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Methyl 2-chloropropionate

Product Name
Methyl 2-chloropropionate
CAS No.
17639-93-9
Chemical Name
Methyl 2-chloropropionate
Synonyms
Methyl 2-Chloropropionat;2-CHLOROPROPIONIC ACID METHYL ESTER;NSC-70983;CH3CHClC(O)OCH3;Methyl 2-chloropropi;2-chloropropyl Methyl;Methyl 2-chloropropion;Methly 2-chloropionate;Methyl 2-chloropropiote;Mehyl 2-chloropropionate
CBNumber
CB8853211
Molecular Formula
C4H7ClO2
Formula Weight
122.55
MOL File
17639-93-9.mol
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Methyl 2-chloropropionate Property

Melting point:
-10 °C
Boiling point:
132-133 °C(lit.)
Density 
1.075 g/mL at 25 °C(lit.)
vapor density 
4.22 (vs air)
vapor pressure 
5.25 mm Hg ( 20 °C)
refractive index 
n20/D 1.417(lit.)
Flash point:
101 °F
storage temp. 
Store at +5°C to +30°C.
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form 
clear liquid
Specific Gravity
1.075
color 
Colorless to Almost colorless
PH
6-7 (H2O, 20℃)
explosive limit
2.8-13.9%(V)
Water Solubility 
immiscible
BRN 
1421535
Stability:
Stable. Flammable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
17639-93-9(CAS DataBase Reference)
NIST Chemistry Reference
Methyl 2-chloropropionate(17639-93-9)
EPA Substance Registry System
Propanoic acid, 2-chloro-, methyl ester (17639-93-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
26-36-37/39-16
RIDADR 
UN 2933 3/PG 3
WGK Germany 
1
RTECS 
UE9100000
Autoignition Temperature
430 °C DIN 51794
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29159080
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20331
Product name
Methyl 2-chloropropionate
Purity
for synthesis
Packaging
250ML
Price
$93.1
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20331
Product name
Methyl 2-chloropropionate
Purity
for synthesis
Packaging
1L
Price
$238
Updated
2024/03/01
TCI Chemical
Product number
C0970
Product name
Methyl 2-Chloropropionate
Purity
>95.0%(GC)
Packaging
25mL
Price
$32
Updated
2024/03/01
TCI Chemical
Product number
C0970
Product name
Methyl 2-Chloropropionate
Purity
>95.0%(GC)
Packaging
100mL
Price
$48
Updated
2024/03/01
Alfa Aesar
Product number
A18541
Product name
Methyl 2-chloropropionate, 97%
Packaging
250g
Price
$78.65
Updated
2024/03/01
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Methyl 2-chloropropionate Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Methyl 2-chloropropionate is used as initiator during the synthesis of acrylamide homopolymers and acrylamide-N-isopropylacrylamide block copolymers. It is also used to produce 2-thiophen-2-yl-propionic acid methyl ester.

General Description

A colorless liquid. Flash point 101°F. Density 8.9 lb / gal. Insoluble in water. Irritating and narcotic in high concentrations. Used as a solvent and for making other chemicals and dyes.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

METHYL CHLOROPROPIONATE is a halogenated ester. Reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Reacts exothermically with bases. Flammable hydrogen is generated with alkali metals and hydrides.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by intraperitoneal route. See also ESTERS. A flammable liquid when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl-.

Methyl 2-chloropropionate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-chloropropionate Suppliers

Changzhou Yuantong Fine Chemical Co.,Ltd.
Tel
0519-83631498 13906116156
Email
13906116156@139.com
Country
China
ProdList
1
Advantage
58
Changzhou Liren Medical Technology Co. Ltd.
Tel
0519-85859058 13915836899
Email
2078957504@qq.com
Country
China
ProdList
235
Advantage
58
Zibo Chuanggu Chemical Technology Co., Ltd.
Tel
00-15864498288 15864498288
Email
15864498288@163.cn
Country
China
ProdList
43
Advantage
58
PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Fax
86-025-86918232
Email
sales@pharmablock.com
Country
China
ProdList
4986
Advantage
55
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2964
Advantage
65
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9414
Advantage
66
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View Lastest Price from Methyl 2-chloropropionate manufacturers

Hebei shuoxi biotechnology co. LTD
Product
Methyl 2-chloropropionate 17639-93-9
Price
US $60.00/KG
Min. Order
1g
Purity
99.8%
Supply Ability
10tons
Release date
2019-10-24
Hebei Henghe Import and Export Trading Co. LTD
Product
Methyl 2-Chloropropionate, 2-Chloropropionic Acid Methyl Ester 17639-93-9
Price
US $150.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100
Release date
2020-12-18
Career Henan Chemical Co
Product
Methyl 2-chloropropionate 17639-93-9
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-22

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