Diethyl chloromalonate

Product Name: Diethyl chloromalonate
CAS No.: 14064-10-9
Chemical Name: Diethyl chloromalonate
Synonyms: Nsc 227952;Einecs 237-913-0;RARECHEM AL BI 0643;Diethyl chloromalote;Ethyl chloromalonate;Bosentan Impurity 16;DIETHYL CHLOROMALONATE;α-Chlorodiethylmalonate;Ethylmonochloromalonate;Diethyl chloroMalonate 95%
CBNumber: CB7686706
Molecular Formula: C7H11ClO4
Formula Weight: 194.61
MOL File: 14064-10-9.mol

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Diethyl chloromalonate Property

Boiling point:: 279.11°C (rough estimate)
Density: 1.204 g/mL at 25 °C (lit.)
refractive index: n20/D 1.432(lit.)
Flash point:: >230 °F
storage temp.: Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka: 9.07±0.46(Predicted)
form: Liquid
color: Clear colorless
Specific Gravity: 1.204
LogP: 2.23 at 40℃ and pH4-9
CAS DataBase Reference: 14064-10-9(CAS DataBase Reference)
EPA Substance Registry System: Propanedioic acid, 2-chloro-, 1,3-diethyl ester (14064-10-9)

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Safety

Hazard Codes: C
Risk Statements: 34-36/37
Safety Statements: 26-27-28-36/37/39-45
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: III
HS Code: 29171990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H400Very toxic to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 437786
Product name: Diethyl chloromalonate
Purity: 95%
Packaging: 25ml
Price: $100
Updated: 2024/03/01

Sigma-Aldrich

Product number: 437786
Product name: Diethyl chloromalonate
Purity: 95%
Packaging: 5ml
Price: $103
Updated: 2024/03/01

TRC

Product number: D444060
Product name: Diethyl chloromalonate
Packaging: 25g
Price: $485
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD21791
Product name: Diethyl chloromalonate
Packaging: 50g
Price: $500
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK139928
Product name: Diethyl chloromalonate
Purity: 98%
Packaging: 100g
Price: $557
Updated: 2021/12/16

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Diethyl chloromalonate Chemical Properties,Usage,Production

Chemical Properties

Clear Colourless Liquid

Uses

A compound used in the models of aquatic toxicity developed (QSAR). Combinatorial QSAR modeling of chemical toxicants tested against Tetrahymena pyriformis.

Uses

Diethyl chloromalonate is a compound used in the models of aquatic toxicity developed

General Description

Diethyl chloromalonate (Diethyl α-chloromalonate) is a 2-halo-1,3-dicarbonyl compound. It participates in K₂CO₃-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives to afford functionalized 2,3-dihydrobenzofurans. It reacts with Cs₂CO₃ in the presence of elemental S₈ or Se_n to afford the corresponding diethyl thioxo- or selenoxomalonates, which can be trapped in situ with various 1,3-dienes.

Diethyl chloromalonate Preparation Products And Raw materials

Raw materials

Sodium hypochlorite Ethanol Sodium sulfite Chlorine Sulfuryl chloride Sodium bicarbonate Dichloromethane Diethyl malonate

Preparation Products

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Diethyl chloromalonate Suppliers

Canada 1 China 203 Germany 4 India 4 Japan 2 South Korea 1 Switzerland 1 United Kingdom 4 United States 17 Global 237

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View Lastest Price from Diethyl chloromalonate manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd

Product: diethyl chloromalonate 14064-10-9
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.6%
Supply Ability: 100000
Release date: 2024-04-23

Hebei Yanxi Chemical Co., Ltd.

Product: Diethyl chloromalonate 14064-10-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99.00%
Supply Ability: 100tons
Release date: 2023-09-27

Hebei Mojin Biotechnology Co., Ltd

Product: Diethyl chloromalonate 14064-10-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-28

14064-10-9, Diethyl chloromalonateRelated Search:

Diethyl dibutylmalonate Mefenpyr-diethyl Methyl acrylate Ethyl malonyl chloride Ethylene glycol diethyl ether Diethyl benzylmalonate Diethyl methylmalonate Tris(trimethylsilyl)phosphate 2-AMINODIETHYLMALONATE Diethyl malonate Diethyl oxalate Dimethyl succinate Diethyl fluoromalonate Dimethyl chloromalonate DIETHYL BROMOMALONATE METHYL CHLORODIFLUOROACETATE Bosentan Impurity 5 2-Cyanopyrimidine

2-Chloropropanedioic Acid 1,3-Diethyl Ester

Chloropropanedioic Acid Ethyl Ester

Diethyl MonochloroMalonate

Chlorinated diethylMalonate

DIETHYL CHLOROMALONATE FOR SYNTHESIS

Diethyl chloroMalonate 95%

2-Chloro-malonic acid 1,3-diethyl ester

Chloropropanedioicaciddiethylester

chloro-propanedioicacidiethylester

RARECHEM AL BI 0643

Diethyl chloromalote

Propanedioic acid, chloro-, diethyl ester

2-chloro-malonic acid diethyl ester

α-Chlorodiethylmalonate

Ethyl chloromalonate

Diethyl chloromalonate ,98%

Diethyl chloromalonate ,90%

2-Chloromalonic acid diethyl

Chloromalonic acid diethyl

Einecs 237-913-0

Ethylmonochloromalonate

Malonic acid, chloro-, diethyl ester

Nsc 227952

Propanedioic acid, 2-chloro-, 1,3-diethyl ester

Diethyl chloromalonate ,95%

DIETHYL CHLOROMALONATE

CHLOROMALONIC ACID DIETHYL ESTER

Bosentan Impurity 16

1,3-diethyl 2-chloropropanedioate

Diethyl 2-chloropropanedioate

14064-10-9

C7H11ClO4

ClCHCO2C2H52

Carbonyl Compounds

C6 to C7

Building Blocks

Organic Building Blocks

Esters

ester series

Aliphatics

Pharmaceutical Intermediates

TheMalonateRamificationProducts

C6 to C7

Carbonyl Compounds

Esters