, round-bottomed flask and concentrated on a rotary evaporator. The residue was diluted with 1-propanol (140 mL) and this solution was concentrated on a rotary evaporator to half of its original volume. The residue was cooled to 5¨C10 C?? for 30 min and the beige solid that crystallized was collected by filtration through a Buchner funnel. The filter cake was rinsed with 1-propanol (2?á75 mL). The beige solid was dried in vacuo for 3¨C4 h to give 18.1¨C19.7 g (70¨C 76%) of a-tosylbenzyl isocyanide 1616.
Structurally analogous to TosMIC 1600 is PhosMIC 1617, which has a phosphonate residue instead of a sulfonate residue. Some representatives have been described by Bartlett.

(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (1-PHENYL-1-TOSYL)METHYL ISOCYANIDE manufacturers

Career Henan Chemical Co
Product
(1-PHENYL-1-TOSYL)METHYL ISOCYANIDE 36635-66-2
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-02

36635-66-2, (1-PHENYL-1-TOSYL)METHYL ISOCYANIDERelated Search:

A-(P-TOLUENESULFONYL)-4-FLUOROBENZYLISONITRILE [1-(2-FLUOROPHENYL)-1-TOSYL]METHYL ISOCYANIDE A-TOSYL-(4-CHLOROBENZYL) ISOCYANIDE [1-(3-FLUOROPHENYL)-1-TOSYL]METHYL ISOCYANIDE [1-(3-Chlorophenyl)-1-tosyl]methyl isocyanide (1-PHENYL-1-TOSYL)METHYL ISOCYANIDE METHYL ISOCYANIDE ISOCYANO(3-METHOXYPHENYL)METHYL-4-METHYLPHENYL SULFONE [1-(3-TRIFLUOROMETHYLPHENYL)-1-TOSYL]METHYL ISOCYANIDE [1-(4-TRIFLUOROMETHYLPHENYL)-1-TOSYL]METHYL ISOCYANIDE ISOCYANO(2-METHOXYPHENYL)METHYL-4-METHYLPHENYL SULFONE 1-O-TOLYL-1-TOSYLMETHYL ISOCYANIDE 3-BROMO-1-[ISOCYANO-(TOLUENE-4-SULFONYL)-METHYL]-BENZENE 1-M-TOLYL-1-TOSYLMETHYL ISOCYANIDE 1-(2,3-DICHLOROPHENYL)-1-TOSYLMETHYL ISOCYANIDE ISOCYANO(4-METHOXYPHENYL)METHYL-4-METHYLPHENYL SULFONE A-TOSYL-(2-BROMOBENZYL) ISOCYANIDE 1-P-TOLYL-1-TOSYLMETHYL ISOCYANIDE

  • A-TOSYLBENZYL ISOCYANIDE
  • ALPHA-TOSYLBENZYL ISOCYANIDE
  • (1-PHENYL-1-TOSYL)METHYL ISOCYANIDE
  • 1-([ISOCYANO(PHENYL)METHYL]SULPHONYL)-4-METHYLBENZENE
  • alfa-Tosylbenzylisocyanide
  • alpha-(p-Toluenesulfonyl)benzyl Isocyanide
  • 1-(isocyano(p-tolyl)methylsulfonyl)-4-methylbenzene
  • Isocyano(phenyl)methyl 4-methylphenyl sulphone
  • Benzene,1-[(isocyanophenylMethyl)sulfonyl]-4-Methyl-
  • alpha-(Toluene-4-sulphonyl)benzyl isocyanide
  • a-(4-Tolylsulfonyl)benzylisocyanide
  • alpha-(Toluene-4-sulphonyl)benzyl isocyanide, 4-{[Isocyano(phenyl)methyl]sulphonyl}toluene, alpha-Tosylbenzyl isocyanide
  • Isocyano(phenyl)methyl 4-methylphenyl sulphone 97%
  • 1-(Isocyano-phenyl-Methanesulfonyl)-4-Methyl-benzene
  • 1-((Isocyano(phenyl)methyl)sulfonyl)-4-methylbenzene
  • Isocyano(phenyl)methyl4-methylphenylsulphone97%
  • -(<i>p</i>-Toluenesulfonyl)benzyl Isocyanide
  • α-(p-Toluenesulfonyl)benzyl Isocyanide
  • 5-(isocyanomethylsulfonyl)-2-methyl-5-phenylcyclohexa-1,3-diene
  • Isocyano(phenyl)methyl 4-methylphenyl sulfone
  • SKL019
  • α-(p-Toluenesulfonyl)benzyl Isocyanide
  • 36635-66-2
  • C15H13NO2S
  • pharmacetical