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2-FLUORORESORCINOL

Product Name
2-FLUORORESORCINOL
CAS No.
103068-40-2
Chemical Name
2-FLUORORESORCINOL
Synonyms
2-Fluoro-1,3-diol;2-fluororesocinol;2-Fluoro-1,3-benzenediol;1,3-Benzenediol, 2-fluoro-;2-fluoro-1,3-dihydroxybenzene
CBNumber
CB91263823
Molecular Formula
C6H5FO2
Formula Weight
128.1
MOL File
103068-40-2.mol
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2-FLUORORESORCINOL Property

Melting point:
114-116 °C
Boiling point:
223.5±20.0 °C(Predicted)
Density 
1.415±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
pka
8.19±0.10(Predicted)
Appearance
White to off-white Solid
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Safety

HS Code 
2908990000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
F598210
Product name
2-Fluorobenzene-1,3-diol
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
F598210
Product name
2-Fluorobenzene-1,3-diol
Packaging
100mg
Price
$130
Updated
2021/12/16
Apolloscientific
Product number
PC500671
Product name
2-Fluororesorcinol
Packaging
250mg
Price
$270
Updated
2021/12/16
SynQuest Laboratories
Product number
2604-3-08
Product name
2-Fluororesorcinol
Packaging
250mg
Price
$320
Updated
2021/12/16
Apolloscientific
Product number
PC500671
Product name
2-Fluororesorcinol
Packaging
1g
Price
$682
Updated
2021/12/16
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2-FLUORORESORCINOL Chemical Properties,Usage,Production

Synthesis

447462-87-5

103068-40-2

General procedure for the demethylation of BBr3: 2-fluoro-3-methoxyphenol (8.7 mmol) was dissolved in dry dichloromethane (40 mL) under nitrogen protection and cooled to -78°C. BBr3 (1 M solution in dichloromethane, 4 equivalents per methoxide) was added slowly and dropwise. The reaction mixture was stirred at -78 °C overnight, during which time the cooling bath was allowed to warm naturally to room temperature. Upon completion of the reaction, the mixture was cooled again to -78 °C and the reaction was quenched by careful dropwise addition of water. The aqueous layer was extracted with EtOAc, the organic layers were combined and dried over anhydrous Na2SO4. The solvent was evaporated under reduced pressure to give the crude product. The crude product was ground with EtOAc to give 2-fluoro-1,3-benzenediol, which could be used in subsequent reactions without further purification. The yield of the method was 93%. Mass spectrometry (MS) data: m/z 129.1 (MH+).

References

[1] Patent: US2009/298820, 2009, A1. Location in patent: Page/Page column 34
[2] Patent: WO2010/30727, 2010, A1. Location in patent: Page/Page column 92-93
[3] Patent: EP3401309, 2018, A1. Location in patent: Paragraph 0505
[4] Patent: US2009/311217, 2009, A1. Location in patent: Page/Page column 51
[5] Patent: WO2006/57860, 2006, A1. Location in patent: Page/Page column 114-115

2-FLUORORESORCINOL Preparation Products And Raw materials

Raw materials

Preparation Products

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2-FLUORORESORCINOL Suppliers

Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
150-2103-5486 18017383231
Fax
qq:2817624287
Email
983544897@qq.com
Country
China
ProdList
9342
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Tianjin Anhao Biological Technology Co., Ltd.
Tel
Email
sales@ahpharmatech.com
Country
China
ProdList
5734
Advantage
55
Changzhou Anxuan Chemical, Co., Ltd.
Tel
13912302692
Fax
0519-88064678
Email
sales@anxuanchem.com
Country
China
ProdList
4828
Advantage
58
Shanghai JingRon Chemical Technology Co., Ltd.
Tel
021-60546673 13701861782
Fax
QQ:670259431
Email
kuanga111@sina.com
Country
China
ProdList
934
Advantage
58
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Beijing Hechemist Technology CO.,LTD
Tel
18511709189
Fax
010-58043593
Email
sales@hechemist.com
Country
China
ProdList
2835
Advantage
58
Shanghai SuperLan Chemcial Technique Centre
Tel
0-2022843681 15618226720
Fax
+86-21-51601218
Email
chaolaichem@foxmail.com
Country
China
ProdList
12476
Advantage
58
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View Lastest Price from 2-FLUORORESORCINOL manufacturers

Honest Joy Holdings Limited
Product
2-Fluorobenzene-1,3-diol 103068-40-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98.1%
Supply Ability
100 tons
Release date
2022-01-17
Career Henan Chemical Co
Product
2-Fluoro-1,3-benzenediol 103068-40-2
Price
US $9.80/KG
Min. Order
1KG
Purity
>98%HPLC
Supply Ability
20 tons
Release date
2020-02-06