ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE

Product Name: ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE
CAS No.: 84028-88-6
Chemical Name: ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE
Synonyms: ethyl (S)-lactate triflate;ETHYL L-LACTATE 2-O-TRIFLATE;ETHYL L-LACTATE TRIFLUOROMETHANESULFONATE;ETHYL O-TRIFLUOROMETHANESULFONYL-L-LACTATE;ethyle(S)-2-(trifluoromethylsulfonyloxy)propionate;ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE;(S)-Ethyl 2-(((trifluoromethyl)sulfonyl)oxy)propanoate;Ethyl (S)-2-(((trifluoromethyl)sulfonyl)oxy)propanoate;ETHYL (S)-(-)-2-[(TRIFLUOROMETHYLSULFONYL)OXY]PROPIONATE;Ethyl (S)-2-(trifluoromethylsulfonyloxy)propionate
CBNumber: CB8727352
Molecular Formula: C6H9F3O5S
Formula Weight: 250.19
MOL File: 84028-88-6.mol

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ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE Property

Boiling point:: 34 °C/0.005 mmHg (lit.)
Density: 1.342 g/mL at 25 °C (lit.)
refractive index: n20/D 1.374(lit.)
Flash point:: 174 °F
storage temp.: -20°C
form: Liquid
color: Clear to cloudy colorless to pink to brown
optical activity: [α]20/D 44°, neat
BRN: 3549394
InChI: 1S/C6H9F3O5S/c1-3-13-5(10)4(2)14-15(11,12)6(7,8)9/h4H,3H2,1-2H3/t4-/m0/s1
InChIKey: RYSBPHXTNVWICH-BYPYZUCNSA-N
SMILES: CCOC(=O)[C@H](C)OS(=O)(=O)C(F)(F)F

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3265 8/PG 3
WGK Germany: 3
F: 10-21
Storage Class: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Skin Corr. 1B

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 374636
Product name: Ethyl (S)-2-(trifluoromethylsulfonyloxy)propionate
Purity: ≥96%
Packaging: 1g
Price: $235
Updated: 2023/06/20

American Custom Chemicals Corporation

Product number: HCH0066793
Product name: ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE
Purity: 95.00%
Packaging: 1G
Price: $707.64
Updated: 2021/12/16

AHH

Product number: MT-12642
Product name: Ethylo-trifluoromethanesulfonyl-L-lactate
Purity: 96%
Packaging: 10g
Price: $328
Updated: 2021/12/16

Crysdot

Product number: CD13003588
Product name: (S)-Ethyl2-(((trifluoromethyl)sulfonyl)oxy)propanoate
Purity: 97%
Packaging: 5g
Price: $877
Updated: 2021/12/16

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ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE Chemical Properties,Usage,Production

Uses

Ethyl (S)-2-(trifluoromethylsulfonyloxy)propionate can be used:

In the synthesis of tetra-methylated analog of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTMA) based chelates for imaging applications.
As a substrate in the synthesis of α-silylated carboxyl compounds via Cu-catalyzed stereoinvertive nucleophilic silylation of α-triflyloxy esters.

ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE Suppliers

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84028-88-6, ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATERelated Search:

Ethyl L(-)-lactate Methyl trifluoromethanesulfonate 4-PHENYL-2-(S)-TRIFLUOROMETHANESULFONYLOXY-BUTYRIC ACID, ETHYL ESTER Ethyl trifluoromethanesulfonate ETHYL (S)-(-)-2-((METHYLSULFONYL)OXY)-PROPIONATE, TECH., 90 ISOPROPYL TRIFLUOROMETHANESULFONATE ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE

ETHYL O-TRIFLUOROMETHANESULFONYL-L-LACTATE

ETHYL (S)-(-)-2-[(TRIFLUOROMETHYLSULFONYL)OXY]PROPIONATE

ETHYL (S)-2-(TRIFLUOROMETHYLSULFONYLOXY)PROPIONATE

ETHYL L-LACTATE 2-O-TRIFLATE

ETHYL L-LACTATE TRIFLUOROMETHANESULFONATE

ETHYL (S)-(-)-2-((TRIFLUOROMETHYL-SULFON YL)OXY)PROPIONATE, 96+%

Ethyl O-trifluoromethanesulfonyl-L-lactate, Ethyl L-lactate 2-O-triflate

ethyl (S)-lactate triflate

ethyle(S)-2-(trifluoromethylsulfonyloxy)propionate

Propanoic acid, 2-[[(trifluoromethyl)sulfonyl]oxy]-, ethyl ester, (2S)-

(S)-Ethyl 2-(((trifluoromethyl)sulfonyl)oxy)propanoate

Ethyl (S)-2-(((trifluoromethyl)sulfonyl)oxy)propanoate

Ethyl (<i>S</i>)-2-(trifluoromethylsulfonyloxy)propionate

84028-88-6

CH3CHOSO2CF3CO2C2H5

C6H9F3O5S

Chiral Building Blocks

Asymmetric Synthesis

Esters

Organic Building Blocks