Ethyl4-methylamino-3-nitrobenzoate
- Product Name
- Ethyl4-methylamino-3-nitrobenzoate
- CAS No.
- 71254-71-2
- Chemical Name
- Ethyl4-methylamino-3-nitrobenzoate
- Synonyms
- -3-nitrobenzoate;Ethyl4-methylamino-3-nitrobenzoate;4-(Methylamino)-3-nitro-benzoic acid ethylester;Benzoic acid, 4-(methylamino)-3-nitro-, ethyl ester
- CBNumber
- CB91073525
- Molecular Formula
- C10H12N2O4
- Formula Weight
- 224.21
- MOL File
- 71254-71-2.mol
Ethyl4-methylamino-3-nitrobenzoate Property
- Melting point:
- 101 °C
- Boiling point:
- 372.8±32.0 °C(Predicted)
- Density
- 1.280±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- -2.62±0.25(Predicted)
- Appearance
- Yellow to orange Solid
Safety
- HS Code
- 2922390090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- W8024
- Product name
- Ethyl4-(methylamino)-3-nitrobenzoate
- Packaging
- 1g
- Price
- $212
- Updated
- 2021/12/16
- Product number
- 175038
- Product name
- Ethyl 4-(methylamino)-3-nitrobenzoate
- Packaging
- 1g
- Price
- $432
- Updated
- 2021/12/16
- Product number
- CHM0079483
- Product name
- ETHYL 4-METHYLAMINO-3-NITROBENZOATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $909.56
- Updated
- 2021/12/16
- Product number
- 175038
- Product name
- Ethyl 4-(methylamino)-3-nitrobenzoate
- Packaging
- 5g
- Price
- $1206
- Updated
- 2021/12/16
- Product number
- 175038
- Product name
- Ethyl 4-(methylamino)-3-nitrobenzoate
- Packaging
- 10g
- Price
- $1602
- Updated
- 2021/12/16
Ethyl4-methylamino-3-nitrobenzoate Chemical Properties,Usage,Production
Synthesis
367-80-6
74-89-5
71254-71-2
Ethyl 4-fluoro-3-nitrobenzoate (10.0 g, 46.9 mmol) prepared in Step 1-1-1 was dissolved in methanol (40 mL) and triethylamine (10 mL, 70.4 mmol) was added. A 40% methylamine-methanol solution (5.50 g, 70.4 mmol) was slowly added to the reaction mixture under ice bath cooling conditions. The reaction mixture was stirred continuously for 1 h under ice bath cooling and then ice water was added to quench the reaction. The precipitate was separated by filtration and washed with cold water. The washed product was subjected to cyclic drying overnight to afford ethyl 4-methylamino-3-nitrobenzoate (10.4 g, 99% yield) as a yellow powder.1H-NMR (CDCl3) δ: 8.87 (d, J = 1.9 Hz, 1H), 8.33 (brs, 1H), 8.08 (dd, J = 1.9, 9.2 Hz, 1H), 6.87- 6.84 (m, 1H), 4.35 (q, J = 6.9 Hz, 2H), 3.08 (d, J = 5.0 Hz, 3H), 1.38 (t, J = 6.9 Hz, 3H). Mass spectrum (m/z): 224 (M+), 179, 105 (base peak).
References
[1] Patent: US2013/79306, 2013, A1. Location in patent: Paragraph 0230; 0231; 0232; 0233
Ethyl4-methylamino-3-nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Ethyl4-methylamino-3-nitrobenzoate Suppliers
- Tel
- --
- Fax
- --
- akos@akosgmbh.eu
- Country
- Germany
- ProdList
- 1061
- Advantage
- 60
- Tel
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- Fax
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- sales@chemos-group.com
- Country
- Germany
- ProdList
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- Advantage
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View Lastest Price from Ethyl4-methylamino-3-nitrobenzoate manufacturers
- Product
- Ethyl4-methylamino-3-nitrobenzoate 71254-71-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-02