4-(4-Bromobenzyl)morpholine

Product Name: 4-(4-Bromobenzyl)morpholine
CAS No.: 132833-51-3
Chemical Name: 4-(4-Bromobenzyl)morpholine
Synonyms: Morpholine,4-[(4-broMophenyl)Methyl]-;4-(morpholin-4-ylmethyl)-1-bromobenzene
CBNumber: CB8957102
Molecular Formula: C11H14BrNO
Formula Weight: 256.14
MOL File: 132833-51-3.mol

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4-(4-Bromobenzyl)morpholine Property

storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: solid
color: White
InChI: InChI=1S/C11H14BrNO/c12-11-3-1-10(2-4-11)9-13-5-7-14-8-6-13/h1-4H,5-9H2
InChIKey: KWJZFQQTDGVBOX-UHFFFAOYSA-N
SMILES: N1(CC2=CC=C(Br)C=C2)CCOCC1

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 22
WGK Germany: 3
Hazard Note: Irritant
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: BML00227
Product name: 4-(4-Bromobenzyl)morpholine
Purity: Aldrich
Packaging: 1g
Price: $42.8
Updated: 2025/07/31

TRC

Product number: B680883
Product name: 4-(4-Bromobenzyl)morpholine
Packaging: 100mg
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H56-9-X1
Product name: 4-(4-Bromobenzyl)morpholine
Packaging: 250mg
Price: $16
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H56-9-X1
Product name: 4-(4-Bromobenzyl)morpholine
Packaging: 1g
Price: $32
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB124240
Product name: 4-(4-Bromobenzyl)morpholine
Packaging: 500mg
Price: $75
Updated: 2021/12/16

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4-(4-Bromobenzyl)morpholine Chemical Properties,Usage,Production

Synthesis

110-91-8

589-15-1

132833-51-3

Morpholine (13, 1.4 mL, 1.39 g, 16 mmol) and 4-bromobenzyl bromide (12, 1.0 g, 4 mmol) were reacted in acetonitrile (50 mL). The reaction mixture was heated to reflux for 4 hours. After completion of the reaction, water was added and extracted with dichloromethane (3 x 50 mL). The organic layers were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The residue was purified by fast column chromatography (silica gel column, 6 cm diameter, 50 mL volume, eluent n-hexane/ethyl acetate=8/2, Rf=0.19) to afford the target product 14 as a colorless solid (1.0 g, 3.9 mmol, 98% yield). The melting point of the product was 85 °C. Structural confirmation and purity analysis of the product were carried out by various analytical methods including 1H NMR, 13C NMR, IR, MS (ESI), HRMS and HPLC, which showed that the product was pure and structurally correct.

References

[1] Carbohydrate Research, 2012, vol. 359, p. 59 - 64,6
[2] Carbohydrate Research, 2012, vol. 359, p. 59 - 64
[3] Patent: WO2013/153357, 2013, A1. Location in patent: Page/Page column 18; 39
[4] Patent: US2015/45354, 2015, A1. Location in patent: Paragraph 0233-0236
[5] Patent: WO2008/154642, 2008, A2. Location in patent: Page/Page column 188-189

4-(4-Bromobenzyl)morpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(4-Bromobenzyl)morpholine Suppliers

China 78 India 1 United Kingdom 2 United States 9 Global 90

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View Lastest Price from 4-(4-Bromobenzyl)morpholine manufacturers

Career Henan Chemical Co

Product: 4-(4-Bromobenzyl)morpholine 132833-51-3
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 200KG
Release date: 2018-12-23

Career Henan Chemical Co

Product: 4-(4-Bromobenzyl)morpholine 132833-51-3
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 200KG
Release date: 2018-12-23

Career Henan Chemical Co

Product: 4-(4-Bromobenzyl)morpholine 132833-51-3
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 200KG
Release date: 2018-12-23

132833-51-3, 4-(4-Bromobenzyl)morpholineRelated Search:

4-[2-(2-BROMOPHENOXY)ETHYL]MORPHOLINE 1-[2-(3-BROMOPHENOXY)ETHYL]-PYRROLIDINE 1-(3-BROMOBENZYL)PYRROLIDINE 3-(DIETHYLAMINOMETHYL)-BROMOBENZENE 4-(DIETHYLAMINOMETHYL)-BROMOBENZENE 4-(4-BROMOBENZOYL) MORPHOLINE 4-(4-Bromobenzyl)morpholine ((4-BROMO-3-METHYLPHENYL)CARBONYL)MORPHOLINE 4-(4-bromobenzoyl)-2-methylmorpholine RARECHEM AL FE 0071 4-(4-bromo-2-fluorobenzoyl)-2,6-dimethylmorpholine 2-(4-bromophenyl)-2-(2,6-dimethylmorpholin-4-yl)ethanamine 2-(4-bromophenyl)-2-morpholin-4-ylethanamine C-[4-(4-BROMO-BENZYL)-MORPHOLIN-2-YL]-METHYLAMINE DIHYDROCHLORIDE 4-(4-bromobenzoyl)-2,6-dimethylmorpholine 2-(4-bromophenyl)-2-(2-methylmorpholin-4-yl)ethanamine 4-(4-bromo-2-fluorobenzoyl)-2-methylmorpholine 4-(4-bromo-2-fluorobenzoyl)morpholine

Morpholine,4-[(4-broMophenyl)Methyl]-

4-(morpholin-4-ylmethyl)-1-bromobenzene

132833-51-3

alkyl bromide

Amino

Aryl

Organohalides