Benzyl isocyanide
- Product Name
- Benzyl isocyanide
- CAS No.
- 10340-91-7
- Chemical Name
- Benzyl isocyanide
- Synonyms
- (IsocyanoMethyl)benzene;BENZYL ISONITRILE;HANSA ISN-0155;BENZYL ISOCYANIDE;Benzyl carbylamine;BIO-FARMA BF000644;Benzyl lsocyanide;Benzyl isocyanide,98%;Benzyl Isocyanide >Phenylmethyl isocyanide
- CBNumber
- CB8765835
- Molecular Formula
- C8H7N
- Formula Weight
- 117.15
- MOL File
- 10340-91-7.mol
Benzyl isocyanide Property
- Boiling point:
- 105-106 °C75 mm Hg(lit.)
- Density
- 0.962 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.521(lit.)
- Flash point:
- 175 °F
- storage temp.
- -20°C
- pka
- 27.4
- form
- clear liquid
- color
- Colorless to Red to Green
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- 133299
- Product name
- Benzyl isocyanide
- Purity
- 98%
- Packaging
- 1g
- Price
- $112
- Updated
- 2024/03/01
- Product number
- 133299
- Product name
- Benzyl isocyanide
- Purity
- 98%
- Packaging
- 5g
- Price
- $355
- Updated
- 2024/03/01
- Product number
- B2185
- Product name
- Benzyl Isocyanide
- Purity
- >96.0%(GC)
- Packaging
- 1g
- Price
- $82
- Updated
- 2024/03/01
- Product number
- B2185
- Product name
- Benzyl Isocyanide
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $261
- Updated
- 2024/03/01
- Product number
- B279995
- Product name
- Benzyl isocyanide
- Packaging
- 2.5g
- Price
- $140
- Updated
- 2021/12/16
Benzyl isocyanide Chemical Properties,Usage,Production
Chemical Properties
clear colorless to yellowish liquid
Uses
Benzyl Isocyanide is used in the preparation of arylamide compounds. also used as a catalyst in the cycloaddition of norbornenes with internal and terminal acetylenes.
Application
Benzyl isocyanide forms phosphaalkene-containing complexes. Benzyl isocyanide was used in the synthesis of Ru(II) complexes containing hydrazine and benzyl isocyanide ligands. It was used in a three-component coupling process leading to O- and N-arylamides.
Synthesis
Synthesis of benzyl isocyanide
In a 500-mL, round-bottomed flask equipped with a magnetic stirring bar and a pressure-equalizing funnel are placed 5-benzylaminotetrazole (10.5 g, 60 mmol), 100 mL of 10% sodium hydroxide solution, and 70 mL of dichloromethane. The mixture is cooled to 0°C and a solution of NaOBr in water (165 mL, 65 mmol) (Note 2) is added with vigorous stirring over a 15-min period (Note 3). The dichloromethane layer is separated and the aqueous phase extracted with five 50-mL portions of dichloromethane. The combined dichloromethane extracts are dried over anhydrous MgSO4, the drying agent is removed by filtration, and the dichloromethane is removed by simple distillation. The pressure is then reduced to ~20 mm with an aspirator and benzyl isocyanide is distilled at 98–100°C; yield: 5.91 g (84%) (Note 4) and (Note 5).
Organic Syntheses, Coll. Vol. 7, p. 27, 1990
http://www.orgsyn.org
Benzyl isocyanide Preparation Products And Raw materials
Raw materials
Preparation Products
Benzyl isocyanide Suppliers
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- Country
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- Country
- Germany
- ProdList
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View Lastest Price from Benzyl isocyanide manufacturers
- Product
- Benzyl isocyanide 10340-91-7
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-09