ChemicalBook > CAS DataBase List > 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide

Product Name
2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide
CAS No.
572-09-8
Chemical Name
2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide
Synonyms
(2R,3R,4S,5R,6R)-2-(Acetoxymethyl)-6-bromotetrahydro-2H-pyran-3,4,5-triyl triacetate;ACETOBROMOGLUCOSE;2,3,4,6-tetra-o-acetyl-α-d-glucopyranosyl bromide;2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide;acetobromo-a-d-glucose;Acetobromglucose;Acetobromo-α-D-glucose;A-D-GLUCOPYRANOSYL BROMIDE;TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE;Acetobromo-α-D-glucose;Acetobromglucose;Tetraacetyl bromoglucose
CBNumber
CB9142437
Molecular Formula
C14H19BrO9
Formula Weight
411.2
MOL File
572-09-8.mol
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2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Property

Melting point:
86-89 °C
alpha 
194.5 º (c=2,chloroform)
Boiling point:
0.125-30 °C(Press: 0.0005 Torr)
Density 
1.49±0.1 g/cm3(Predicted)
storage temp. 
−20°C
solubility 
Acetontrile (Very Slightly), Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
White to beige
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
Merck 
14,60
BRN 
96669
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
CYAYKKUWALRRPA-RGDJUOJXSA-N
CAS DataBase Reference
572-09-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-36-26
WGK Germany 
-
F 
8-10-21
HS Code 
29329985
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
A1750
Product name
Acetobromo-α-D-glucose
Purity
≥95% (TLC)
Packaging
10g
Price
$165
Updated
2024/03/01
Sigma-Aldrich
Product number
A1750
Product name
Acetobromo-α-D-glucose
Purity
≥95% (TLC)
Packaging
25g
Price
$354
Updated
2024/03/01
TCI Chemical
Product number
T1961
Product name
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide (stabilized with CaCO3)
Purity
>98.0%(T)
Packaging
5g
Price
$53
Updated
2024/03/01
Alfa Aesar
Product number
L04151
Product name
Acetobromo-alpha-D-glucose, 97%, stab. with 2% calcium carbonate
Packaging
10g
Price
$111
Updated
2024/03/01
Alfa Aesar
Product number
L04151
Product name
Acetobromo-alpha-D-glucose, 97%, stab. with 2% calcium carbonate
Packaging
50g
Price
$352
Updated
2024/03/01
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2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Chemical Properties,Usage,Production

Chemical Properties

White Fluffy Solid

Uses

An Intermediate in synthesis of ∫-glucosides

Uses

Acetobromo-α-D-glucose acts as an intermediate in the preparation of beta-glucosides. It is also used as a possible poly(ethylene terephthalate) surface modification reagent to enhance its blood compatibility.

Purification Methods

If nicely crystalline, recrystallise it from Et2O/pentane or pet ether (b 40-60o). Alternatively dissolve it in diisopropyl ether (dried over CaCl2 for 24hours, then over P2O5 for 24hours) by shaking and warming (for as short a period as possible), and filter warm. Cool to ca 45o, then slowly to room temperature and finally at 5o for more than 2hours. Collect the solid, wash it with cold dry diisopropyl ether and dry it in a vacuum over Ca(OH)2 and NaOH. Store it dry in a desiccator in the dark. Solutions can be stabilised with 2% CaCO3. [Redemann & Niemann Org Synth 65 236 1987, Coll Vol III 11 1955, Beilstein 17/6 V 368.]

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide Suppliers

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View Lastest Price from 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide 572-09-8
Price
US $5.00/kg
Min. Order
1kg
Purity
99.92%
Supply Ability
50000tons
Release date
2024-04-26
Henan Fengda Chemical Co., Ltd
Product
2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide 572-09-8
Price
US $5.00-2.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-16
Hebei Mojin Biotechnology Co., Ltd
Product
2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide 572-09-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-15

572-09-8, 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromideRelated Search:

BETA-GLUCOSIDASE Rocuronium bromide Acetoxyacetic acid Sodium triacetoxyborohydride Acetyl coenzyme A sodium salt 2,5-DIDEOXY-2,5-IMINO-D-MANNITOL Ethidium bromide Acetylacetone SILICON TETRAACETATE Allyl bromide Sodium bromate Centchroman Polydextrose Acetyl chloride AMYLOGLUCOSIDASE 2,3,4,6-Tetra-O-acetyl-alpha-D-galactopyranosyl bromide ACETOBROMO-ALPHA-D-GLUCURONIC ACID METHYL ESTER 2,5-Dimethoxyacetoacetanilide

  • BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSE
  • BROMO 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE
  • BROMO 2,3,4,6-TETRA-O-ACETYL-A-D-GLUCOPYRANOSE
  • 2,3,4,6-O-tetraacetyl-α-D-glucopyranosyl bromide
  • Acetobromglucose
  • Acetobromo-α-D-glucose;Acetobromglucose;Tetraacetyl bromoglucose
  • Tetraacetyl bromoglucose
  • ACETOBROMO-ALPHA-D-GLUCOSE, STAB.
  • ACETOBROMO-A-D-GLUCOSE CRYSTALLINE
  • 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosideBro
  • A-D-GLUCOPYRANOSYL BROMIDE
  • 1-BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE
  • 1-BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOSE
  • D-(+)-ALPHA-ACETOBROMOGLUCOSE (STABILISED)
  • ALPHA-BROMOGLUCOSE TETRAACETATE
  • ALPHA-D-ACETOBROMOGLUCOSE
  • ALPHA-D-ACETOBROMOGLUCOPYRANOSIDE
  • Tetraacetyl-α-D-galactopyranosyl bromide
  • 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide, stab., 98.50%
  • Bromo 2,3,4,6-Tetra-O-acetyl-a-D-glucopyranoside
  • 2,3,4,6-tetra-o-acetyl-à-d-glucopyranosyl bromide
  • 2,3,4,6-tetra-o-acetyl-α-d-glucopyranosyl bromide
  • acetobromo-à-d-glucose
  • 2,3,4,6-tetra-O-acetyl-α-D-glycopyranosyl bromide
  • 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE STABILIZED 98.5%
  • 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl broMide, stabilized, 98.5% 10GR
  • 2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl BroMide (stabilized with CaCO3)
  • 2,3,4,6-Tetra-O-acetyl-1-bromo-1-deoxy-alpha-D-glucopyranose min. 99%
  • Acetobromo-alpha-D-glucose, 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide, alpha-D-Glucopyranosyl bromide tetraacetate
  • 2,3,4,6-Tetra-O-acetyl-&alpha
  • -D-glucopyranosylBroMide
  • Acetobromo-
  • 2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide, stab. with 2% calcium carbonat
  • Acetobromo-alpha-D-glucose, stabilized with 2% calcium carbonate
  • 2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl bromide, Stabilized
  • ucopyranosyL
  • pha-D-g
  • [(2R,3R,4S,5R,6R)-3,4,5-TRIS(ACETYLOXY)-6-BROMOOXAN-2-YL]METHYL ACETATE
  • Acetobromo-D-glucose - 2% CaCO3
  • 2,3,4,6-tetra-O-acetyl-D-mannopyranosyl bromide
  • Reaxys ID: 1692090
  • Reaxys ID: 6074286
  • Reaxys ID: 6074287
  • tetra-O-acetyl-glucopyranosyl bromide
  • α-D-Tetramethylbromglucose
  • Tetra-O-pivaloyl-&alpha
  • acetobromo-a-d-glucose
  • alpha-d-glucopyranosylbromide,tetraacetate
  • α-D-Glucopyranosylbromide,tetraacetate
  • TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE
  • TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
  • 2,3,4,6-TETRA-O-ACETYL-1-DEOXY-ALPHA-D-GLUCOPYRANOSYL BROMIDE
  • 2,3,4,6-TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE
  • 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE BROMIDE
  • 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL
  • 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
  • 2,3,4,6-TETRA-O-ACETYLGLUCOSYLROMIDE
  • 2,3,4,6-TETRA-O-ACETYL-DEOXY-A-D-GLUCOPYRANOSYL BROMIDE