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Tetramethylammonium borohydride

Product Name
Tetramethylammonium borohydride
CAS No.
16883-45-7
Chemical Name
Tetramethylammonium borohydride
Synonyms
TMAB;Nsc164901;BISMUTH(III) SUBNITRATE 98%;tetramethylammoniumborohydrate;TETRAMETHYLAMMONIUM BOROHYDRIDE;Tetramethylammoniumborohydride,95%;Tetra-methyl ammonium boron hydride;TetraMethylaMMoniuM borohydride 95%;Tetramethylammonium Borohydride Tetramethylammonium borohydride,TMAB
CBNumber
CB9101342
Molecular Formula
C4H16BN
Formula Weight
88.99
MOL File
16883-45-7.mol
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Tetramethylammonium borohydride Property

Melting point:
150°C (dec.)
Density 
0,813 g/cm3
storage temp. 
2-8°C
Water Solubility 
almost transparency in Water
form 
crystal
color 
white
Specific Gravity
0.813
Sensitive 
Moisture Sensitive
BRN 
3684968
EPA Substance Registry System
Methanaminium, N,N,N-trimethyl-, tetrahydroborate(1-) (16883-45-7)
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Safety

Hazard Codes 
F,T,Xi
Risk Statements 
15-25-36/38-36/37/38
Safety Statements 
26-36/37/39-43-45-36
RIDADR 
UN 3134 4.3/PG 2
WGK Germany 
3
RTECS 
BS8310000
TSCA 
Yes
HS Code 
2942.00.5000
HazardClass 
4.3
PackingGroup 
I
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H261In contact with water releases flammable gas

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
310689
Product name
Tetramethylammonium borohydride
Purity
95%
Packaging
10g
Price
$29.2
Updated
2022/05/15
Sigma-Aldrich
Product number
310689
Product name
Tetramethylammonium borohydride
Purity
95%
Packaging
50g
Price
$139
Updated
2022/05/15
TCI Chemical
Product number
T0852
Product name
Tetramethylammonium Borohydride [Reducing Reagent]
Purity
>90.0%(T)
Packaging
5g
Price
$28
Updated
2024/03/01
TCI Chemical
Product number
T0852
Product name
Tetramethylammonium Borohydride [Reducing Reagent]
Purity
>90.0%(T)
Packaging
25g
Price
$78
Updated
2024/03/01
Alfa Aesar
Product number
A17655
Product name
Tetramethylammonium borohydride
Purity
95%
Packaging
5g
Price
$29.5
Updated
2021/12/16
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Tetramethylammonium borohydride Chemical Properties,Usage,Production

Uses

Reactant for:

  • Preparation of iridium tetrahydride complexes bearing a tridentate pincer-type bis(phosphino)silyl ligand
  • Reduction reactions (reducing agent)

Purification Methods

Recrystallisation of the borohydride from H2O three times yields ca 94% pure compound. Dry in high vacuum at 100o for 3hours. The solubility in H2O is 48% (20o), 61% (40o), and in EtOH 0.5% (25o) and MeCN 0.4% (25o). It decomposes slowly in a vacuum at 150o, but rapidly at 250o. The rate of hydrolysis of Me4N.BH4 (5.8M) in H2O at 40o is constant over a period of 100hours at 0.04% of original wt/hour. The rate decreases to 0.02%/hour in the presence of Me4NOH (5% of the wt of Me4N.BH4). [Banus et al. J Am Chem Soc 74 2346 1952, Beilstein 4 IV 148.]

Tetramethylammonium borohydride Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetramethylammonium borohydride Suppliers

China 49 France 1 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 3 United States 10 Global 69
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from Tetramethylammonium borohydride manufacturers

Career Henan Chemical Co
Product
Tetramethylammonium borohydride 16883-45-7
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-02-01

16883-45-7, Tetramethylammonium borohydrideRelated Search:

Tetramethylammonium hydroxide pentahydrate Sodium cyanoborohydride Tetraethylammonium tetrafluoroborate Sodium triacetoxyborohydride Tetramethylammonium hydroxide Tetrabutylammonium borohydride TETRAMETHYLAMMONIUM TETRAFLUOROBORATE Tetrabutylammonium tetrafluoroborate 1-ChloroMethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) TETRAETHYLAMMONIUM BOROHYDRIDE Potassium borohydride Lithium borohydride Sodium borohydride BENZYLTRIETHYLAMMONIUM TETRAFLUOROBORATE BENZYLTRIETHYLAMMONIUM BOROHYDRIDE TETRA-N-BUTYLAMMONIUM TETRAPHENYLBORATE TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE Tetrabutylammonium cyanoborohydride

  • Ammonium, tetramethyl-, tetrahydroborate(1-)
  • Methanaminium, N,N,N-trimethyl-, tetrahydroborate(1-)
  • Nsc164901
  • Tetra-methyl ammonium boron hydride
  • Tetramethylammonium tetrahydroborate(1-)
  • Tetramethylammonium borohydride,TMAB
  • TetraMethylaMMoniuM borohydride 95%
  • Tetramethylammonium Borohydride&nbsp
  • n,n,n-trimethylmethanaminiumtetrahydroborate(1-)
  • n,n,n-trimethyl-methanaminiutetrahydroborate(1-)
  • tetramethylammoniumborohydrate
  • tetramethyl-ammoniutetrahydroborate(1-)
  • TMAB
  • TETRAMETHYLAMMONIUM TETRAHYDRIDOBORATE
  • TETRAMETHYLAMMONIUM BOROHYDRIDE
  • tetramethylammonium tetrahydroborate
  • BISMUTH(III) SUBNITRATE 98%
  • Tetramethylammoniumborohydride,95%
  • Tetramethylammonium Borohydride [Reducing Reagent]
  • TetramethylammoniumBorohydride[ReducingReagent]&gt
  • Tetramethylammonium borohydride (6CI)
  • 16883-45-7
  • C4H16NB
  • CH34NBH4
  • C4H12NBH4
  • C4H16BN
  • Borohydrides
  • Synthetic Reagents
  • Quaternary Ammonium Compounds
  • B (Classes of Boron Compounds)
  • Ammonium Polyhalides, etc. (Quaternary)
  • Tetrahydroborates
  • Reduction
  • Ammonium Polyhalides, etc. (Quaternary)
  • B (Classes of Boron Compounds)
  • metal hydrides
  • Quaternary Ammonium Compounds
  • Reduction
  • Synthetic Organic Chemistry
  • Tetrahydroborates