1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

Product Name: 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
CAS No.: 18422-53-2
Chemical Name: 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE
Synonyms: D-EPOXONE;D-EPOXONE(R);D-Epoxone(rg;-[1,4]dioxolan]-7-one;Shi’s epoxidation catalyst;shi epoxidation diketal catalyst;Shi Epoxidation Diketal Catalyst 98%;1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- &;1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO&;1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo
CBNumber: CB9122633
Molecular Formula: C12H18O6
Formula Weight: 258.27
MOL File: 18422-53-2.mol

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1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Property

Melting point:: 102-104 °C(lit.)
Boiling point:: 341.9±42.0 °C(Predicted)
Density: 1.28±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,2-8°C
solubility: Soluble in chloroform and methanol.
form: Solid
color: White to Pale Yellow
optical activity: [α]20/D 120.9°, c = 1 in chloroform
BRN: 1319073

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29329990

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 520160
Product name: Shi Epoxidation Diketal Catalyst
Purity: 98%
Packaging: 5g
Price: $222
Updated: 2024/03/01

Alfa Aesar

Product number: L18989
Product name: D-Epoxone, 98%
Packaging: 1g
Price: $50.65
Updated: 2024/03/01

Alfa Aesar

Product number: L18989
Product name: D-Epoxone, 98%
Packaging: 5g
Price: $203.65
Updated: 2024/03/01

TRC

Product number: S354000
Product name: Shi Epoxidation Diketal Catalyst
Packaging: 1g
Price: $120
Updated: 2021/12/16

TRC

Product number: S354000
Product name: Shi Epoxidation Diketal Catalyst
Packaging: 5g
Price: $485
Updated: 2021/12/16

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1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

Shi Epoxidation Diketal Catalyst is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.

Uses

Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline''s reagent guide.

An Efficient Catalytic Asymmetric Epoxidation Method

Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

Uses

1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose is a chemical reagent used in the synthesis of Irciniastatin (A & B), cytotoxic secondary metabolites. Used in epoxidation reactions.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE Suppliers

Canada 2 China 98 Germany 2 India 6 Switzerland 1 The Netherlands 1 United Kingdom 4 United States 9 Global 123

DSM Pharma Chemicals

Tel: --
Fax: --
Email: ian.freelance@dsm.com
Country: The Netherlands
ProdList: 78
Advantage: 30

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View Lastest Price from 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose 18422-53-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-30

Career Henan Chemical Co

Product: 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE 18422-53-2?
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 100KG
Release date: 2018-12-21

18422-53-2, 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSERelated Search:

Allene GLYOXAL DIMETHYL ACETAL 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE KETHOXAL 3,3-Dimethoxybutan-2-one 1,3,3-TRIMETHOXYBUTANE 1,3-DIMETHOXYACETONE 2H-PYRAN-3(4H)-ONE, DIHYDRO- 2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

1,2:4,5-DI-O-ISOPROPYLIDEN-BETA-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

-[1,4]dioxolan]-7-one

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE

shi epoxidation diketal catalyst

di-O-isopropylidene-beta-D-erythro-2,3-hexodiulopyranose

D-EPOXONE

D-EPOXONE(R)

1,2:4,5-di-O-isopropylidene-B-D-*erythro-2,3-hexo

D-Epoxone(rg

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA- &

1 2:4 5-DI-O-ISOPROPYLIDENE-B-D-ERYTHRO&

1,2:4,5-di-o-isopropylidene-á-d-erythro-2,3-hexodiulo-2,6-pyranose

1,2:4,5-di-o-isopropylidene-β-d-erythro-2,3-hexodiulo-2,6-pyranose

Shi’s epoxidation catalyst

Shi Epoxidation Diketal Catalyst 98%

(3'aR,4S,7'aR)-2,2,2',2'-tetramethylspiro[1,3-dioxolane-4,6'-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7'-one

(3aR,4'R,7aR)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolo[4,5-c]pyran-6,4'-[1,3]dioxolan]-7(7aH)-one

(3a'R,4R,7a'R)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one

1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE USP/EP/BP

1,2:4,5-di-O-isopropylidene-β-D-erythro-hexo-2,3-diulo-2,6-pyranose

1,2:4,5-Bis-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose

C12H18O6 1,2:4,5-DI-O-ISOPROPYLIDENE-BETA-D-ERYTHRO-2,3-HEXODIULO-2,6-PYRANOSE 18422-53-2

(4S,7''aR)-2,2,2'',2''-tetramethylspiro[1,3-dioxolane-4,6''-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7''-one

1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose

β-D-erythro-2,3-Hexodiulo-2,6-pyranose, 1,2:4,5-bis-O-(1-methylethylidene)-

(3aR,6S,7aR)-2,2,5',5'-tetramethyl-tetrahydro-2H-spiro[[1,3]dioxolo[4,5-c]pyran-6,2'-[1,4]dioxolan]-7-one

(3a'R,4R,7a'R)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolane-4,6'-[1,3]dioxolo[4,5-c]pyran]-7'(4'H)-one

1,2:4,5-Di-O-Isopropylidene-L-Erythro-2,3-Hexodiuro-2,6-Pyranose

18422-53-2

Epoxidation

Monosaccharide

Asymmetric Synthesis

Carbohydrates

Chiral Catalysts, Ligands, and Reagents

BioChemical

Biochemicals and Reagents