ChemicalBook > CAS DataBase List > 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

Product Name
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
CAS No.
18422-53-2
Chemical Name
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
Synonyms
D-EPOXONE;D-EPOXONE(R);D-Epoxone(rg;-[1,4]dioxolan]-7-one;Shi’s epoxidation catalyst;shi epoxidation diketal catalyst;Shi Epoxidation Diketal Catalyst 98%;1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- &;1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO&;1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo
CBNumber
CB9122633
Molecular Formula
C12H18O6
Formula Weight
258.27
MOL File
18422-53-2.mol
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1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Property

Melting point:
102-104 °C(lit.)
Boiling point:
341.9±42.0 °C(Predicted)
Density 
1.28±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Soluble in chloroform and methanol.
form 
Solid
color 
White to Pale Yellow
optical activity
[α]20/D 120.9°, c = 1 in chloroform
BRN 
1319073
InChI
InChI=1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3
InChIKey
IVWWFWFVSWOTLP-UHFFFAOYSA-N
SMILES
C12(COC(C)(C)O1)OCC1OC(C)(C)OC1C2=O
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29329990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
520160
Product name
Shi Epoxidation Diketal Catalyst
Purity
98%
Packaging
5g
Price
$229
Updated
2025/07/31
TCI Chemical
Product number
E1579
Product name
Shi Epoxidation Diketal Catalyst
Purity
min. 98.0 %
Packaging
1G
Price
$144
Updated
2025/07/31
TCI Chemical
Product number
E1579
Product name
Shi Epoxidation Diketal Catalyst
Purity
min. 98.0 %
Packaging
5G
Price
$432
Updated
2025/07/31
TRC
Product number
S354000
Product name
Shi Epoxidation Diketal Catalyst
Packaging
1g
Price
$120
Updated
2021/12/16
TRC
Product number
S354000
Product name
Shi Epoxidation Diketal Catalyst
Packaging
5g
Price
$485
Updated
2021/12/16
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1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

Shi Epoxidation Diketal Catalyst is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.

Uses

Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline''s reagent guide.

An Efficient Catalytic Asymmetric Epoxidation Method

Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

Uses

1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Suppliers

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View Lastest Price from 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose 18422-53-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-30
Career Henan Chemical Co
Product
1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE 18422-53-2?
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
100KG
Release date
2018-12-21

18422-53-2, 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSERelated Search:

Allene GLYOXAL DIMETHYL ACETAL 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE KETHOXAL 3,3-Dimethoxybutan-2-one 1,3,3-TRIMETHOXYBUTANE 1,3-DIMETHOXYACETONE 2H-PYRAN-3(4H)-ONE, DIHYDRO- 2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

  • 1,2:4,5-DI-O-ISOPROPYLIDEN-BETA-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
  • 4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
  • -[1,4]dioxolan]-7-one
  • 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
  • shi epoxidation diketal catalyst
  • di-O-isopropylidene-beta-D-erythro-2,3-hexodiulopyranose
  • D-EPOXONE
  • D-EPOXONE(R)
  • 1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo
  • D-Epoxone(rg
  • 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- &
  • 1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO&
  • 1,2:4,5-di-o-isopropylidene-á-d-erythro-2,3-hexodiulo-2,6-pyranose
  • 1,2:4,5-di-o-isopropylidene-β-d-erythro-2,3-hexodiulo-2,6-pyranose
  • Shi’s epoxidation catalyst
  • Shi Epoxidation Diketal Catalyst 98%
  • (3'aR,4S,7'aR)-2,2,2',2'-tetramethylspiro[1,3-dioxolane-4,6'-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7'-one
  • (3aR,4'R,7aR)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolo[4,5-c]pyran-6,4'-[1,3]dioxolan]-7(7aH)-one
  • (3a'R,4R,7a'R)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one
  • 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE USP/EP/BP
  • 1,2:4,5-di-O-isopropylidene-β-D-erythro-hexo-2,3-diulo-2,6-pyranose
  • 1,2:4,5-Bis-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose
  • C12H18O6 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE 18422-53-2
  • (4S,7''aR)-2,2,2'',2''-tetramethylspiro[1,3-dioxolane-4,6''-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7''-one
  • β-D-erythro-2,3-Hexodiulo-2,6-pyranose, 1,2:4,5-bis-O-(1-methylethylidene)-
  • (3aR,6S,7aR)-2,2,5',5'-tetramethyl-tetrahydro-2H-spiro[[1,3]dioxolo[4,5-c]pyran-6,2'-[1,4]dioxolan]-7-one
  • 1,2:4,5-Di-O-Isopropylidene-L-Erythro-2,3-Hexodiuro-2,6-Pyranose
  • (3a'R,4R,7a'R)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one - [T89302]
  • 18422-53-2
  • Epoxidation
  • Monosaccharide
  • Asymmetric Synthesis
  • Carbohydrates
  • Chiral Catalysts, Ligands, and Reagents
  • BioChemical
  • Biochemicals and Reagents