ChemicalBook > CAS DataBase List > Methyl cyanoformate
Methyl cyanoformate
- Product Name
- Methyl cyanoformate
- CAS No.
- 17640-15-2
- Chemical Name
- Methyl cyanoformate
- Synonyms
- Methyl carbonocyanidate;cyklona;Cyklon A;CH3OC(O)CN;METHYL CYANOFORMATE;Methylcyanomethanoate;cyanoformatemethylester;Cyanoformic acid methyl;Methyl cyanoforMate 99%;Methyl cyanoformate ,98%
- CBNumber
- CB8748128
- Molecular Formula
- C3H3NO2
- Formula Weight
- 85.06
- MOL File
- 17640-15-2.mol
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Methyl cyanoformate Property
- Melting point:
- 185-186 °C
- Boiling point:
- 100-101 °C (lit.)
- Density
- 1.072 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.374(lit.)
- Flash point:
- 79 °F
- form
- liquid
- BRN
- 1742994
- EPA Substance Registry System
- Carbonocyanidic acid, methyl ester (17640-15-2)
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Safety
- Hazard Codes
- T+
- Risk Statements
- 10-26/27/28-36/38-36/37/38
- Safety Statements
- 26-28-36/37-45
- RIDADR
- UN 3275 6.1/PG 2
- WGK Germany
- 3
- RTECS
- LQ7525000
- F
- 10-19-21
- HazardClass
- 3.2
- PackingGroup
- III
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 319813
- Product name
- Methyl cyanoformate
- Purity
- 99%
- Packaging
- 5g
- Price
- $105
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 319813
- Product name
- Methyl cyanoformate
- Purity
- 99%
- Packaging
- 25g
- Price
- $429
- Updated
- 2024/03/01
Usbiological
- Product number
- 455885
- Product name
- Methyl Cyanoformate
- Packaging
- 250mg
- Price
- $355
- Updated
- 2021/12/16
TRC
- Product number
- M295250
- Product name
- Methyl cyanoformate
- Packaging
- 250mg
- Price
- $85
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0030773
- Product name
- METHYL CYANOFORMATE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1059.45
- Updated
- 2021/12/16
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Methyl cyanoformate Chemical Properties,Usage,Production
Description
Methyl cyanoformate is the organic compound with the formula CH3OC(O)CN. It is used as a reagent in organic synthesis as a source of the methoxy carbonyl group , in which context it is also known as Mander's reagent. It was also the active ingredient in the pesticide product Zyklon A.
Chemical Properties
Colorless liquid; ethereal odor. Decomposedby alkalies and water. Soluble in alcohol, benzene,ether.
Uses
Selective acylating reagent.
Uses
Organic synthesis.
Purification Methods
Purify the ester by fractionation through a 45cm glass helices packed column or a 30cm spinning band column. [Sheppard J Org Chem 27 3756 1962.] It has been distilled through a short Vigreux column (p 11), and further purified by recrystallisation from Et2O at -40o as white crystals which melt at room temperature. NMR: 4.0 ( C3), and IR: 2250 (CN) and 1750 (CO) cm-1 . [Childes & Weber JOrg Chem 41 3486 1976, Beilstein 2 III 1587.]
Methyl cyanoformate Preparation Products And Raw materials
Raw materials
Preparation Products
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