4-(Iodomethyl)tetrahydro-2H-pyran
- Product Name
- 4-(Iodomethyl)tetrahydro-2H-pyran
- CAS No.
- 101691-94-5
- Chemical Name
- 4-(Iodomethyl)tetrahydro-2H-pyran
- Synonyms
- 4-(iodomethyl)oxane;4-IODOMETHYLTETRAHYDROPYRAN;4-(Iodomethyl)tetrahydropyrane;4-(IODOMETHYL)TETRAHYDRO-2H-PYRAN;(4-TETRAHYDROPYRANYL)METHYL IODIDE;Tetrahydro-4-(iodomethyl)-2H-pyran;4-(Iodomethyl)tetrahydro-2H-pyrane;2H-Pyran, tetrahydro-4-(iodomethyl)-
- CBNumber
- CB9120260
- Molecular Formula
- C6H11IO
- Formula Weight
- 226.06
- MOL File
- 101691-94-5.mol
4-(Iodomethyl)tetrahydro-2H-pyran Property
- Boiling point:
- 229.1±13.0 °C(Predicted)
- Density
- 1.645±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Store in freezer, under -20°C
Safety
- Risk Statements
- 34
- Safety Statements
- 23-26-36/37/39-45
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 2H10-H-03
- Product name
- 4-(Iodomethyl)oxane
- Packaging
- 1g
- Price
- $83
- Updated
- 2021/12/16
- Product number
- 092540
- Product name
- 4-(Iodomethyl)tetrahydro-2H-pyran
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $189
- Updated
- 2021/12/16
- Product number
- 2H10-H-03
- Product name
- 4-(Iodomethyl)oxane
- Packaging
- 5G
- Price
- $300
- Updated
- 2021/12/16
- Product number
- 092540
- Product name
- 4-(Iodomethyl)tetrahydro-2H-pyran
- Purity
- 95+%
- Packaging
- 1g
- Price
- $420
- Updated
- 2021/12/16
- Product number
- HCH0022345
- Product name
- 4-(IODOMETHYL)TETRAHYDRO-2H-PYRAN
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $750.68
- Updated
- 2021/12/16
4-(Iodomethyl)tetrahydro-2H-pyran Chemical Properties,Usage,Production
Synthesis
4-(Iodomethyl)tetrahydro-2H-pyran is prepared from 4-(methanesulfonyloxymethyl)tetrahydropyran by heating and refluxing under conditions of reaction with sodium iodide in acetone. The specific method of operation is described below:
.
Preparation: A mixture of Preparation (328g, 1.69mol) and sodium iodide (507g, 3.4mol) in acetone (3.3L) was refluxed for 4h. TLC (diethyl ether) showed significant mesylate remaining so further sodium iodide (127g, 0.65mol) was added and reflux continued for 16h. The mixture was cooled and filtered. The resulting cake was washed with acetone, dried, and11then partitioned between diethyl ether (800mL) and water (800mL). The aqueous phase was re-extracted with diethyl ether (200mL), the ether extracts combined and washed with 10% sodium thiosulphate solution (300mL) which decolourised the extract. Final washing with water (300mL), drying (MgS04) and then removal of the solvent provided the 4-(IODOMETHYL)TETRAHYDRO-2H-PYRAN (365g, 92% yield).
4-(Iodomethyl)tetrahydro-2H-pyran Preparation Products And Raw materials
Raw materials
Preparation Products
4-(Iodomethyl)tetrahydro-2H-pyran Suppliers
View Lastest Price from 4-(Iodomethyl)tetrahydro-2H-pyran manufacturers
- Product
- 4-(Iodomethyl)tetrahydro-2H-pyran 101691-94-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 500kg
- Release date
- 2018-08-16