Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI)
- Product Name
- Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI)
- CAS No.
- 132844-48-5
- Chemical Name
- Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI)
- Synonyms
- N-Boc-CycL;N-Boc-cyclopropylamine;tert-Butyl cyclopropylcarbamate;REF DUPL: N-Boc-cyclopropylamine;Cyclopropylamine, N-BOC protected;tert-butyl N-cyclopropylcarbaMate;BOC-Cyclopropylamine extrapure, 98%;Cyclopropylamine, N-BOC protected 97%;N-(tert-Butoxycarbonyl)cyclopropylamine;1,1-Dimethylethyl N-cyclopropylcarbamate
- CBNumber
- CB91060127
- Molecular Formula
- C8H15NO2
- Formula Weight
- 157.21
- MOL File
- 132844-48-5.mol
Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI) Property
- Melting point:
- 62-64°
- Boiling point:
- 228.6±7.0 °C(Predicted)
- Density
- 1.01±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 12.74±0.20(Predicted)
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2924190090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B646258
- Product name
- N-Boc-Cyclopropylamine
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 4256-1-07
- Product name
- tert-Butyl N-cyclopropylcarbamate
- Purity
- 98.0%
- Packaging
- 1g
- Price
- $56
- Updated
- 2021/12/16
- Product number
- FB140638
- Product name
- tert-Butyl cyclopropylcarbamate
- Packaging
- 2g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 074921
- Product name
- N-Boc-Cyclopropylamine
- Purity
- 95+%
- Packaging
- 1g
- Price
- $70
- Updated
- 2021/12/16
- Product number
- B260
- Product name
- N-Boc-Cyclopropylamine
- Packaging
- 10g
- Price
- $75
- Updated
- 2021/12/16
Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI) Chemical Properties,Usage,Production
Synthesis
24424-99-5
765-30-0
132844-48-5
Step 1. Dissolve cyclopropylamine (12.4 g, 252.2 mmol) in dichloromethane (50 mL) at 0°C and cool in an ice water bath. A solution of di-tert-butyl dicarbonate (43.7 g, 200 mmol) in dichloromethane (100 mL) was slowly added dropwise. After the dropwise addition, the reaction mixture was transferred to room temperature and stirred continuously for 18 hours. Upon completion of the reaction, the solvent was removed by vacuum evaporation to afford N-Boc-cyclopropylamine (31 g, 99% yield).
References
[1] Journal of Medicinal Chemistry, 2014, vol. 57, # 6, p. 2213 - 2236
[2] Journal of Heterocyclic Chemistry, 1990, vol. 27, # 6, p. 1527 - 1536
[3] Patent: US2007/225280, 2007, A1. Location in patent: Page/Page column 17
[4] Monatshefte fur Chemie, 2017, vol. 148, # 12, p. 2143 - 2153
[5] Organic Letters, 2012, vol. 14, # 17, p. 4458 - 4461
Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI) manufacturers
- Product
- Carbamic acid, cyclopropyl-, 1,1-dimethylethyl ester (9CI) 132844-48-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2019-12-25