Tetrabutylammonium cyanoborohydride
- Product Name
- Tetrabutylammonium cyanoborohydride
- CAS No.
- 43064-96-6
- Chemical Name
- Tetrabutylammonium cyanoborohydride
- Synonyms
- TETRABUTYLAMMONIUM CYANOBOROHYDRIDE;TETRABUTYLAMMONIUM CYANOTRIHYDROBORATE;Tetra-n-butylammonium Cyanoborohydride;Tetrabutylammonium cyanoborohydride,98%;Tetrabutylammonium cyanoborohydride,95%;Cyano-trihydrido-boron tetrabutylazanium;tetrabutylammonium (cyano-C)trihydroborate;Tetrabutylammonium cyanoborohydride ISO 9001:2015 REACH;1-Butanaminium, N,N,N-tributyl-, (T-4)-(cyano-C)trihydroborate(1-)
- CBNumber
- CB1312506
- Molecular Formula
- C17H39BN2
- Formula Weight
- 282.32
- MOL File
- 43064-96-6.mol
Tetrabutylammonium cyanoborohydride Property
- Melting point:
- 144-146 °C(lit.)
- storage temp.
- water-free area
- solubility
- sol most polar (e.g. alcohols, carboxylic acids), polar aprotic (e.g. HMPA, DMSO, DMF), and nonpolar (e.g. CH2Cl2, benzene, hexane) solvents; sparingly sol H2O, ether.
- form
- nonhydroscopic solid
- color
- white
- CAS DataBase Reference
- 43064-96-6
Safety
- Hazard Codes
- Xi,F
- Risk Statements
- 36/37/38-15
- Safety Statements
- 26-36-7/8-37/39
- WGK Germany
- 3
- F
- 21
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- T310840
- Product name
- Tetrabutylammonium cyanoborohydride
- Packaging
- 500mg
- Price
- $80
- Updated
- 2021/12/16
- Product number
- ING0003094
- Product name
- TETRABUTYLAMMONIUM CYANOBOROHYDRIDE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1260.65
- Updated
- 2021/12/16
Tetrabutylammonium cyanoborohydride Chemical Properties,Usage,Production
Chemical Properties
white crystalline powder
Uses
Tetrabutylammonium Cyanoborohydride is used in preparation method of novel biomass plastic material.
Uses
Reactant for:
- Hydroxymethylation reactions
- Radical carbonylation reactions
- Reduction reactions (reductant)
Application
Tetrabutylammonium cyanoborohydride (TBAC) is used as a selective, mild reducing reagent for aldehydes, conjugated aldehydes and ketones, alkyl iodides and bromides; useful for reductive aminations of aldehydes and ketones in nonpolar solvents.
Preparation
Tetrabutylammonium cyanoborohydride is prepared from n-Bu4NHSO4 suspended in H2O, treated with Sodium Hydroxide and Sodium Cyanoborohydride, and extracted into CH2Cl2; recrystallized from ethyl acetate. Other tetraalkylammonium derivatives are available (including polymersupported) or can be generated in situ from NaBH3CN and Aliquat 336.
reaction suitability
reagent type: reductant
Tetrabutylammonium cyanoborohydride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tetrabutylammonium cyanoborohydride manufacturers
- Product
- Tetrabutylammonium cyanoborohydride 43064-96-6
- Price
- US $1.00-22.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100000KG
- Release date
- 2024-08-23