4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
Application- Product Name
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
- CAS No.
- 870774-25-7
- Chemical Name
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID
- Synonyms
- 4-(Naphthalen-1-yl);Boronic acid, [4-(1-napht;1-(4-Boronophenyl)naphthalene;4-(1-phthyl)phenylboronic acid;4-(1-Naphtyl)phenylboronic acid;-(1-Naphthyl)benzeneboronic Acid;4-(1-Naphthyl)phenylboronic acid;4-(1-Naphthyl)benzeneboronic Acid;4-(Naphth-1-yl)benzeneboronic acid;4-(1-naphthalenyl)phenylboronic acid
- CBNumber
- CB91119184
- Molecular Formula
- C16H13BO2
- Formula Weight
- 248.08
- MOL File
- 870774-25-7.mol
4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID Property
- Boiling point:
- 449.4±48.0 °C(Predicted)
- Density
- 1.23±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- soluble in Tetrahydrofuran
- form
- powder to crystal
- pka
- 8.58±0.16(Predicted)
- color
- White to Light yellow
- InChI
- InChI=1S/C16H13BO2/c18-17(19)14-10-8-13(9-11-14)16-7-3-5-12-4-1-2-6-15(12)16/h1-11,18-19H
- InChIKey
- BQHVXFQXTOIMQM-UHFFFAOYSA-N
- SMILES
- B(C1=CC=C(C2=C3C(C=CC=C3)=CC=C2)C=C1)(O)O
Safety
- HS Code
- 2931900090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- N0798
- Product name
- 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $27
- Updated
- 2025/07/31
- Product number
- N0798
- Product name
- 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $75
- Updated
- 2025/07/31
- Product number
- N378423
- Product name
- 4-(Naphthalen-1-yl)phenylboronicAcid
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- CS-W000991
- Product name
- 4-(1-Naphthyl)benzeneboronic acid
- Purity
- 98.65%
- Packaging
- 5g
- Price
- $25
- Updated
- 2021/12/16
- Product number
- CS-W000991
- Product name
- 4-(1-Naphthyl)benzeneboronic acid
- Purity
- 98.65%
- Packaging
- 25g
- Price
- $96
- Updated
- 2021/12/16
4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID Chemical Properties,Usage,Production
Application
4-(1-Naphthyl)phenylboronic acid is an acid derivative that can be used as an intermediate in organic synthesis.
Chemical Properties
off-white powder
Synthesis
204530-94-9
870774-25-7
A mixed solution of 208.8 g (737.4 mmol) of 1-(4-bromophenyl)naphthalene with 2.1 L of anhydrous tetrahydrofuran (THF) was cooled to -60 °C under argon protection. Subsequently, 567 mL (884.9 mmol) of 1.56 M n-butyllithium hexane solution was added slowly dropwise under stirring conditions. After the dropwise addition was completed, the reaction mixture was continued to be stirred at -60 °C for 2 hours. Maintaining the temperature at -60 °C, 416 g (2.21 mol) of triisopropyl borate was added dropwise to the reaction system. After completion of the dropwise addition, the reaction mixture was gradually warmed to room temperature and stirred for 17 hours. At the end of the reaction, an aqueous hydrochloric acid solution was added to the mixture and stirred for 1 hour at room temperature. The reaction mixture was extracted with toluene, and the aqueous phase was separated and discarded. The organic phase was dried with magnesium sulfate and the solvent was removed by distillation under reduced pressure. The resulting solid was purified by recrystallization from toluene to give 126 g of 4-(1-naphthyl)phenylboronic acid in 67% yield.
References
[1] Patent: US2010/331585, 2010, A1. Location in patent: Page/Page column 96-97
4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID manufacturers
- Product
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID 870774-25-7
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-27
- Product
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID 870774-25-7
- Price
- US $188.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-05
- Product
- 4-(NAPHTHALEN-1-YL)PHENYLBORONIC ACID 870774-25-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%Min
- Supply Ability
- 1000kg
- Release date
- 2023-03-12