Benzyl isocyanide

Product Name: Benzyl isocyanide
CAS No.: 10340-91-7
Chemical Name: Benzyl isocyanide
Synonyms: (IsocyanoMethyl)benzene;BENZYL ISONITRILE;HANSA ISN-0155;BENZYL ISOCYANIDE;Benzyl carbylamine;BIO-FARMA BF000644;Benzyl lsocyanide;Benzyl isocyanide,98%;Benzyl Isocyanide >Phenylmethyl isocyanide
CBNumber: CB8765835
Molecular Formula: C8H7N
Formula Weight: 117.15
MOL File: 10340-91-7.mol

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Benzyl isocyanide Property

Boiling point:: 105-106 °C75 mm Hg(lit.)
Density: 0.962 g/mL at 25 °C(lit.)
refractive index: n20/D 1.521(lit.)
Flash point:: 175 °F
storage temp.: -20°C
pka: 27.4
form: clear liquid
color: Colorless to Red to Green

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 36/37
RIDADR: UN 3334
WGK Germany: 3
HS Code: 29269090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 133299
Product name: Benzyl isocyanide
Purity: 98%
Packaging: 1g
Price: $112
Updated: 2024/03/01

Sigma-Aldrich

Product number: 133299
Product name: Benzyl isocyanide
Purity: 98%
Packaging: 5g
Price: $355
Updated: 2024/03/01

TCI Chemical

Product number: B2185
Product name: Benzyl Isocyanide
Purity: >96.0%(GC)
Packaging: 1g
Price: $82
Updated: 2024/03/01

TCI Chemical

Product number: B2185
Product name: Benzyl Isocyanide
Purity: >96.0%(GC)
Packaging: 5g
Price: $261
Updated: 2024/03/01

TRC

Product number: B279995
Product name: Benzyl isocyanide
Packaging: 2.5g
Price: $140
Updated: 2021/12/16

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Benzyl isocyanide Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellowish liquid

Uses

Benzyl Isocyanide is used in the preparation of arylamide compounds. also used as a catalyst in the cycloaddition of norbornenes with internal and terminal acetylenes.

Application

Benzyl isocyanide forms phosphaalkene-containing complexes. Benzyl isocyanide was used in the synthesis of Ru(II) complexes containing hydrazine and benzyl isocyanide ligands. It was used in a three-component coupling process leading to O- and N-arylamides.

Synthesis

Synthesis of benzyl isocyanide
In a 500-mL, round-bottomed flask equipped with a magnetic stirring bar and a pressure-equalizing funnel are placed 5-benzylaminotetrazole (10.5 g, 60 mmol), 100 mL of 10% sodium hydroxide solution, and 70 mL of dichloromethane. The mixture is cooled to 0°C and a solution of NaOBr in water (165 mL, 65 mmol) (Note 2) is added with vigorous stirring over a 15-min period (Note 3). The dichloromethane layer is separated and the aqueous phase extracted with five 50-mL portions of dichloromethane. The combined dichloromethane extracts are dried over anhydrous MgSO4, the drying agent is removed by filtration, and the dichloromethane is removed by simple distillation. The pressure is then reduced to ~20 mm with an aspirator and benzyl isocyanide is distilled at 98–100°C; yield: 5.91 g (84%) (Note 4) and (Note 5).
Organic Syntheses, Coll. Vol. 7, p. 27, 1990
http://www.orgsyn.org

Benzyl isocyanide Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl isocyanide Suppliers

Americas 1 Belgium 2 Canada 1 China 98 Europe 1 France 1 Germany 6 India 9 Japan 2 Russia 1 Switzerland 2 United Kingdom 6 United States 13 Global 143

TCI Chemicals (India) Pvt. Ltd.

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Alfa Aesar

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Innovative Labs

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Sai Quest Syn. Ltd

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Reax Chemicals

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TSK Lifesciences

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Rasayan Drugs Private Limited

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A.J Chemicals

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View Lastest Price from Benzyl isocyanide manufacturers

Career Henan Chemical Co

Product: Benzyl isocyanide 10340-91-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98% HPLC
Supply Ability: 10 tons/month
Release date: 2020-01-09

10340-91-7, Benzyl isocyanideRelated Search:

ISOCYANIC ACID CYCLOHEXYL ISOCYANIDE Benzeneacetonitrile Benzyl chloride Benzyl isocyanate Ethyl acetoacetate 3-(ISOCYANOMETHYL)BENZYL-ISOCYANIDE 4-(ISOCYANOMETHYL)BENZYL-ISOCYANIDE

HANSA ISN-0155

BENZYL ISOCYANIDE

BENZYL ISONITRILE

BIO-FARMA BF000644

Benzyl carbylamine

Phenylmethyl isocyanide

Benzyl isocyanide,98%

Benzyl lsocyanide

Benzyl isocyanide, 98% 1GR

(IsocyanoMethyl)benzene

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Benzyl Isocyanide &gt

10340-91-7

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