ChemicalBook > CAS DataBase List > 4,4'-(1,4-Butanediyl)dioxydianiline

4,4'-(1,4-Butanediyl)dioxydianiline

Product Name
4,4'-(1,4-Butanediyl)dioxydianiline
CAS No.
6245-50-7
Chemical Name
4,4'-(1,4-Butanediyl)dioxydianiline
Synonyms
DA4MG;diaminodiphenoxybutane;beta,beta'-Bi-p-phenetidine;1,4-Bis(4-aminophenoxy)butane;4,4'-(Butane-1,4-diylbis(oxy);4,4'-(1,4-Butanediyl)dioxydianiline;1,4-bis(4-aminophenoxy)butane (DA4MG);4,4'-(Butane-1,4-diylbis(oxy))dianiline;4,4''-(1,4-BUTANEDIYL)DIOXYDIANILINE ,98%;Benzenamine, 4,4'-[1,4-butanediylbis(oxy)]bis-
CBNumber
CB8947442
Molecular Formula
C16H20N2O2
Formula Weight
272.34
MOL File
6245-50-7.mol
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4,4'-(1,4-Butanediyl)dioxydianiline Property

Density 
1.154
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
InChI
InChI=1S/C16H20N2O2/c17-13-3-7-15(8-4-13)19-11-1-2-12-20-16-9-5-14(18)6-10-16/h3-10H,1-2,11-12,17-18H2
InChIKey
LAFZPVANKKJENB-UHFFFAOYSA-N
SMILES
C(OC1=CC=C(N)C=C1)CCCOC1=CC=C(N)C=C1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
1709BA
Product name
Diaminodiphenoxybutane
Packaging
1g
Price
$95
Updated
2021/12/16
AK Scientific
Product number
1709BA
Product name
Diaminodiphenoxybutane
Packaging
25g
Price
$397
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0002737
Product name
4-[4-(4-AMINOPHENOXY)BUTOXY]ANILINE
Purity
95.00%
Packaging
250MG
Price
$727.65
Updated
2021/12/16
Ambeed
Product number
A713922
Product name
4,4'-(Butane-1,4-diylbis(oxy))dianiline
Purity
97%
Packaging
250mg
Price
$11
Updated
2021/12/16
Ambeed
Product number
A713922
Product name
4,4'-(Butane-1,4-diylbis(oxy))dianiline
Purity
97%
Packaging
1g
Price
$26
Updated
2021/12/16
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4,4'-(1,4-Butanediyl)dioxydianiline Chemical Properties,Usage,Production

Synthesis

14467-68-6

6245-50-7

1,4-bis(4-nitrophenoxy)butane (15, 0.97 g, 2.92 mmol) was used as feedstock and dissolved in dioxane (60 mL). The solution was passed through a Thalesnano H-cube TM continuous flow hydrogenation reactor equipped with a 30 mm Raney nickel catalyst (flow rate 0.5 mL/min) under 100% H2 atmosphere, 50 bar pressure, and 50°C. The reaction was carried out by thin layer chromatography (TLC). The reaction progress was monitored by thin layer chromatography (TLC) (unfolding agent ratio 50:50 ethyl acetate:hexane, Rf = 0.12). After complete consumption of the feedstock, the reaction mixture was concentrated under vacuum to afford the yellow solid product 4,4'-(1,4-butanedioxy)diphenylamine (0.98 g, 98% yield) with a melting point of 128-130 °C. The structure of the product was determined by 1H NMR (400 MHz, CD3OD) δ 6.87-6.58 (m, 8H), 4.12-3.80 (bm, 4H), 1.98-1.84 (bm, 4H); 13C NMR (101 MHz, CD3OD) δ 153.8,141.4,118.3,116.6,69.4,27.3; and confirmed by LRMS (ESI+) m/z 273 ([M+H]+, 100%).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2017, vol. 27, # 2, p. 162 - 167
[2] European Journal of Medicinal Chemistry, 1992, vol. 27, # 8, p. 799 - 808
[3] Justus Liebigs Annalen der Chemie, 1951, vol. 574, p. 85,97
[4] Journal of Medicinal Chemistry, 1985, vol. 28, # 11, p. 1728 - 1740

4,4'-(1,4-Butanediyl)dioxydianiline Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-(1,4-Butanediyl)dioxydianiline Suppliers

Tak Chi technology (Linyi) Limited
Tel
18669681830
Email
dechi1118@163.com
Country
China
ProdList
35
Advantage
58
ZHIWE CHEMTECH CO LTD
Tel
021-20221225 13917446399
Fax
QQ:115820162
Email
zwchem@163.com
Country
China
ProdList
616
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2803
Advantage
65
Changzhou Ruibo Biotechnology Co., Ltd.
Tel
0519-81884608 18205027398
Fax
0519-81884608
Email
sales@ruibobio.com
Country
China
ProdList
108
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56
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-0431-80514535 19917294565
Email
et@chemextension.com
Country
China
ProdList
3936
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55
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
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60
Shijiazhuang Yesheng Chemical Technology Co., Ltd
Tel
18031147013 18031147013;
Fax
0311-68030586
Email
yeshengchemical@163.com
Country
China
ProdList
2606
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58
Zhengzhou Huiju Chemical Co., Ltd.
Tel
0371-55900031 18137872243
Fax
QQ:2853979815
Email
2853979815@qq.com
Country
China
ProdList
9996
Advantage
55
Aikon International Limited
Tel
025-66061636 18013972705
Fax
(3)02557626880
Email
qqyang@aikonchem.com
Country
China
ProdList
15814
Advantage
58
Henan Alfa Chemical Co., Ltd
Tel
+8615838112936
Email
alfa10@alfachem.cn
Country
China
ProdList
12921
Advantage
58
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View Lastest Price from 4,4'-(1,4-Butanediyl)dioxydianiline manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4,4'-(Butane-1,4-diylbis(oxy))dianiline 6245-50-7
Price
US $2.20-8.80/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-24
Shaanxi Dideu New Materials Co. Ltd
Product
4,4'-(1,4-Butanediyl)dioxydianiline 6245-50-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-05-20

6245-50-7, 4,4'-(1,4-Butanediyl)dioxydianilineRelated Search:


  • diaminodiphenoxybutane
  • 4,4''-(1,4-BUTANEDIYL)DIOXYDIANILINE ,98%
  • 1,4-Bis(4-aminophenoxy)butane
  • beta,beta'-Bi-p-phenetidine
  • 4,4'-(Butane-1,4-diylbis(oxy))dianiline
  • 4,4'-(Butane-1,4-diylbis(oxy)
  • 4,4'-(1,4-Butanediyl)dioxydianiline
  • DA4MG
  • Benzenamine, 4,4'-[1,4-butanediylbis(oxy)]bis-
  • 1,4-bis(4-aminophenoxy)butane (DA4MG)
  • 6245-50-7