ChemicalBook > CAS DataBase List > 3-Hexanol

3-Hexanol

Product Name
3-Hexanol
CAS No.
623-37-0
Chemical Name
3-Hexanol
Synonyms
METHYL N-BUTYL KETONE;MBK;Hexan-3-ol;Ethyln-propylcarbinol,mixedisomers;MNBK;3-Hexanol;Hexanol-(3);n-Hexanol-3;CIS3HEXANOL;3-Hexanol>
CBNumber
CB8853998
Molecular Formula
C6H14O
Formula Weight
102.17
MOL File
623-37-0.mol
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3-Hexanol Property

Melting point:
−57 °C(lit.)
Boiling point:
134-135 °C (lit.)
Density 
0.820 g/mL at 20 °C 0.819 g/mL at 25 °C (lit.)
vapor pressure 
10 mm Hg ( 39 °C)
refractive index 
n20/D 1.401(lit.)
FEMA 
3351 | 3-HEXANOL
Flash point:
95 °F
storage temp. 
Flammables area
solubility 
Soluble in alcohol.
pka
15.31±0.20(Predicted)
form 
clear liquid
color 
Colorless to Almost colorless
Odor
Characteristic; strong, disagreeable odor resembling acetone.
Odor Type
alcoholic
Water Solubility 
15.84g/L(25 ºC)
JECFA Number
282
BRN 
1718964
LogP
1.70
CAS DataBase Reference
623-37-0(CAS DataBase Reference)
EPA Substance Registry System
3-Hexanol (623-37-0)
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Safety

Hazard Codes 
T
Risk Statements 
10-48/23-62-67
Safety Statements 
36/37-45-24/25
RIDADR 
UN 1224 3/PG 3
WGK Germany 
1
RTECS 
MP1400000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29051990
Toxicity
A colorless liquid used as a solvent, in paints and in the printing industry. It enters the body primarily by inhalation or skin absorption. MBK causes irritation of the skin and mucous membranes and, on continued exposure, peripheral axonopathy; the latter is due to its metabolic conversion to 2,5-hexanedione. It is known to potentiate the hepatotoxicity of haloalkanes.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
H12404
Product name
3-Hexanol
Purity
97%
Packaging
25g
Price
$125
Updated
2022/05/15
Sigma-Aldrich
Product number
04649
Product name
3-Hexanol
Purity
analytical standard
Packaging
1ml
Price
$98.9
Updated
2022/05/15
TCI Chemical
Product number
H0132
Product name
3-Hexanol
Purity
>98.0%(GC)
Packaging
25mL
Price
$57
Updated
2024/03/01
Alfa Aesar
Product number
B20210
Product name
3-Hexanol, 98%
Packaging
25g
Price
$68.65
Updated
2024/03/01
Alfa Aesar
Product number
B20210
Product name
3-Hexanol, 98%
Packaging
100g
Price
$242
Updated
2024/03/01
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3-Hexanol Chemical Properties,Usage,Production

Description

3-Hexanol is alcoholic, ethereal, medicinal. May be synthesized by hydroboration of ds-3-hexene; from 3-hexyne; from l-(and 2-) hexenes.

Chemical Properties

CLEAR COLOURLESS LIQUID

Chemical Properties

3-Hexanol has an alcoholic, ethereal, medicinal odor.

Occurrence

Reported found in lavender and sweet grass oil, as a volatile flavor components in pineapple and in the odorous portion of Vaccinium macrocarpon. Also reported found in apricot, banana, cranberry, lingonberry, black currants, melon, papaya, Parmesan cheese, cooked chicken, cognac, cocoa, soybeans, beans, mushrooms, mango and lemon balm.

Uses

It finds it application as a flavoring agent or adjuvant.

Definition

ChEBI: Hexan-3-ol is a hexanol in which the hydroxy group is at position 3. It has a role as a plant metabolite. It is a secondary alcohol and a hexanol.

Preparation

By hydroboration of cis-3-hexene; from 3-hexyne; from 1-(and 2-) hexenes.

Aroma threshold values

Detection: 820 ppb to 2.5 ppm

General Description

3-Hexanol is an aliphatic alcohol that is reported to occur in freesia oil, pandan leaves and in tomato and dried products.

Health Hazard

Recommended Personal Protective Equipment: Protective gloves; goggles or face shield; approved respirator (for major spills); Symptoms Following Exposure: Inhalation of high concentrations of vapor may result in narcosis; peripheral neuropathy may develop. Ingestion of large amounts may cause some systemic injury. Contact with eyes causes mild to moderate irritation. Liquid irritates skin; prolonged or repeated contact may cause defatting of the skin with resultant dermatitis; General Treatment for Exposure: INHALATION: move to uncontaminated atmosphere and treat symptomatically; alert physician to possible development of peripheral neuropathy. INGESTION: give large amount of water and induce vomiting. EYES: irrigate immediately and thoroughly with water for 15 min. and get medical attention. SKIN: flush exposed areas thoroughly with water; Toxicity by Inhalation (Threshold Limit Value): 100 ppm; Short-Term Inhalation Limits: Data not available; Toxicity by Ingestion: Grade 2; oral LD50 = 2,590 mg/kg (rat); Late Toxicity: Peripheral neuropathy in experimental animals and man (disease of motor and/or sensor nerves); Vapor (Gas) Irritant Characteristics: Data not available; Liquid or Solid Irritant Characteristics: Data not available; Odor Threshold: Data not available.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

3-Hexanol Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Hexanol Suppliers

Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1390
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2963
Advantage
65
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Shijiazhuang Lida Chemical Co., Ltd.
Tel
+86 (311) 8573-7996
Fax
+86 (311) 8573-9175
Email
service@lid-ff.cn
Country
China
ProdList
294
Advantage
65
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
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View Lastest Price from 3-Hexanol manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
3-Hexanol 623-37-0
Price
US $30.00-22.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 mt
Release date
2024-12-04
Hebei Mojin Biotechnology Co., Ltd
Product
3-Hexanol 623-37-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-18
Shaanxi Dideu Medichem Co. Ltd
Product
3-Hexanol 623-37-0
Price
US $0.00-0.00/Kg
Min. Order
1KG
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-16

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