Allyl acetate

Product Name: Allyl acetate
CAS No.: 591-87-7
Chemical Name: Allyl acetate
Synonyms: 2-Propenyl acetate;ALLYL ACETATE;acetated’allyle;AllylAcetate99%;3-Acetoxypropene;PROPENYL ACETATE;Allyl acetate 99%;Allyl Acetate >Allyl acetate, 98%+;3-acetoxy-1-propene
CBNumber: CB8746311
Molecular Formula: C5H8O2
Formula Weight: 100.12
MOL File: 591-87-7.mol

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Allyl acetate Property

Melting point:: 6°C
Boiling point:: 103-104 °C (lit.)
Density: 0.928 g/mL at 25 °C (lit.)
vapor pressure: 27.2 hPa (20 °C)
refractive index: n20/D 1.404(lit.)
Flash point:: 44 °F
storage temp.: 2-8°C
solubility: 28g/l
form: Liquid
Specific Gravity: 0.928
color: Clear colorless
explosive limit: 2.1-13.0%(V)
Water Solubility: slightly
Merck: 14,285
BRN: 1742050
LogP: 0.970
CAS DataBase Reference: 591-87-7(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid, 2-propenyl ester(591-87-7)
EPA Substance Registry System: Acetic acid, 2-propen-1-yl ester (591-87-7)

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Safety

Hazard Codes: F,T
Risk Statements: 11-21-23/25-36-25
Safety Statements: 16-26-36-45-27
RIDADR: UN 2333 3/PG 2
WGK Germany: 3
RTECS: AF1750000
Autoignition Temperature: 705 °F
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29153990
Hazardous Substances Data: 591-87-7(Hazardous Substances Data)
Toxicity: LD50: 0.13 g/kg orally in rats; 1.1 ml/kg dermally in rabbits (Smyth); LD50 in rats, mice (mg/kg): 142, 170 orally (Jenner)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H301Toxic if swalloed

H312Harmful in contact with skin

H319Causes serious eye irritation

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.20554
Product name: Allyl acetate
Purity: for synthesis
Packaging: 100mL
Price: $129
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20554
Product name: Allyl acetate
Purity: for synthesis
Packaging: 500mL
Price: $591
Updated: 2024/03/01

Sigma-Aldrich

Product number: 185248
Product name: Allyl acetate
Purity: 99%
Packaging: 100ml
Price: $63.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 185248
Product name: Allyl acetate
Purity: 99%
Packaging: 500ml
Price: $126.6
Updated: 2024/03/01

TCI Chemical

Product number: A0020
Product name: Allyl Acetate
Purity: >98.0%(GC)
Packaging: 25mL
Price: $46
Updated: 2024/03/01

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Allyl acetate Chemical Properties,Usage,Production

Chemical Properties

Allyl acetate is a flammable, colorless liquid with an acrid odor.

Uses

Ally acetate is used in nonalcoholic beverages at 1 ppm, ice cream and ices at 2 ppm, candy at 5 ppm, baked goods at 5 ppm, and margarine at 2 ppm.

Uses

Ally acetate is used in industrial intermediate. Used in synthesis of colophony and bond.

Production Methods

Allyl acetate is produced by the following methods: decarboxylation of allylmalonic acid with heat, boiling ethyl 4- chloro-N-valerate in quinoline, and acetoxylation of propylene.
Allyl acetate is produced primarily for manufacturing allyl alcohol. It is also used as a synthetic flavoring for cheese, butter, and fruit.

General Description

A liquid. Insoluble in water and slightly less dense than water. Hence floats on water. Flash point below 75°F. Poisonous by ingestion and moderately toxic by inhalation and skin contact. Irritating to skin and eyes.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Allyl acetate is an ester. Reacts with acids to liberate heat along with alcohols and acids. Generates heat with strong oxidizing acids. The reaction may be sufficiently exothermic to ignite the reaction products. Also generates heat with basic solutions. Generates flammable hydrogen with alkali metals and hydrides. Emits acrid smoke and irritating fumes when heated to decomposition.

Hazard

Skin and eye irritant; poisonous.

Health Hazard

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and skin contact. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes. Dangerous fire hazard. See also ALLYL COMPOUNDS

Potential Exposure

Allyl Acetate is used to control insects in homes and animal shelters, and to treat lice in humans. May be used to enhance taste of dairy products and fruit. Generally speaking, most allyl compounds may be metabolized to allyl alcohol (see A:0540) which is metabolized to acrolein (see A:0380).

Solubility in organics

Insoluble in water, miscible with alcohol, essential oils, perfume and flavor chemicals.

Shipping

UN2333 Allyl acetate, Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials

Purification Methods

The ester is freed from peroxides by standing with crystalline ferrous ammonium sulfate, then washed with 5% NaHCO3, followed by saturated CaCl2 solution. Dry it with Na2SO4 and fractionally distil it in an all-glass apparatus. FLAMMABLE LIQUID. [Beilstein 2 H 136, 2 IV 180.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Incompatible with strong acids (liberates heat), nitrates, strong alkalis (liberates heat). Contact with alkali metals and strong reducing agents such as hydrides evolves highly flammable hydrogen gas. Attacks some plastics, coatings, and rubber. Flow or agitation of substance may generate electrostatic charges due to low conductivity; ground all equipment containing this material

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Allyl acetate Preparation Products And Raw materials

Raw materials

Palladium (II) Acetate Potassium Acetate

Preparation Products

Allyl alcohol

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Allyl acetate Suppliers

Americas 1 Belgium 2 China 145 Europe 3 France 1 Germany 5 India 3 Japan 4 Singapore 1 South Korea 1 Switzerland 2 United Kingdom 6 United States 38 Global 212

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View Lastest Price from Allyl acetate manufacturers

Qingdao RENAS Polymer Material Co., Ltd.

Product: Allyl acetate 591-87-7
Price: US $0.00/kg
Min. Order: 200kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-08-08

Hebei Yanxi Chemical Co., Ltd.

Product: Allyl acetate 591-87-7
Price: US $30.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-23

Hebei Weibang Biotechnology Co., Ltd

Product: Allyl acetate 591-87-7
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2023-01-11

591-87-7, Allyl acetateRelated Search:

Allyl chloroformate Allyl cyclohexylpropionate Allyl methacrylate Allyl chloride Isopropyl acetate Sodium acetate ALLYL ACRYLATE Ethyl acetate Allyl heptanoate Allyl bromide Vinyl acetate Glatiramer acetate Allyl hexanoate Diallyl phthalate Propyl acetate Ammonium acetate Allyl glycidyl ether PHENYL ALLYL ACETATE

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2-Propenyl ester of acetic acid

2-propenylmethanoate

3-acetoxy-1-propene

liquid-solid phase transfer

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Allyl acetate 99%

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acetated’allyle

Aceticacid,2-propenylester

aceticacidprop-2-enylester

CH2=C(CH3)OC(=O)CH3

PROPENYL ACETATE

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ALLYL ACETATE FOR SYNTHESIS 100 ML

Acetic acid, 2-propen-1-yl ester

prop-2-enyl acetate

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591-87-7

CH3CO2CH2CHCH2

CH3COOCH2CHCH2

CH3COOC3H5

591877

ALKYNE

Carbonyl Compounds

C2 to C5

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