4-(4-Bromobenzyl)morpholine
- Product Name
- 4-(4-Bromobenzyl)morpholine
- CAS No.
- 132833-51-3
- Chemical Name
- 4-(4-Bromobenzyl)morpholine
- Synonyms
- Morpholine,4-[(4-broMophenyl)Methyl]-;4-(morpholin-4-ylmethyl)-1-bromobenzene
- CBNumber
- CB8957102
- Molecular Formula
- C11H14BrNO
- Formula Weight
- 256.14
- MOL File
- 132833-51-3.mol
4-(4-Bromobenzyl)morpholine Property
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- solid
- color
- White
- InChI
- InChI=1S/C11H14BrNO/c12-11-3-1-10(2-4-11)9-13-5-7-14-8-6-13/h1-4H,5-9H2
- InChIKey
- KWJZFQQTDGVBOX-UHFFFAOYSA-N
- SMILES
- N1(CC2=CC=C(Br)C=C2)CCOCC1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- BML00227
- Product name
- 4-(4-Bromobenzyl)morpholine
- Purity
- Aldrich
- Packaging
- 1g
- Price
- $42.8
- Updated
- 2025/07/31
- Product number
- B680883
- Product name
- 4-(4-Bromobenzyl)morpholine
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB124240
- Product name
- 4-(4-Bromobenzyl)morpholine
- Packaging
- 2g
- Price
- $218
- Updated
- 2021/12/16
- Product number
- FB124240
- Product name
- 4-(4-Bromobenzyl)morpholine
- Packaging
- 10g
- Price
- $741
- Updated
- 2021/12/16
- Product number
- HCH0022161
- Product name
- 4-(4-BROMOBENZYL)MORPHOLINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $765.23
- Updated
- 2021/12/16
4-(4-Bromobenzyl)morpholine Chemical Properties,Usage,Production
Synthesis
110-91-8
589-15-1
132833-51-3
Morpholine (13, 1.4 mL, 1.39 g, 16 mmol) and 4-bromobenzyl bromide (12, 1.0 g, 4 mmol) were reacted in acetonitrile (50 mL). The reaction mixture was heated to reflux for 4 hours. After completion of the reaction, water was added and extracted with dichloromethane (3 x 50 mL). The organic layers were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The residue was purified by fast column chromatography (silica gel column, 6 cm diameter, 50 mL volume, eluent n-hexane/ethyl acetate=8/2, Rf=0.19) to afford the target product 14 as a colorless solid (1.0 g, 3.9 mmol, 98% yield). The melting point of the product was 85 °C. Structural confirmation and purity analysis of the product were carried out by various analytical methods including 1H NMR, 13C NMR, IR, MS (ESI), HRMS and HPLC, which showed that the product was pure and structurally correct.
References
[1] Carbohydrate Research, 2012, vol. 359, p. 59 - 64,6
[2] Carbohydrate Research, 2012, vol. 359, p. 59 - 64
[3] Patent: WO2013/153357, 2013, A1. Location in patent: Page/Page column 18; 39
[4] Patent: US2015/45354, 2015, A1. Location in patent: Paragraph 0233-0236
[5] Patent: WO2008/154642, 2008, A2. Location in patent: Page/Page column 188-189
4-(4-Bromobenzyl)morpholine Preparation Products And Raw materials
Raw materials
Preparation Products
4-(4-Bromobenzyl)morpholine Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 4-(4-Bromobenzyl)morpholine manufacturers
- Product
- 4-(4-Bromobenzyl)morpholine 132833-51-3
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200KG
- Release date
- 2018-12-23
- Product
- 4-(4-Bromobenzyl)morpholine 132833-51-3
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200KG
- Release date
- 2018-12-23
- Product
- 4-(4-Bromobenzyl)morpholine 132833-51-3
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200KG
- Release date
- 2018-12-23