Description Chemical Properties References
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Isoprene

Description Chemical Properties References
Product Name
Isoprene
CAS No.
78-79-5
Chemical Name
Isoprene
Synonyms
2-METHYL-1,3-BUTADIENE;ACETATE BUFFER;BUFFER SOLUTION;SODIUM ACETATE BUFFER;lsoprene;BUFFER PH7.20;BUFFER PH 4.65;Isoprene, stabilized;2-Methyl-1,3-butadien;nsc9237
CBNumber
CB8854379
Molecular Formula
C5H8
Formula Weight
68.12
MOL File
78-79-5.mol
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Isoprene Property

Melting point:
323-329 °C(lit.)
Boiling point:
34 °C(lit.)
Density 
0.681 g/mL at 25 °C(lit.)
vapor density 
2.35 (vs air)
vapor pressure 
8.82 psi ( 20 °C)
refractive index 
n20/D 1.422(lit.)
Flash point:
−65 °F
storage temp. 
Store at <= 20°C.
solubility 
0.7g/l
form 
solid
pka
>14 (Schwarzenbach et al., 1993)
color 
Clear colorless to very pale yellow
Odor
petroleum-like odor
explosive limit
1-9.7%(V)
Odor Threshold
0.048ppm
Water Solubility 
0.07 g/100 mL
FreezingPoint 
-145.96℃
λmax
231nm(neat)(lit.)
Merck 
14,5201
BRN 
969158
Henry's Law Constant
(x 10-2 atm?m3/mol): 3.45 at 18 °C (dynamic stripping cell-MS, Karl et al., 2003)
Dielectric constant
2.1（25℃）
Stability:
Stability Extremely flammable. Readily forms explosive mixtures with air. Note low flash point, low boiling point, high vapour pressure. Unstable - prone to spontaneous polymerization. May contain a polymerization inhibitor. Incompatible with strong oxidizing agents.
LogP
2.42 at 20℃
CAS DataBase Reference
78-79-5(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Butadiene, 2-methyl-(78-79-5)
IARC
2B (Vol. 60, 71) 1999
EPA Substance Registry System
Isoprene (78-79-5)
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Safety

Hazard Codes 
F+,T,N
Risk Statements 
45-12-52/53-68-51/53
Safety Statements 
53-45-61-36/37-16
RIDADR 
UN 1218 3/PG 1
WGK Germany 
1
RTECS 
NT4037000
Autoignition Temperature
428 °F
TSCA 
Yes
HS Code 
2901 24 00
HazardClass 
3
PackingGroup 
I
Hazardous Substances Data
78-79-5(Hazardous Substances Data)
Toxicity
LD50 for mice: 144 mg isoprene vapors/l air (Gostinskii)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H224Extremely flammable liquid and vapour

H341Suspected of causing genetic defects

H350May cause cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P273Avoid release to the environment.

P308+P313IF exposed or concerned: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I19551
Product name
Isoprene
Purity
99%, contains <1000?ppm p-tert-butylcatechol as inhibitor
Packaging
18L
Price
$906
Updated
2025/07/31
Sigma-Aldrich
Product number
8.21258
Product name
2-Methyl-1,3-butadiene
Purity
(stabilised) for synthesis
Packaging
100mL
Price
$41.1
Updated
2025/07/31
Sigma-Aldrich
Product number
8.21258
Product name
2-Methyl-1,3-butadiene
Purity
(stabilised) for synthesis
Packaging
1L
Price
$158
Updated
2025/07/31
Sigma-Aldrich
Product number
59240
Product name
Isoprene
Purity
analytical standard
Packaging
1mL
Price
$48.45
Updated
2025/07/31
Sigma-Aldrich
Product number
59240
Product name
Isoprene
Purity
analytical standard
Packaging
10ml
Price
$337
Updated
2025/07/31
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Isoprene Chemical Properties,Usage,Production

Description

Isoprene is a volatile colorless liquid monomer that is the basic building block of rubber,polybutadiene rubber, and polychloroprene rubber. These substances are labeled as rubber, but they differ from natural rubber. Isoprene rubber (IR) is the one synthetic rubber that is similar to natural rubber. The production of synthetic IR occurred in the mid 1950s when special organometallic catalysts for polymerizing isoprene were developed by Karl Ziegler (1898 1973) from Germany and the Italian Giulio Natta (1903 1979). Ziegler and Natta shared the 1963 Nobel Prize in chemistry for their work. Isoprene rubber has the same cis polyisoprene structure as natural rubber and has similar, but somewhat inferior, characteristics.
Rubber results from the polymerization of isoprene to form polyisoprene. The resulting structure dictates the properties of the rubber. Natural rubber has a cis 1,4 structure.This means that the carbon atoms that form the chainattach to the same side of the chain at the 1 and 4 positions. The cisstructure gives rubber its elasticity. Polyisoprene also exists in a trans 1,3 configuration. In the trans configuration, the addition takes place on opposite sides of the carbon chain.
Natural rubber occurs in a colloidal milky suspension called latex, which is obtained from numerous plants.

Chemical Properties

Isoprene is the monomeric unit of polyisoprene. The structure of this molecule is very similar to that of butadiene, with a simple methyl substitution differentiating the two. Although it is mainly used in the production of polyisoprene, isoprene is also used in styrene-based polymers and in butyl rubber. At room temperature it is a clear, colorless liquid with a faint odor; it is insoluble in water but soluble in acetone and other organic solvents. Unlike the chemically similar butadiene, isoprene is found in abundance in nature; for example, it is a component of natural terpenes and also is expired by plants and humans.

References

  1. https://en.wikipedia.org/wiki/Isoprene
  2. http://www.shell.com
  3. http://www.dgmk.de/petrochemistry/abstracts_content16/Reyer.pdf
  4. https://pubchem.ncbi.nlm.nih.gov 
  5. https://www.lyondellbasell.com

Description

Isoprene is a naturally occurring clear colorless volatile liquid (at room temperature) with a faint odor. Isoprene is an important building block for lipids, steroids, terpenoids, and a wide variety of natural products, including natural rubber. Isoprene is found in abundance in nature and is produced and emitted to the environment by plants and trees; it is also emitted from food crops since isoprene serves as the basic structural unit of numerous substances such as terpenes and vitamins A and K. Hence, isoprene is found in ambient air at low concentrations (e.g., the reported concentration of isoprene in the ambient air of the United States ranges between 1 and 21 ppb and is generally less than 10 ppb). Because the biosynthesis of isoprene is associated with photosynthesis, emission of isoprene from plants and trees is negligible at night. Emission of isoprene from plants and trees is also seasonal with the highest emission occurring in the summer and the lowest emission occurring in the winter. Once emitted to the atmosphere, isoprene is converted by free radicals (e.g., nitric oxide, hydroxyl radicals, ozone) to various species (e.g., aldehydes, hydroperoxides, organic nitrates, epoxides) that mix with water droplets and help create aerosols and haze.
Isoprene is produced endogenously in experimental animals and humans. The rate of endogenous production of isoprene in rats and mice is approximately 1.9 and 0.4 mmol kg-1 h-1, respectively, while in humans it is approximately 0.15 mmol kg-1 h-1 (approximately 2–4 μmol kg-1 per day). The precursor to endogenous isoprene production in humans is believed to be mevalonic acid, a precursor of cholesterol synthesis. Isoprene is the major hydrocarbon found in human breath, accounting for up to 70% of exhaled hydrocarbons. The mean concentration of isoprene reported in human breath is 118 ppb (range 0–474 ppb). The concentration of isoprene in human blood is between 1 and 4.8 μg l-1. The rate of production of isoprene is higher in males than females and in adults than in children.
Anthropogenic sources of isoprene include production of ethylene by cracking naphtha, wood pulping, combustion of wood and other biomass, tobacco smoke (smoking one cigarette can increase the concentration of isoprene in exhaled air by 70%), gasoline, and automobile exhaust.

Chemical Properties

Isoprene is a colourless liquid, b.p. 34°C.

Chemical Properties

Isoprene (2-methyl-l,3-butadiene) is a colorless, volatile, flammable liquid with specific gravity 0.6758. It is highly reactive, usually occurs as its dimer, and unless inhibited undergoes explosive polymerization. Isoprene naturally occurs in the environment as emissions from vegetation. It may be released to the environment as emissions during wood pulping, biomass combustion, and rubber abrasion; through tobacco smoke, gasoline, turbine, and automobile exhaust. In tobacco smoke, isoprene has been determined to be the precursor of a number of polycyclic aromatics, as demonstrated by thermal condensations in the range of 450–700℃.

Physical properties

Colorless, volatile, extremely flammable liquid with an petroleum-like odor. An odor threshold concentration of 48 ppbV was reported by Nagata and Takeuchi (1990).

Uses

The primary use of isoprene is the manufacture of polyisoprene, or ‘synthetic’ natural rubber, which is subsequently used to make tires. Other major uses of isoprene include the production of styrenic thermoplastic elastomer block copolymers (styrene–isoprene–styrene) and butyl rubber (isobutene– isoprene copolymer). Isoprene is also used to manufacture other chemicals, intermediates, and derivatives, which are subsequently used to manufacture vitamins, pharmaceuticals, flavorings and fragrances, and epoxy hardeners.

Uses

Isoprene occurs in nature and it is produced by many plants. Its polymers are the main component of natural rubber. The most important application of isoprene is to manufacture polymers and copolymers. Polyisoprene, a synthetic rubber made from isoprene, is used in a wide variety of rubber applications including medical equipment, baby bottle teats/nipples, toys, shoe soles, tires, elastic films, threads for golf balls or textiles, adhesives, paints, and coatings. Copolymer butyl rubber, made from isobutene with a small amount of isoprene, has excellent impermeability to gases and is used in inner tubes. Another copolymer styrene-isoprene rubber is used in pressure sensitive adhesives. Isoprene is also used as a chemical intermediate.

Uses

The majority of isoprene produced commercially is used to make synthetic rubber (cis-polyisoprene), most of which is used to produce vehicle tires. The second- and third-largest uses are in the production of styrene-isoprene-styrene block polymers and butyl rubber (isobutene-isoprene copolymer) (IARC 1994).

Preparation

Isoprene is obtained from propylene by the followin,g route:


In the first step, propylene is dimerized to 2-methyl-l-pentene by passage over a catalyst of tri-n-propylaluminium at about 200??C and 20 MPa (200 atmospheres). This product is then isomerized to 2-methyl-2-pentene by heating at 150-300??C in the presence of a silica-alumina catalyst. The final step in the process is the pyrolysis of the olefin to isoprene at 650-800??C in the presence of a free radical initiator such as hydrogen bromide. The isomerization step is necessary because pyrolysis of 2-methyl-l-pentene gives much poorer yields of isoprene than pyrolysis of 2-methyl-2-pentene.

Definition

ChEBI: A hemiterpene with the formula CH22C(CH3)CH2CH2; the monomer of natural rubber and a common structure motif to the isoprenoids, a large class of other naturally occurr ng compounds.

Production Methods

Rubber results from the polymerization of isoprene to form polyisoprene. The resultingstructure dictates the properties of the rubber. Natural rubber has a cis 1,4 structure.This means that the carbon atoms that form the chainattach to the same side ofthe chain at the 1 and 4 positions. The cisstructure gives rubber its elasticity. Polyisoprene alsoexists in a trans 1,3 configuration. In the trans configuration, the addition takes place onopposite sides of the carbon chain.
Natural rubber occurs in a colloidal milky suspension called latex, which is obtained fromnumerous plants. The most important of these is the para rubber tree, Hevea brasiliensis. Naturalrubber is harvested by cutting a v-shape incision into a plant and allowing latex to drain intoa container containing a preservative. About 50mL of latex is obtained on a daily basis. Latexis transported to collection stations where it is processed for shipment. Processing can includepreservation, coagulation, and concentrating before being sent to rubber factories.

General Description

A clear colorless liquid with a petroleum-like odor. Density 5.7 lb / gal. Flash point -65°F. Boiling point 93°F. May polymerize exothermically if heated or contaminated. If polymerization takes place inside a closed container, the container may rupture violently. Less dense than water and insoluble in water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

ISOPRENE may react vigorously with strong oxidizing agents. May react exothemically with reducing agents to release hydrogen gas. May undergo exothermic addition polymerization in the presence of various catalysts (such as acids) or initiators. Undergoes autoxidation upon exposure to the air to form explosive peroxides. Mixing isoprene in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, nitric acid (70%), oleum, sulfuric acid (90%) [NFPA 1991].

Hazard

Highly flammable, dangerous fire and explosion risk. Irritant. Possible carcinogen.

Health Hazard

Vapor produces no effects other than slight irritation of the eyes and upper respiratory tract. Liquid may irritate eyes; like gasoline.

Flammability and Explosibility

Extremely flammable

Carcinogenicity

Isoprene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Environmental Fate

At 25 ℃, isoprene has a high vapor pressure of 733 hPa, a low water solubility of 642 mg l-1, and a Henry’s law constant of 7781 Pam3 mol-1. Isoprene’s log Kow is 2.42 while its log Koc is 1.83. Isoprene’s vapor density relative to air is 2.4. Because of its high vapor pressure at ambient temperature, isoprene will partition largely into the atmosphere, with negligible amounts partitioning to soil and water. Due to a short half-life in air (0.5 h by reaction with nitric oxide, 1.2–4 h by reaction with hydroxyl radicals, and 19 h by reaction with ozone), wet deposition of isoprene from air is not expected to play a significant role in its atmospheric fate. Although laboratory testing demonstrates that isoprene has the potential to biodegrade, microbial metabolism is unlikely to contribute significantly to the removal of isoprene from the environment due to rapid volatilization from terrestrial and aquatic media. Isoprene has a low bioaccumulation potential and is not expected to bioaccumulate.

Purification Methods

Reflux it with sodium then distil it from sodium or NaBH4 under nitrogen, and pass it through a column containing KOH, CaSO4 and silica gel. tert-Butylcatechol (0.02% w/w) is added, and the isoprene is stored in this way until redistilled before use. The inhibitor (tert-butylcatechol) in isoprene can be removed by several washings with dilute NaOH and water. The isoprene is then dried over CaH2, distilled under nitrogen at atmospheric pressure, and the fraction distilling at 32o is collected. Store it under nitrogen at -15o. [Beilstein 1 H 252, 1 IV 1001.]

Toxicity evaluation

The acute effects of isoprene are related to irritation, central nervous system depression, and asphyxia at high concentrations. The mutagenic and genotoxic effects of isoprene seen in in vivo and in vitro studies, as well as the carcinogenic effects of isoprene in experimental animals (principally mice), are believed to be due to the formation of isoprene diepoxide.

Toxics Screening Level

Use of this potency factor, 0.0538 (μg/m3)-1, results in a calculated IRSL pf 0.02 μg/m3 and an SRSL of 0.2 μg/m3 with annual averaging.

Isoprene Preparation Products And Raw materials

Raw materials

3-Methyl-1-butene 2-Methylbutane C5 Fraction

Preparation Products

2,2-DIMETHYLCYCLOPENTANONE 3-METHYL-2,5-DIHYDROTHIOPHENE-1,1-DIOXIDE 6-Methyl-5-hepten-2-one 3-Methyl-2-buten-1-ol butyl rubber 2-Methyl-2-butene METHYLIONONE Cyclopentene TERPINEOL 1-Chloro-3-methyl-2-butene
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View Lastest Price from Isoprene manufacturers

Henan Fengda Chemical Co., Ltd
Product
Isoprene 78-79-5
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Shaanxi Didu New Materials Co. Ltd
Product
Isoprene(BIO) 78-79-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99.0% Min
Supply Ability
100 Tons
Release date
2023-11-22
Career Henan Chemical Co
Product
Isoprene 78-79-5
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-07-04

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  • decyclo-C5
  • 2-Methyl-1,3-butadien
  • Isoprene, 99%, stab. with ca 0.02% 4-tert-butylcatechol
  • Isoprene, 99%, inhibited with 100ppm p-tert-butycatechol
  • Isoprene (stabilized with TBC)
  • isoprene (stabilized) 2-methyl-1,3-butadiene
  • Isoprene, 98%, stabilized
  • Isoprene, stabilized
  • 2-Methylbutane-1,3-diene
  • 1,3-Butadiene,2-methyl-
  • 2-methyl-3-butadiene
  • 2-Methylbutadiene
  • 2-methyldivinyl
  • 2-methylethene
  • 3-Butadiene,2-methyl-1
  • 2-Methylerythrene
  • beta-Methylbutadiene
  • Isoprene&nbsp
  • Isoprene, stabilized, 98% 100ML
  • Isoprene, stabilized, 98% 1LT
  • Isoprene, stabilized, 98% 500ML
  • Isoprene 99%, contains <1000 ppM p-tert-butylcatechol as inhibitor
  • 2-Methyl-1,3-butadiene (stabilised) for synthesis
  • Isoprene, stabilized with &ap:0.02% 4-tert-butylcatechol
  • Isoprene 〔2-Methyl-1,3-butadiene〕
  • Isoprene(stabilizedwithTBC)&gt
  • 2-METHYL-1,3-BUTADIENE (STABILISED) FOR
  • lsoprene
  • Isoprene ISO 9001：2015 REACH
  • 1,1,2,4,4-pentachloro-3-(trichloromethyl)buta-1,3-diene
  • 2-(2-methoxy-2-oxoethyl)-5-methylhexa-3,5-dienoic acid
  • 3-(methoxycarbonyl)-6-methylhepta-4,6-dienoic acid
  • 3-(3-methylbuta-1,3-dien-1-yl)oxolane-2,5-dione
  • 78-79-5 Isoprene
  • BUFFER SOLUTION