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Tetradecanal

Product Name
Tetradecanal
CAS No.
124-25-4
Chemical Name
Tetradecanal
Synonyms
TETRADECANAL;MYRISTALDEHYDE;MYRISTYL ALDEHYDE;MYRISTIC ALDEHYDE;1-tetradecylaldehyde;1-Tetradecyl aldehyde;ALDEHYDE C-14 MYRISTIC;FEMA 2763;NSC 66435;etradecanal
CBNumber
CB8727473
Molecular Formula
C14H28O
Formula Weight
212.37
MOL File
124-25-4.mol
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Tetradecanal Property

Melting point:
23°C(lit.)
Boiling point:
166°C/24mmHg(lit.)
Density 
0.8278
refractive index 
1.4410
FEMA 
2763 | MYRISTALDEHYDE
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form 
Solid
color 
White to Dark Orange
Odor
at 100.00 %. fatty waxy amber incense dry citrus peel musk
Odor Type
waxy
JECFA Number
112
InChI
InChI=1S/C14H28O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h14H,2-13H2,1H3
InChIKey
UHUFTBALEZWWIH-UHFFFAOYSA-N
SMILES
C(=O)CCCCCCCCCCCCC
LogP
6.01
EPA Substance Registry System
Tetradecanal (124-25-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RTECS 
XB7900000
HS Code 
2912190090
Toxicity
The acute oral LD50 value was reported as > 5Og/kg in the rat . The acute dermal LD50 for sample no. 71-17 was reported to be > 10 g/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T2696
Product name
Tetradecanal
Purity
>96.0%(GC)
Packaging
1g
Price
$368
Updated
2024/03/01
TRC
Product number
T291440
Product name
Tetradecanal
Packaging
500mg
Price
$65
Updated
2021/12/16
TRC
Product number
T291440
Product name
Tetradecanal
Packaging
25g
Price
$215
Updated
2021/12/16
Chem-Impex
Product number
39114
Product name
Tetradecanal,≥96%(GC)
Purity
≥96%(GC)
Packaging
1G
Price
$401.86
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
53095
Product name
Tetradecanal
Packaging
25g
Price
$1050
Updated
2021/12/16
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Tetradecanal Chemical Properties,Usage,Production

Description

Myristaldehyde (Tetradecanal) has a strong, fatty, orris-like odor with a sweet, fatty, “citrus-peel” flavor (diluted). Industrially prepared from the corresponding myristic acid.

Chemical Properties

Myristaldehyde (Tetradecanal) has a strong, fatty, orris-like odor and a sweet, fatty, “citrus-peel” flavor (diluted)

Chemical Properties

White Semi-Solid

Occurrence

Tetradecanal is reported found in the essential oils of Ocotea usambarensis Engl., Pinus sabiniana Dougl.; also reported found in kumquat peel, ginger, chicken fat, hop oil, apricot, citrus peel oils and juices, bilberry, blackberry, cucumber, cassia leaf, butter, parmesan cheese, milk powder, cooked chicken, beef, cured pork, beer, peanuts, trassi, coriander leaf, dried bonito, cherimoya, mountain papaya, scallop and angelica root oil.

Uses

A major component of the essential oil found in the leaves of Azadirachta indica.

Definition

ChEBI: A long-chain fatty aldehyde that is tetradecane in which two hydrogens attached to a terminal carbon are replaced by an oxo group. It is found in coriander.

Preparation

Industrially prepared from the corresponding myristic acid

Taste threshold values

Taste characteristics at 10 ppm: fatty, lactonic, coconut, woody and fishy with a fruity nuance

Synthesis Reference(s)

Canadian Journal of Chemistry, 46, p. 75, 1968 DOI: 10.1139/v68-013

Synthesis

A solution of oxalylchloride (8.0 mL, 88.0 mmol, 2.2 eq.) in abs. dichloromethane (200 mL) was treated with DMSO (13.6 mL, 192 mmol, 4.8 eq.) at -60 °C. After 3 min, the reaction mixture was warmed to approx. 15 °C. Then a solution of tetradecan-1-ol (8.56 g, 40.0 mmol) in dry dichloromethane (40 mL) and after a further 3 min triethylamine (28 mL, 200 mmol, 5.0 eq.) was added. Then, the reaction mixture was slowly warmed to 5 °C and quenched with the addition of water (200 mL). The phases were separated, and the aqueous phase was extracted with dichloromethane (3 χ 100 mL). The combined organic phases were washed with brine (1 χ 200 mL) and dried over MgS04. The solvent was removed under reduced pressure, and the product was isolated as a white solid Tetradecanal, which was used in the next reaction without purification—yield: 10.4 g (100%), purity: 98% (GC).

Metabolism

See monograph on aldehyde C-8*

Tetradecanal Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetradecanal Suppliers

Toronto Research Chemicals
Tel
--
Fax
--
Email
info@trc-canada.com
Country
Canada
ProdList
6038
Advantage
71
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View Lastest Price from Tetradecanal manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Tetradecanal 124-25-4
Price
US $99.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-12-19
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetradecanal 124-25-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%min
Supply Ability
5000kg/month
Release date
2024-07-12
JINING XINHE CHEMICAL CO., LTD
Product
Tetradecanal 124-25-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10ton
Release date
2024-07-22

124-25-4, TetradecanalRelated Search:


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